12-008 Code Vt. R. 12-032-008-X - CHAPTER 35 - INVESTIGATION AND REMEDIATION OF CONTAMINATED PROPERTIES RULE

SUBCHAPTER 1 GENERAL PROVISIONS
101 Authority and Purpose
(a) Authority. This rule is adopted by the Secretary of the Agency of Natural Resources pursuant to the authority granted by 10 V.S.A. chapters 47, 59, and 159.
(b) Purpose. This rule is intended to protect public health and the environment by establishing procedures and requirements for conducting investigations and corrective actions at properties where a release of hazardous materials has occurred. This includes procedures for identifying hazardous material contamination to environmental media as well as requirements for source treatment, removal, or containment, long term monitoring, institutional controls, and site closure.
102 Release Prohibition; Reporting; Emergency Response
(a) Release prohibition. The release of hazardous materials into the surface or groundwater, or onto the land of the State is prohibited.
(b) Releases and suspected releases. Any person required by 10 V.S.A. § 6617 shall immediately report any of the following releases or suspected releases:
(1) A release of hazardous material that exceeds two gallons.
(2) A release of hazardous material that is less than or equal to 2 gallons and poses a potential or actual threat to human health or the environment.
(3) A discharge of hazardous waste, or release of hazardous material that equals or exceeds its corresponding reportable quantity under CERCLA as specified under 40 CFR 302.4.
(4) The detection of non-aqueous phase petroleum liquid (NAPL) at a thickness greater than 0.01'.
(5) An exceedance of an environmental media standard other than an exceedance for which notification is required under subdivision (c) of this subsection.
(c) Notification of exceedances. Verbal notification within 24 hours of an exceedance of environmental media standard and written analytical results within five business days of the exceedance shall be provided to the Secretary under the following circumstances:
(1) When drinking water supply laboratory analytical results report an exceedance of the groundwater enforcement standards; and
(2) When indoor air quality laboratory analytical results report an exceedance of an indoor air standard.
(d) Reporting and notification under subsections (b) and (c) of this section must be directed to:

Monday through Friday, 7:45 AM to 4:30 PM; Waste Management & Prevention Division at (802) 828-1138.

At all other times including State holidays: Department of Public Safety Division of Emergency Management and Homeland Security at (800) 641-5005.

(e) Emergency response.
(1) Notwithstanding the site investigation and corrective action requirements of this rule, the Secretary may require or undertake an emergency response pursuant to 10 V.S.A. § 6615 when the Secretary determines that a release may cause an immediate and serious threat of harm to human health or the environment.
(2) When undertaking emergency responses pursuant to 10 V.S.A. § 1283, notification to the potentially responsible party (PRP) in advance of undertaking emergency response is not required, unless:
(A) The Secretary determines that there is need for additional investigation of the release to determine the impact to sensitive receptors and to human health and that it is appropriate for the PRP to conduct the investigation; or
(B) The Secretary determines that an additional response is necessary to address short-term impacts to sensitive receptors, impact to human health, and that it is appropriate for the PRP to conduct the additional response.
(3) The Secretary may direct the PRP to conduct a limited site investigation to determine if the release requires further site investigation or corrective action. As used in this subsection, "limited site investigation" means the steps the Secretary deems necessary to determine whether additional site investigation or corrective action is necessary to respond to the release of hazardous materials. In the event the PRP is unwilling, unable, or unknown, the Secretary may perform these actions and seek redress from the PRP at a later date as allowed by 10 V.S.A. § 1283.
103 Severability

The provisions of any section of this rule are severable. If any provision of this rule is invalid or if any application of this rule to any person or circumstance is invalid, the invalidity shall not affect other provisions or applications that can be given effect without the invalid provision or application.

104 Signatories

All deliverables required by § 35-102 (emergency response; limited site investigation); § 35-304 (site investigation work plan), § 35-306 (site investigation report); § 35-503 (response actions; releases of heating fuels; initial release investigation report); § 35-505 (additional site investigation); § 35-507(a) (response actions; releases of heating fuels; additional site characterization report); § 35-604 (evaluation of corrective action alternatives); § 35-606 (corrective action plan); § 35-608 (corrective action construction completion report); § 35-610 (corrective action performance monitoring and O&M); § 35-702 (long term monitoring work plan); and § 35-704 (long term monitoring; reporting) shall be prepared, signed, and certified by an environmental professional.

Deliverables shall be signed with the following certification:

"I certify under penalty of perjury that I am an environmental professional and that all content contained within this deliverable is to the best of my knowledge true and correct."

105 Deliverables

All deliverables shall be submitted electronically via text searchable PDF. Paper copies are to be submitted only upon request of the Secretary. Raw data, field notes, billing records, time sheets, or any other supporting documentation used to create the deliverable shall be made available upon request by the Secretary.

106 Hazardous Material Listing

Pursuant to 10 V.S.A. § 6602(16)(A)(iv) any chemical or substance listed in Appendix D is a hazardous material.

107 Historical Fill Exemption

The Secretary shall make a determination in writing that historical fill is present at a site and may exempt the historical fill from the site investigation and corrective action requirements of this rule. No exemption shall apply without the prior, written approval by the Secretary.

SUBCHAPTER 2 DEFINITIONS
201 Definitions

As used in this rule, terms shall have the following meanings:

(1) ".Aboveground storage tank" or "AST" means any tank, other than an underground storage tank, used to store any of the following petroleum products: gasoline, diesel, kerosene, used oil, or heating oil.
(2) "Agency" means the Vermont Agency of Natural Resources.
(3) "Analysis" or "analyze" means to test for the presence of hazardous materials using a standard US Environmental Protection Agency (US EPA) method or an alternative approved by the Secretary.
(4) "Area of contamination" means a defined area on a site where contaminated environmental media that is a hazardous waste has been generated by site remediation activities (e.g., excavated).
(5) "Background" means naturally occurring constituents where the concentration detected in the environmental media sampled is not influenced by site related activities.
(6) "Background Air Quality" means pollutant concentrations due to:
(1) natural sources;
(2) nearby sources other than the one(s) currently under consideration; or
(3) unidentified sources other than the one(s) currently under consideration.
(7) "Brownfield" means real property, the expansion, redevelopment, or reuse of which may be complicated by the presence, or perceived presence of, a hazardous material. "Brownfield" does not include any of the following:
(A) A facility that is the subject of a planned or ongoing removal action under CERCLA.
(B) A facility that is listed as a CERCLA site or is proposed for listing.
(C) A facility that is the subject of any State or federal administrative or court order under any of the following authorities:
(i) 33 U.S.C. § 1251 et seq. (federal Water Pollution Control Act) or 10 V.S.A. chapter 47 (water pollution control);
(ii) 15 U.S.C. § 2601 et seq. (Toxic Substances Control Act);
(iii) 42 U.S.C. § 300f et seq. (Safe Drinking Water Act) or 10 V.S.A. chapter 56 (public water supply).
(D) A facility that is subject to either of the following:
(i) corrective action under 42 U.S.C. §§ 6924(u) or 6928(h);
(ii) corrective action permit or order issued or modified to require the implementation of corrective measures.
(E) A land disposal unit in regard to which both of the following apply:
(i) a closure notification under subtitle C of 42 U.S.C. § 6921 et seq. has been submitted;
(ii) closure requirements have been specified in a closure plan or permit.
(F) A facility that is subject to the jurisdiction, custody, or control of any instrumentality of the United States, except for land held in trust by the United States for an Indian tribe.
(G) A portion of a facility to which both the following apply:
(i) a release of polychlorinated biphenyls has occurred;
(ii) is subject to remediation under 1. 5 U.S.C. § 2601 et seq. (Toxic Substances Control Act).
(H) A portion of a facility for which assistance for response activity has been obtained under subtitle I of 42 U.S.C. § 6991 et seq. (Solid Waste Disposal Act) from the Leaking Underground Storage Tank Trust Fund established under 26 U.S.C. § 9508.
(8) "BRELLA" means the Vermont Brownfields Reuse and Environmental Liability Limitation Act.
(9) "Category one underground storage tank" means any underground storage tank, regardless of its capacity, except:
(A) Fuel oil storage tanks used only for on-premises heating purposes; or
(B) Farm or residential tanks used for storing motor fuel.
(10) "Compliance point" means:
(A) the point of compliance as defined in the Vermont Groundwater Protection Rule and Strategy; and
(B) any point established in an approved corrective action plan established to evaluate a release's impact on a sensitive receptor.
(11) "Conceptual Site Model" or "CSM" is a written description of the physical, chemical, and biological processes that control the transport, migration, and actual and potential impacts of contamination (in soil, groundwater, soil gas, indoor air, sediment, or surface water) to sensitive receptors. CSM may include illustrations as appropriate.
(12) "Contamination" or "Contaminated" means the presence of any hazardous material in soil, groundwater, soil gas, indoor air, sediment, surface water, or any other material at a concentration that has the potential to adversely affect human health or the environment. This term does not include naturally occurring substances at or below background levels.
(13) "Development soil" means unconsolidated mineral and organic matter overlying bedrock that contains only PAHs, arsenic, or lead in concentrations that:
(A) exceed the relevant Vermont Soil Standard;
(B) when managed in accordance with § 35-804 or the Vermont Solid Waste Management Rule:
(i) pose no greater risk than the Agency-established soil standard for the intended reuse of the property; and
(ii) pose no unreasonable risk to human health through a dermal, inhalation, or ingestion exposure pathway;
(C) do not leach compounds at concentrations that exceed groundwater enforcement standards; and
(D) do not result in an exceedance of Vermont Groundwater Enforcement Standards.
(14) "Direct contact" means physical exposure to contaminants or naturally occurring compounds in environmental media including soil, groundwater, soil gas, indoor air, sediment, or surface water via incidental ingestion, dermal contact, inhalation of vapors, or fugitive dust via a completed contact pathway.
(15) "Environmental easement" means a legal restriction on a property that grants a real property interest to the State to enforce maintenance requirements, monitoring requirements, or land use restrictions.
(16) "Engineered control" means any physical barrier, system, technology, or method that removes or reduces exposure to a hazardous material by sensitive receptors.
(17) "Environmental media" means components of the environment including soil, groundwater, soil gas, indoor air, sediment, or surface water.
(18) "Environmental media standards" means numeric or narrative criteria adopted by the Secretary to protect human health and the environment.
(19) "Environmental professional" means a person who possesses the following education, training, and experience:
(A) A current professional engineer's (with certification within relevant area of expertise) or professional geologist's license or registration from a state, tribe, or U.S. territory (or the Commonwealth of Puerto Rico) and the equivalent of three years of relevant fulltime experience;
(B) A license or certification by the federal government, a state, tribe, or U.S. territory (or the Commonwealth of Puerto Rico) to perform environmental site work equivalent to that required by this rule and have the equivalent of three years of relevant fulltime experience;
(C) A baccalaureate or higher degree from an accredited institution of higher education in a discipline of engineering, geology, hydrogeology, or an applicable science and the equivalent of five years of relevant fulltime experience; or
(D) The equivalent of ten years of relevant fulltime experience in a discipline of engineering, geology, hydrogeology, or an applicable science.
(20) "Emergency response" means a response action to a situation that may cause immediate and serious threat of harm to human health or the environment.
(21) "Groundwater" means water below the land surface in a zone of saturation.
(22) "Hazardous material":
(A) means all petroleum and toxic, corrosive, or other chemicals and related sludge included in any of the following:
(i) any substance defined in section 101(14) of the federal Comprehensive Environmental Response, Compensation and Liability (CERCLA) Act of 1980;
(ii) petroleum, including crude oil or any fraction thereof;
(iii) hazardous wastes as defined by the Vermont Hazardous Waste Management Regulations; or
(iv) a chemical or substance that, when released, poses a risk to human health or other living organisms and that is listed by this rule.
(B) does not include herbicides and pesticides when applied consistent with good practice conducted in conformity with federal, state, and local laws and regulations and according to manufacturer's instructions.
(23) "Hazardous waste" means any waste subject to regulation as hazardous waste under the Vermont Hazardous Waste Management Regulations.
(24) "Heating fuel" means heating oil, kerosene, or other dyed diesel fuel that is not used to propel a motor vehicle and which is typically used to heat a structure. Includes any blend of petroleum and biodiesel used to heat a structure.
(25) "Historical fill" means non-indigenous material deposited to raise the topographic elevation of the site, which, if contamination exists in such material, is not resultant from the land use or activities at the location of emplacement. Material is "historical fill" if, based on the weight of evidence the material is determined by the Secretary to meet the following criteria:
(A) was emplaced before May 20, 1985 (the effective date of § 6615.V.S.A.);
(B) is not primarily composed of, construction and demolition debris, reworked soils, dredge spoils, coal, coal ash, wood ash or other solid waste material;
(C) was contaminated with metals, hydrocarbons, or polycyclic aromatic hydrocarbons where such contamination occurred prior to emplacement and exists at concentrations consistent with the pervasive use and release of such materials prior to 1985;
(D) does not contain oil or hazardous materials originating from operations or activities at the location of emplacement;
(E) is not and does not contain a generated hazardous waste;
(F) does not contain chemical production waste, manufacturing waste, or waste from processing of metal or mineral ores, residues, slag or tailings; and
(G) does not contain waste material disposed in a municipal solid waste dump, burning dump, landfill, waste lagoon or other waste disposal location.
(26) "Impervious surface" means those fabricated surfaces, including paved and unpaved roads, parking areas, roofs, driveways, and walkways, from which precipitation runs off rather than infiltrates
(27) "Institutional controls" means non-engineered instruments, such as administrative and legal controls, that help minimize the potential for exposure to a hazardous material or protect the integrity of a remedy.
(28) "Investigation derived waste" means all waste generated during the site investigation or corrective action including, but not limited to, soil cuttings, groundwater, cleaning fluids and wash water, or disposable equipment.
(29) "Land record notice" means a notice on a property land record that informs individuals of the release of a hazardous material on a property and any steps necessary to address this release or residual contamination under the direction of the Secretary.
(30) "Legal description of property" is a description that identifies the location, boundaries, and any existing easements on the property, also referred to as metes and bounds.
(31) "Linear construction project" means construction and development activities, such as waterline and sewer line improvements, that take place within a public or private roadway, railroad, utility line, or their respective rights-of-way where contamination is encountered.
(32) "Long term monitoring" means sampling and analysis of environmental media for contaminants of concern in accordance with an approved monitoring plan. The purpose of long-term monitoring is to demonstrate that the selected remedial method is protective of human health and the environment.
(33) "Method detection limit" means the minimum concentration of a hazardous material that can be quantified consistently and reliably using methods approved by US EPA or another method approved by the Secretary.
(34) "Non-aqueous phase liquid" or "NAPL" means a liquid solution contaminant that does not dissolve in or easily mix with water, such as oil, gasoline, coal tar, or chlorinated solvents. A NAPL may be denser than water, sinking below the water table, or lighter than water, floating on the water table.
(35) "Non-hazardous waste contaminated soil" means soils that are contaminated with hazardous materials at concentrations above the Residential Vermont Soil Standard that are not hazardous wastes under the Vermont Hazardous Waste Management Rule.
(36) "Non-hazardous petroleum contaminated soil" means soils that are contaminated with petroleum but meet the exemption requirements of the Vermont Hazardous Waste Management Regulations in § 7-203(p) and may be managed in accordance with this Rule.
(37) "Non-residential" means any property or portion thereof that is designated as non-residential by municipal zoning ordinance or has a restriction prohibiting residential use.
(38) "Polyencapsulation" means action of storage of contaminated soil by stockpiling on plastic sheeting and enclosing the stockpile with plastic sheeting.
(39) "Potable water supply" means the source, treatment, and conveyance equipment used to provide water used or intended to be used for human consumption, including drinking, washing, bathing, the preparation of food, or laundering. This definition does not include any internal piping or plumbing, except for mechanical systems, such as pump stations and storage tanks or lavatories, that are located inside a building or structure and that are integral to the operation of a potable water system. This definition also does not include a potable water supply that is subject to regulation as a public water supply.
(40) "Potentially Responsible Party" or "PRP" means any individual or organization that is potentially liable for a release of hazardous materials pursuant to 10 V.S.A. § 6615.
(41) "Public water source protection area" means a surface and subsurface area from or through which contaminants are reasonably likely to reach a public water system source.
(A) "Public water system" shall have the same meaning as set forth in the 10 V.S.A. § 1671.
(42) "Receiving site" means a location approved by the Secretary where excavated development soils are disposed in accordance with this rule.
(43) "Recognized environmental condition" means the presence or likely presence of a hazardous material at a property:
(A) due to a release;
(B) under conditions indicative of a release to the environment; or
(C) under conditions that pose a material threat of a future release to the environment.
(44) "Release" means any intentional or unintentional action or omission resulting in the spilling, leaking, pumping, pouring, emitting, emptying, dumping, or disposing of hazardous materials into the surface or groundwaters, or onto the lands in the State, or into waters outside the jurisdiction of the State when damage may result to the public health, lands, waters, or natural resources within the jurisdiction of the State.
(45) "Remedy" means an action that results in either a reduction of exposure to human health to contaminants, or a lessening of risk to a sensitive receptor.
(46) "Residential" includes all locations used as or for residences as well as parks, playgrounds, schoolyards and child care facilities.
(47) "Residual contamination" means hazardous materials that remain in any environmental media above screening values or standards after all required site investigation and correction action has been completed and that the Secretary has determined does not pose a threat to human health or the environment given the current condition or location of the hazardous materials.
(48) "Secretary" means the Secretary of the Vermont Agency of Natural Resources or the Secretary's duly authorized representative.
(49) "Sensitive receptor" means any natural or human-constructed feature that may be adversely affected by a hazardous material and includes public health, public water sources, other sources of potable water supplies, groundwater, surface waters, wetlands, soils, sensitive ecological areas, outdoor and indoor air, and enclosed spaces such as basements, sewers, and subsurface utilities.
(50) "Site" means the area where a release is known or suspected to have occurred, including the extent of contamination resulting from the release. A site may not be limited by legal property boundaries.
(51) "Substantial completion" means:
(A) the site is enrolled in the BRELLA program; and
(B) the property has a remediation system constructed in accordance with an approved corrective action plan; and
(i) the remediation system is operating as designed following implementation of corrective action;
(ii) the institutional controls for the property have not been finalized; or
(iii) long term monitoring is necessary to determine whether remedial objectives are being achieved.
(52) "Surface water" includes all rivers, streams, creeks, brooks, reservoirs, ponds, lakes, springs and all bodies of surface waters, artificial or natural, which are contained within, flow through or border upon the State or any portion of it.
(53) "Surface soil" means soil present at 0-18 inches below ground surface.
(54) "Survey benchmark" means a feature on a site or nearby to which the surveyed elevation of all monitoring wells and site features are referenced.
(55) "Suspected release" means when there is knowledge, information, or other evidence that a release has likely occurred. An exceedance of an environmental media standard shall be presumed to be a suspected release and shall be reported pursuant to § 35-102(b). Knowledge and information of a suspected release may include review of maintenance and operation records, land use history, or industry standard process details.
(56) "Treatment" means any method, technique, or process designed to change the physical, chemical, or biological character or composition, or remove, any contaminant in environmental media.
(57) "Underground Storage Tank" or "UST" shall be defined as set forth in the Vermont Underground Storage Tank Rule.
(58) "Urban Background Area" means any area designated by the Secretary, for reuse of development soils that are below the applicable urban background values.
(59) "US EPA" means United States Environmental Protection Agency.
(60) "Vapor intrusion" means the migration of volatile or semi-volatile chemicals from contaminated environmental media or product into a building, subsurface conduit or structure.
(61) "Volatile Organic Compound (VOC)" are volatile carbon containing compounds which have a high vapor pressure at room temperature or dissolve into water.
(62) "Volatile Organic Compound (VOC) field screening instrument" means a photoionization detector, flame ionization detector, field portable gas chromatograph/ mass spectrometer or another portable instrument approved by the Secretary to detect VOCs.
(63) "Water table" means the top of the saturated zone where the fluid pressure equals the atmospheric pressure.
SUBCHAPTER 3 SITE INVESTIGATION
301 Applicability and Requirement to Perform Site Investigation
(a) This section applies to any release or suspected release that is not fully investigated pursuant to § 3S-102 (emergency response), or Subchapter S (response action; heating fuel) of this rule.
(b) A person who may be liable for the release or suspected release of a hazardous material as established in 10 V.S.A. § 6615 shall conduct a site investigation in accordance with the requirements of this chapter.
302 Objectives of Site Investigation

Objectives of a site investigation are to:

(a) Develop a Conceptual Site Model (CSM) in accordance with § 35-303;
(b) Identify the source, degree, and spatial extent of contamination in all impacted or potentially impacted environmental media;
(c) Identify pathways that are conveying or could convey hazardous materials to sensitive receptors;
(d) Identify sensitive receptors that have been or may be impacted by the release;
(e) Identify data gaps that must be addressed to confirm the CSM or evaluate corrective action alternatives; and
(f) Identify the need to conduct further investigation or corrective action based on the results of all site characterization data gathered to date.
303 Conceptual Site Model
(a) A preliminary CSM shall be developed during the preparation of the site investigation work plan required by § 35-304. The CSM shall be further refined as new site data is collected.
(b) The CSM is a tool to identify sources, receptors, and pathways associated with the site and should support scientific and technical decisions. A CSM is an iterative process of characterizing site contamination based on available site data and both historical and existing conditions. The CSM shall evaluate and present the data in a narrative format that depicts the fate and transport of site contaminants, addresses the threat or potential threat to human health and the environment from the site contaminants, and identifies data gaps.
(c) The CSM shall identify the following or identify how the information will be obtained in the context of the site investigation:
(1) Source(s) of the release;
(2) The location, depths, and characteristics of existing and former engineered structures, subsurface infrastructure, tanks, and containers, from which or through which the suspected contaminants may have been released, transported, or may impact a sensitive receptor;
(3) Historical and current land uses and activities for the site and immediate surrounding area;
(4) Sources and contaminants;
(A) Identify all potential hazardous materials and all potential and actual sources of a release;
(B) Identify, to the extent possible, the release date(s), location(s) known volume(s), and any prior remedial actions;
(C) Identify all hazardous material phases (e.g. NAPL, sorbed to matrix, dissolved in groundwater or soil moisture, and in vapors in the vadose zone);
(D) Identify all hazardous material physical properties and the likely behavior (mobility, physical state, and persistence) of each chemical within environmental media;
(E) If known, an estimate of the amount of hazardous material mass on the site; and
(F) If known, an estimate of the amount of contaminated soil.
(5) Identify the environmental media that is affected or threatened from the release.
(6) Geology. A brief description of regional and site-specific soils and bedrock. Boring logs, well logs and groundwater confining layers shall be included, if available and not been previously submitted to the Secretary. If applicable, values for soil bulk density, porosity, fraction organic content, pH and reduction-oxidation potential, shall be included. If available include geologic maps, fracture trace maps, geophysical data, and cross sections;
(7) Hydrogeology. Describe regional and site-specific hydrogeology, horizontal and vertical groundwater flow gradients and direction, and an assessment of the potential for preferential pathways and multiple aquifers. If available, hydraulic conductivity, transmissivity, and other parameters shall be included;
(8) Contaminant fate and transport. Describe the hazardous material distribution, migration pathways, the amount of migration occurring, the predicted migration of the contamination over time, and if available, the adsorption, desorption, absorption, and retardation of the hazardous material, and naturally occurring degradation processes. If historical groundwater quality data have been collected, estimate the duration of groundwater contamination to determine if groundwater reclassification is warranted per the Groundwater Protection Rule and Strategy;
(9) Receptor study and evaluation. Identify all potentially threatened sensitive receptors and complete exposure pathways. A list of the names and addresses of impacted or threatened third parties shall be included, if applicable. Compare all measured concentrations of hazardous materials with applicable environmental media standards; and
(10) If appropriate, a figure illustrating the site setting and key contaminant migration mechanisms and pathways, both complete and incomplete.
304 Site Investigation Work Plan
(a) General requirements.
(1) A site investigation work plan shall be submitted to the Secretary no later than 30 days of the date the Secretary was notified of a release or upon request by the Secretary, unless the Secretary approves an alternative schedule.
(2) A site investigation work plan shall be approved by the Secretary prior to the initiation of site work.
(b) Content requirements. A site investigation work plan shall include the following:
(1) Site information. Table of names, addresses, email addresses, and phone numbers of the following:
(A) Property owner and operator; and
(B) Any person or entity who released a hazardous material at the site.
(2) Current land use and activities of the property.
(3) Land uses and activities of properties adjacent to the site.
(4) Site description. A physical and environmental description of the site.
(5) Site characterization objectives and strategy. This strategy shall address known data gaps and include contaminant characterization methods, sampling locations and methods, and how this strategy will meet the site investigation objectives;
(6) Identification of analytical methods.
(7) A list of consultant standard operating procedures to be used during the site investigation, which shall be submitted to the Secretary upon request.
(8) A CSM and a description on how the site investigation will gather information to further develop and refine the CSM.
(9) A discussion of how investigation derived waste will be managed, which shall be in accordance with § 3 5-611 (c).
(10) A quality assurance and quality control (QA/QC) plan.
(11) Maps. Unless otherwise required by the Secretary, a vicinity map in accordance with § 35-306(b)(14)(A) and a site map in accordance with § 35-306(b)(14)(B) showing proposed environmental media sampling locations shall be included.
(12) Latitude/longitude of the site, as close as possible to the known or suspected release location or locations, referenced to the WGS1984 coordinate system (Mercator), in decimal degrees with a minimum acceptable accuracy of plus-or-minus 15 feet.
(13) Estimated costs, if requested by the Secretary.
(14) A site investigation implementation schedule.
(15) Signature. A site investigation work plan shall be signed by the environmental professional in accordance with § 35-104.
305 Site Investigation Work Plan; Secretary Review and Determination
(a) The Secretary shall only approve, in writing, a site investigation work plan upon finding the investigation will meet the objectives of § 35-302.
(b) A PRP shall implement an approved site investigation work plan no later than 60 days from the date of the Secretary's approval, unless an alternate implementation timeline is approved by the Secretary.
306 Site Investigation Report
(a) A site investigation report shall be submitted to the Secretary within 90 days of receipt of final laboratory data, or within an alternate schedule approved by the Secretary.
(b) A site investigation report shall include the following:
(1) Executive summary. A site investigation report shall include an executive summary of the site investigation, consisting of a summary of findings, conclusions, and recommendations based upon the data collected during the site investigation.
(2) Site contact information. Table of names, addresses, email addresses, and phone numbers of the following:
(A) Property owner and operator.
(B) Any Potentially Responsible Party who caused or may have caused a release a hazardous material at the site.
(3) Current use or uses of the property.
(4) Land uses and activities of properties adjacent to the site.
(5) Site description. A physical and environmental description of the site.
(6) Latitude/longitude of the site, as close as possible to the known or suspected release location or locations, referenced to the WGS1984 coordinate system (Mercator), in decimal degrees. Minimum acceptable accuracy is plus-or-minus 15 feet.
(7) Property history. Past and present land use, waste storage or disposal areas, potential sources of contamination, and hazardous waste and hazardous materials disposal practices, including any associated EPA ID numbers. The property history section shall include a description of current and historical property uses in the surrounding area. A list of all recognized environmental conditions should be provided if an ASTM Phase I or Phase II Environmental Site Assessment has been completed. Presentation may include copies of historical maps (including Sanborn Fire Insurance Maps, town maps) and copies of town directories.
(8) Site contaminant background. A description of all known releases of hazardous materials, including the following information:
(A) The date and a description of each release, if known, the discovery date of each release, the location of each release, and the PRP for each release.
(B) The date each release was reported to the Secretary.
(C) A description of response actions taken for each release.
(D) A list of any previous environmental investigations and reports (including Phase I Environmental Site Assessments) pertinent to the site relating to a release of hazardous materials, including a summary of findings.
(E) A copy of any previous investigation or report relating to a release of hazardous materials, if not already on file with the Secretary.
(F) A list of governmental records reviewed relating to the site.
(9) A CSM as detailed in § 35-303.
(10) Work plan protocol deviations. Any deviations from the approved work plan shall be identified and discussed.
(11) Sample-collection documentation. Documentation of the sample location, method of collection, and well identification number.
(12) Contaminated media characterization. Analytical results from the Site Investigation and applicable prior investigations shall be tabulated and compared to the applicable environmental media standard in accordance with Subchapter 4, unless a site-specific risk assessment was conducted pursuant to § 35-306(b)(13) or a site-specific background study was performed in accordance with Appendix B (in which case the analytical results from the Site Investigation will be compared with these alternative values).
(13) As applicable, a site-specific risk assessment that includes use of chemical and endpoint specific toxicity values and site-specific exposure assumptions may be performed for both current and potential future site uses. A site-specific risk assessment shall follow standard U.S. E.P.A. risk assessment methodology to determine if an incremental lifetime cancer risk of 10 [-6 ] or a hazard index of 1.0 is exceeded.
(14) Maps. All maps shall include the location of the site, physical and environmental features, the Vermont Department of Environmental Conservation Hazardous Site number, legend, graphical scale bar, and a base map source reference. All maps shall be accurate and to scale. The following maps shall be included:
(A) Vicinity map. Prepared using the Vermont Agency of Natural Resources online Natural Resource Atlas as a base map including property boundary lines, surrounding land use, buildings, hazardous sites, hazardous materials sources, street names, drinking water sources, surface water bodies and any other sensitive receptors identified in § 35-303(c)(9) within 2,000 feet of the site. Alternative base maps and fewer map elements may be used if approved by the Secretary.
(B) Site map. A site investigation map shall include the following:
(i) Surface topography spot elevations or contours.
(ii) Property boundary lines.
(iii) Environmental media sample locations.
(iv) Contaminant source areas, including former or current tank locations, release areas, chemical storage or process areas, waste storage and disposal locations, or other areas as appropriate.
(v) Engineered structures, including asphalt parking surfaces, concrete sidewalks, drainage ways, diversion ditches, drain tiles, manholes, lined areas, leachate collection systems, septic systems, sewer lines, floor drains, drywells.
(vi) Survey benchmark. A permanent and recoverable site feature shall be assigned as the site survey benchmark. The use of the top of monitoring well risers, road box covers, or concrete pads as a benchmark is prohibited.
(C) Groundwater contour map. The groundwater contour map shall include the location of all monitoring points and data collected to create groundwater elevation contours. Multiple maps may be needed to show groundwater flow in different aquifers. A groundwater contour map will not be required if the site investigation did not include the installation of groundwater monitoring wells.
(D) Contaminant distribution map. A contaminant distribution map shall include the location of all monitoring points and laboratory analytical result (including non-detect) for that monitoring point. As applicable, based on the site-specific geology and distribution of contaminants of concerns (i.e. exceeding a standard), isopleths shall be used to indicate the approximate location of compound-specific contaminant plumes that exceed the applicable environmental media standard. Multiple maps may be required to illustrate multiple contaminants or multiple aquifers. Maps solely depicting total contaminants (e.g. total VOCs) will not be accepted, unless otherwise approved by the Secretary. At sites where isopleth maps are not appropriate, contaminant concentrations shall be plotted on the maps adjacent to the sampling points.
(15) Discussion. The discussion shall include a descriptive analysis of how the data gathered further refines the CSM, how the CSM has been updated, and how the site investigation objectives in § 35-302(a) have been met. The discussion shall also establish that the data collected are suitable to determine the existing and future exposure to sensitive receptors and, the need for further characterization. Only data that meets quality assurance quality control (QA/QC) criteria will be accepted. A discussion of data which doesn't meet QA/QC criteria shall be included. The report shall evaluate if the data demonstrates that Vermont Groundwater Enforcement Standards (VGES) are met at compliance points, and if not, the estimated timeframe for meeting VGES at compliance points.
(16) Data presentation. All collected data shall be organized in a narrative, tabular, and graphical form; data shall be presented on maps and cross sections when appropriate. All detected hazardous material concentrations shall be reported. Hazardous materials that are not detected shall be reported as less than the numerical detection limit. Detection limits shall be below the environmental media standards and shall be provided in tabular format with the analytical results. All laboratory data qualifications must be included in tabulated data presentations.
(17) QA/QC sample results. At a minimum, a trip blank, a method blank and a duplicate sample will be required. If field analytical methods are approved in the work plan, the Secretary may require that a subset of samples be analyzed at a fixed base laboratory. Additional QA/QC samples (e.g. field blanks) may be required by the Secretary depending on the complexity of the investigation or sampling methods used. Any deviations from QA/QC procedures or acceptable limits shall be identified and discussed. Only data that meets quality assurance quality control (QA/QC) criteria specified in the QA/QC Plan will be accepted.
(18) Investigation derived waste. All investigation derived waste generated during the site investigation shall be managed in accordance with § 35-611(c). A discussion of how the investigation derived waste was managed shall be included in the site investigation report.
(19) Conclusions and recommendations. The site investigation report shall include a discussion of the findings of the investigation that substantiate the revised CSM, and, specifically, the risk that hazardous materials pose to identified sensitive receptors. Further this section shall identify completed exposure pathways, data gaps, and potential corrective actions. The PRP shall make recommendations on proposed monitoring and frequency and need for further investigation, an evaluation of corrective action alternatives, corrective action, institutional control, or site closure. If additional data collection is necessary in order to identify an appropriate corrective action, then additional site investigation will be required.
(20) Signature and certification. A site investigation report shall be certified by the environmental professional that it was conducted in accordance with the approved workplan and signed in accordance with § 35-104.
(21) Appendices.
(A) Standard operating procedures. A list of consultant standard operating procedures (SOPs) that were used during site investigation. SOPs shall be provided to the Secretary upon request.
(B) Monitoring well and soil boring logs. At a minimum, logs shall include a description and discussion of monitoring well, soil boring and test pit installation. Logs shall include well boring or test pit location with latitude and longitude. In addition, logs shall include the installation method, blow count data, elevation, total depth, depth to groundwater, soil or rock descriptions, well construction, hole backfill, or sealing information, odors noted, and field screening results.
(C) Photographic documentation. Color images showing work performed at the site (UST closure, soil stockpiles, etc.) and pertinent site or vicinity features shall be included as an appendix. Each photographic presentation shall include the date and time, location, and orientation.
(D) Field notes. Copies of the original field notes shall be attached as an appendix and the field notes shall contain the following minimum content: the date the work was performed, name of the person conducting the work, tasks completed, date, documentation of weather conditions, sampling timeline with locations, sampling logs, field monitoring results, and calibration information for each type of field analytical equipment.
(E) Laboratory results. A copy of the laboratory results, chains of custody documentation and all QA/QC data, as specified in the approved work plan shall be included.
(F) Calculations. All calculations, such as contaminant mass or volume, travel and migration time, natural attenuation, Cumulative Risk Assessment and groundwater gradients. If computer modeling is conducted, a reference to the model used, the data inputs, and data output package shall be included.
(G) If a quantitative human health risk assessment is conducted, the full risk assessment report, including summary tables and electronic copies of calculating spreadsheets, shall be included.
(H) Hydrogeologic cross sections. When requested by the Secretary or approved in a work plan.
307 Review of Site Investigation Report
(a) The Secretary shall review the site investigation report for completeness with the requirements of § 35-306(b) and shall provide written notification to the PRP of one of the following determinations:
(1) The site investigation has met the objectives of § 35-302, has adequately defined the degree and extent of contamination, and risks to sensitive receptors have been appropriately evaluated and are absent or have been adequately managed, and that:
(A) The site is eligible for closure in accordance with Subchapter 10;
(B) Long-term monitoring may be required in accordance with Subchapter 7; or
(C) Institutional Controls may be required in accordance with Subchapter 9.
(2) The site investigation has not met the objectives of § 35-302 and/or has not adequately defined the scope and extent of contamination or risk to sensitive receptors. The PRP shall submit a supplemental site investigation work plan that meets the requirements of § 35-304(b) within 30 days of the Secretary's notification to address data gaps or other deficiencies identified by the Secretary.
(3) The site investigation report is incomplete. The site investigation report will be returned to the PRP for additional information and resubmittal within a timeframe established by the Secretary; or
(4) The site investigation has met the objectives of § 35-302 and has adequately defined the degree and extent of contamination but risks to sensitive receptors are present or have not been adequately managed. An evaluation of corrective action alternatives, or corrective action plan shall be completed in accordance with Subchapter 6. If requested by the Secretary, a work plan or cost estimate for an Evaluation of corrective action alternatives (ECAA) and/or CAP may be required.
SUBCHAPTER 4 DATA EVALUATION
401 Evaluation of Environmental Media Laboratory Analytical Results
(a) Applicability. A PRP shall evaluate laboratory analytical data for samples collected from environmental media as part of site characterization or to document corrective action implementation and completion. Acceptable methods for data evaluation include direct comparison to environmental media standards and cumulative assessment of risk. Specific environmental data evaluation methods shall be utilized as provided in this Subchapter.
(b) Applicable standards comparison. All analytical results shall be compared to the applicable standard set forth in Appendix A, the Vermont Groundwater Protection Rule and Strategy and the Vermont Water Quality Standards. In the absence of an applicable standard, a PRP shall refer to the applicable and most current US EPA Regional Screening Level.
(c) Soil analytical results comparison. All soil sample results for each sample shall be compared to the Vermont Soil Standards in Appendix A of this Rule. Laboratory analytical results shall be compared to Vermont Residential Soil Standards unless the property is zoned for non-residential use only.
(d) The following methods shall be applied to determine risk to public health, as applicable:
(1) Method 1 Soil Screening employs a direct comparison of individual soil sample laboratory analytical results to the applicable Vermont Residential or Non-residential Soil Standards as follows:
(A) All detected contaminant concentrations shall be compared to the applicable Vermont Soil Standard (VSS).
(B) All laboratory results that are estimated shall be compared to the VSS using the value reported from the lab. Alternatively, the sample may be re-analyzed by a more sensitive laboratory method to lower the MDL to generate a value that is not estimated.
(C) Any non-detect result for contaminants of concern with an MDL that exceeds the VSS shall be considered a detected concentration equivalent to the MDL.
(D) If the sample was collected from a depth of 0 to 18 inches below ground surface and detected compound concentrations for contaminants of concern do not exceed any VSS, a Method 2 cumulative risk assessment for surface soils shall be performed.
(2) Method 2 Cumulative Risk Assessments (CRA) for surface soils. The Method 2 CRA determines if an incremental lifetime cancer risk (ILCR) of 10 [-6 ] or a hazard index (HI) of 1.0 is exceeded based on direct contact. The risk is expressed as the total (summed) risk made up of each individual compound.
(A) Compounds with non-detect results shall be not be included in the Method 2 CRA.
(B) A Method 2 CRA shall be performed by using the calculations provided in Appendix E.
(3) Method 3 Site-Specific Risk Assessment. A PRP may elect to perform a site-specific risk assessment (SSRA). The Method 3 SSRA determines if an incremental lifetime cancer risk of 10 [-6 ] or a hazard index of 1.0 is exceeded.
(e) Vapor intrusion evaluations. If indoor air sampling is required based on existing soil gas or groundwater analytical data, the presence of non-aqueous phase liquid, and an assessment of vapor intrusion pathways, then an evaluation shall be conducted in accordance with this subsection.
(1) Soil gas analytical results. All detected compound concentrations shall be compared to the Vapor Intrusion Standards (VIS) for soil gas provided in Appendix A of this rule.
(2) Groundwater analytical results. All detected compound concentrations shall be compared to the VISs for groundwater provided in Appendix A of this rule.
(f) Indoor air sample analytical results. All indoor air sample results attributable to a release shall be compared to the applicable Vermont Indoor Air Standards found in Appendix A. Laboratory analytical results shall be compared to Vermont Residential Indoor Air Standards unless the property is zoned for non-residential use only.
(g) The following methods shall be applied to determine risk to public health, as applicable:
(1) Method 1 Indoor Air Screening employs a direct comparison of detected indoor air analytical concentrations in each sample to the applicable Vermont Indoor Air Standards (VIAS) as follows:
(A) All detected analytical concentrations shall be compared to VIAS.
(B) All laboratory estimated concentrations shall be compared to VIAS.
(C) Any non-detect result for contaminants of concern where the MDL exceeds the VIAS shall be considered a detection above a standard.
(D) If detected analytical concentrations for contaminants of concern do not exceed the VIAS, a Method 2 cumulative risk assessment shall be performed.
(2) Method 2 CRA for indoor air.
(A) Compounds with non-detect results shall be not be included in the Method 2 CRA.
(B) Method 2 CRA shall be performed by using the calculations provided in Appendix E.
(3) Method 3 SSRA. A PRP may elect to perform a site-specific risk assessment. The Method 3 SSRA determines if an incremental lifetime cancer risk of 10 [-6 ] or a hazard index of 1.0 is exceeded.
(h) Groundwater analytical results. All detected compound concentrations shall be compared to the Vermont Groundwater Enforcement Standards.
(i) Drinking water analytical results. All detected compound concentrations shall be compared to the Vermont Groundwater Enforcement Standards or, when available, the Vermont Action Levels.
(j) Surface water analytical results. All detected compound concentrations shall be compared to the Vermont Water Quality Standards.
(k) Sediment analytical results. All detected compound concentrations shall be compared to the Threshold Effect Concentration (TEC) and Probable Effects Concentration (PEC) provided in Appendix A.
(l) Data evaluation for specific contaminant classes.
(1) Some chemicals are members of the same family or group and have been shown to exhibit similar toxicological properties; however, each chemical may differ in the degree of toxicity. In such instances, a toxicity equivalence factor (TEF) or relative potency factor (RPF) shall be applied to convert the reported concentration of each member of the group to a toxicity equivalence quotient (TEQ) relative to the toxicity of the index chemical for the group. The index chemical is assigned a TEF of 1. Total TEQ for a sample shall then be compared to the value for the index chemical.
(2) Evaluating classes of contaminants such as dioxins, carcinogenic polycyclic aromatic hydrocarbons, and polychlorinated biphenyls shall be reported as follows:
(A) Dioxins, furans, and dioxin-like PCBs. Soil and sediment results must be compared to (2,3,7,8) tetrachlorodibenzo-p-dioxin (TCDD) toxic equivalency as follows:
(i) Laboratory results must include the 2,3,7,8-TCDD TEFs employed, raw concentrations and TEQ values for each individual dioxin-like compound. The TEF are found in Appendix F of this rule.
(ii) For dioxin-like compounds that are non-detect, a value equal to one half the reported MDL shall be used to calculate the TEQ.
(iii) The total TEQ per sample shall be reported.
(B) Carcinogenic Polycyclic Aromatic Hydrocarbons (cPAHs). cPAHs shall be evaluated as follows:
(i) Soil analytical results for cPAHs shall be reported as benzo(a)pyrene TEQ.
(ii) For cPAH compounds that are non-detect, a value equal to one half the reported MDL shall be used for calculating the TEQ. Sediment shall be compared to the individual PAH in Appendix A. Relative potency factors are found in Appendix F.
(C) Polychlorinated Biphenyls (PCBs). Analytical results for PCBs shall be evaluated as follows:
(i) If results are analyzed as PCB Aroclors, analytical results shall be totaled and used to estimate total PCBs and compared to the VSS or VGES as applicable.
(ii) If PCBs are reported as homologs, the sum of all homologs will be used as an estimate of total PCBs and shall be compared to the VSSs located in Appendix A, or appropriate groundwater enforcement standards or VISs. If PCBs are reported as congeners, dioxin-like congeners shall be segregated and assessed and included in estimates of 2,3,7,8-TCDD TEQ, per the above section. Non-dioxin-like congeners shall be summed and compared to the VSS.
(iii) If PCBs are included in a Method 2 CRA, PCB Aroclor and homo log concentrations shall be added to the concentration for PCBs. PCB congener data shall be separated as described above.
(iv) The total PCBs will be evaluated for noncancer hazard based on the noncancer toxicity value of Aroclor 1254.
(m) Data Quality Assurance/ Quality Control Analytical Results.
(1) Depending on site-specific conditions and quality assurance/ quality control (QA/QC) objectives included in the QA/QC plan, a trip blank, a method blank and a duplicate sample may be required.
(2) If field analytical methods are approved in the work plan, the Secretary may require that a subset of samples be analyzed at a fixed base laboratory.
(3) Additional QA/QC samples (e.g. field blanks) may be required by the Secretary depending on the complexity of the investigation or sampling methods used.
(4) Any deviations from QA/QC procedures or acceptable limits shall be identified.
(5) Only data that meets quality assurance quality control (QA/QC) criteria specified in the QA/QC Plan will be accepted.
402 Investigation; Soil Removal and Drinking Water
(a) Soil removal. Following approval from the Secretary, a PRP shall remove impacted soil in the area where a release of heating oil occurred until VOC field screening instrument readings are below 10 ppmv. Post excavation soil samples shall be collected to document removal of contamination or to characterize soil contamination remaining in place. If removal of soil is not possible due to physical constraints, the PRP shall:
(1) Collect and analyze a soil sample of soils remaining in place from the area determined to be the most contaminated by field measurements; and
(2) If groundwater is encountered, collect and analyze a groundwater sample from the excavation area.
(b) Bedrock. Soil excavation shall be extended to the soil bedrock interface to determine if impacted soil is present unless:
(1) the vertical extent of contaminated soil is delineated and determined to be adequately separated from the bedrock surface; or
(2) excavation to bedrock is physically impossible or a confining soil layer is present, in which case the PRP shall collect a water sample from all drinking water supply wells drilled into bedrock within 200 feet of the release.
(c) Drinking water. If a drinking water supply well is located anywhere on the property or an off-site property within 200 feet of the release, a sample shall be collected from the public water system or potable water supply for appropriate laboratory analysis.
(d) Vapor intrusion. If there is any building within 30 feet of the release, indoor air shall be screened with a VOC field screening instrument.
(e) Surface waters. If visual observations or VOC field screening instrument readings indicate that a release may have impacted surface water then the PRP shall immediately take measures to abate any continuing release to surface water and remove to the extent possible any product in the water.
403 Investigation and Soil Removal Report

Within 30 days of receipt of laboratory data, or an alternate timeframe approved in writing by the Secretary a PRP shall provide the Secretary a report that contains the following:

(1) Site description, in accordance with § 35-305(b)(5);
(2) Property history, in accordance with § 35-305(b)(7);
(3) Results of contaminated environmental media characterization, in accordance with § 35-305(b)(11);
(4) Maps, in accordance with § 35-305(b)(13)(A) and 35-305(b)(13)(B).;
(5) Data presentation, in accordance with § 35-305(b)(15);
(6) Conclusions and recommendations, in accordance with § 35-305(b)(18);
(7) Photographic documentation in accordance with § 35-305(b)(21)(B);
(8) Copies of laboratory reports, in accordance with § 35-305(b)(21)(D);
(9) Waste disposal documentation, in accordance with § 35-505(5)(C) and 35-507(b)(14); and
(10) Recommendations for closure or additional release characterization.
404 Response to Report

The Secretary shall respond, in writing, to the investigation and reporting required by this section, as follows:

(1) No further work is required;
(2) An additional site investigation in accordance with § 35-405 is necessary;
(3) A site investigation in accordance with Subchapter 3 or corrective action in accordance with Subchapter 5 is required; or
(4) The report is incomplete and will be returned to the PRP and the environmental professional for revision and resubmission.
405 Additional Site Investigation

If required by the Secretary under § 35-404(2) of this section, a PRP shall prepare an additional site investigation work plan and provide it to the Secretary for review and approval prior to implementation. At a minimum, the additional site investigation work plan shall include:

(1) Soil borings and soil samples.
(A) Soil borings shall be advanced to below the water table within the former UST location or AST release area and in the downgradient direction.
(B) A representative number of borings shall be advanced to define the extent of the impact to soil.
(C) Soil samples shall be collected for analysis. Samples shall be collected for laboratory analysis from the water table if non-detect, or from the location of the highest VOC field screening instrument result. If the water table is not encountered and soil contamination above 10 ppm is present, the boring shall be advanced 5 feet beyond the depth of non-detect readings as measured with a VOC field screening instrument, or until refusal.
(2) Installation of monitoring wells. If VOC field instrument screening results exceed 10 ppmv in any boring at or above the water table, the PRP shall install monitoring wells sufficient to determine the extent of impacts to groundwater and groundwater flow direction. Groundwater samples shall be collected for appropriate laboratory analysis.
(3) Surface water and sediment. Representative samples shall be collected for laboratory analysis to determine whether there are exceedances of environmental media standards in surface water and sediment.
406 Additional Site Investigation Work Plan; Approval and Implementation
(a) Final determination on additional site investigation work plan. The Secretary shall only approve an additional site investigation work plan if the work plan is designed to adequately characterize the degree and extent of the release and provide information sufficient to evaluate the impact of the release on any sensitive receptor. The Secretary's final decision under this section shall be made in writing.
(b) Implementation of additional site investigation. Upon approval, a PRP shall implement the approved additional site investigation work plan within 30 days of the date of approval or an alternate timeframe approved by the Secretary. The work plan shall be implemented under the supervision of an environmental professional.
407 Additional Site Investigation Report Submission and Review
(a) An additional site investigation report shall be submitted within 90 days of receipt of laboratory data or in accordance with an alternate schedule approved by the Secretary. The additional site investigation report shall include the components of a site investigation report, as required by § 35-305, and that were approved in the additional site investigation work plan.
(b) Upon review of the additional site investigation report, the Secretary shall, in writing, notify the PRP that:
(1) The additional site investigation has adequately defined the scope and extent of contamination and risks to sensitive receptors have been appropriately managed. The site will be closed in accordance with Subchapter 7;
(2) The additional site investigation has not adequately defined the scope and extent of contamination and the PRP is required to investigate the site in accordance with Subchapter 3;
(3) The additional site investigation report is inadequate and will be returned to the PRP and the environmental professional for revisions; or
(4) The additional site investigation has adequately defined the scope and extent of contamination but risks to sensitive receptors have not been appropriately managed. The PRP shall develop a corrective action plan in accordance with Subchapter 5.
SUBCHAPTER 5 RESPONSE ACTIONS; RELEASES OF HEATING FUELS
501 Applicability

This subchapter applies to the release of heating fuel from underground storage tanks or aboveground storage tanks used for storage of heating fuel. At the Secretary's discretion, responses to releases of heating fuel may be managed under Subchapter 3 (site investigation) or Subchapter 6 (corrective action) of this rule.

502 Initial Release Investigation
(a) Soil removal. Following approval from the Secretary, a PRP may remove impacted soil in the area where a release of hearing oil occurred. Removal shall occur until:
(1) VOC field screening instrument readings are below 10 ppmv, or
(2) the water table or bedrock is encountered, or
(3) a predetermined volume as approved by the Secretary is achieved.
(b) Soil treatment or disposal. Soil treatment or disposal shall be approved in writing by the Secretary and performed in accordance with Subchapter 8. A Soil Management Plan shall be required if requested by the Secretary.
(c) Soil analysis. Discrete post excavation soil samples shall be collected for laboratory analysis to document removal of contamination or to characterize soil contamination remaining in place. If removal of all contaminated soil is not possible due to physical constraints, the PRP shall:
(1) Collect and analyze a discrete sample of soil remaining in place from the area(s) determined to be the most contaminated based on VOC field screening instrument results; and
(2) If groundwater is encountered, collect a groundwater sample for laboratory analysis from the excavation area.
(d) Additional site investigation. If contaminated soil excavation is not feasible, additional site investigation in accordance with § 35-505 shall be required as directed by the Secretary. The Secretary shall have discretion to determine the feasibility of excavation of soil for purposes of this provision.
(e) Bedrock. If soil excavation is performed following approval from the Secretary, the excavation shall be extended to the soil bedrock interface to determine if contaminated soil is present unless:
(1) the vertical extent of contaminated soil is delineated and determined to be adequately separated from the bedrock surface;
(2) the water table is encountered; or
(3) excavation to bedrock is physically impossible, a confining soil layer is present, or an alternate remedial approach is approved by the Secretary.
(f) Drinking water. If a water supply well is located within 200 feet of the release, a sample shall be collected from this water supply for appropriate laboratory analysis.
(g) Vapor intrusion. If any building is located within 30 feet of the release, indoor air shall be screened with a VOC field screening instrument.
(h) Surface waters. If visual observations or VOC field screening instrument readings indicate that a release may have impacted surface water, the PRP shall immediately take measures to abate any continuing release to surface water and remove to the extent possible any heating fuel in the surface water.
503 Initial Release Investigation Report
(a) Within 30 days of receipt of laboratory data, or upon an alternate timeframe approved in writing by the Secretary, a PRP shall provide the Secretary a report that contains the following:
(1) Site description, in accordance with § 35-306(b)(5).
(2) Property history, in accordance with § 35-306(b)(7).
(3) Results of contaminated environmental media characterization, in accordance with § 35-306(b)(12).
(4) Maps, in accordance with §§ 35-306(b)(14)(A) and 35-306(b)(14)(B).
(5) Data presentation, in accordance with § 35-306(b)(16).
(6) Conclusions and recommendations, in accordance with § 35-306(b)(19).
(7) Photographic documentation in accordance with § 35-306(b)(21)(C).
(8) Laboratory reports, in accordance with § 35-306(b)(21)(E).
(9) Waste disposal manifests, bill of lading, and weight slips as appropriate.
(10) Recommendations for no further action, additional release characterization, or corrective action, as appropriate.
504 Response to Report
(a) The Secretary shall respond, in writing, to the investigation and reporting required by this section and shall provide written notification to the PRP of one of the following determinations:
(1) No further action is required;
(2) An additional site investigation in accordance with § 35-505 is required;
(3) A site investigation in accordance with Subchapter 3 or corrective action in accordance with Subchapter 6 is required; or
(4) The report is incomplete and will be returned to the PRP for revision and resubmission.
505 Additional Site Investigation
(a) If required by the Secretary under § 35-504 of this subchapter, a PRP shall prepare an additional site investigation work plan and provide it to the Secretary for review and approval prior to implementation.
(b) An additional site investigation work plan shall include:
(1) Soil borings. Soil borings shall be advanced to characterize the degree and extent of petroleum impacts to soil and evaluate risk to groundwater. Soil borings shall be advanced:
(A) within the former UST location or AST release (if this/ these area(s) have not been adequately characterized under § 35-502 ); and
(B) until VOC field screening instrument readings are below 10 ppmv for at least five consecutive feet, or other such depth as is required by the Secretary.
(2) Soil analysis. If required by the Secretary, soil samples shall be collected for laboratory analysis from each boring:
(A) at the water table or the deepest point of the boring if soil screening results from a VOC field instrument are non-detect throughout the soil boring, or
(B) from the location of the highest VOC field instrument reading if contamination is present.
(3) Groundwater monitoring wells. If VOC field screening instrument results exceed 10 ppmv in any boring at or within five feet of the water table, the PRP shall install monitoring wells to determine the extent of impacts to groundwater and groundwater flow direction and shall collect groundwater samples for appropriate laboratory analysis.
(4) Surface water and sediment. If applicable, representative samples shall be collected for laboratory analysis to determine whether there are exceedances of environmental media standards in surface water and sediment.
506 Additional Site Investigation Work Plan; Approval and Implementation
(a) The Secretary shall approve an additional site investigation work plan if the work plan is designed to adequately characterize the degree and extent of the release and provides sufficient information to evaluate the impact of the release on any sensitive receptor. The Secretary's final decision under this section shall be made in writing.
(b) A PRP shall implement the approved additional site investigation work plan within 30 days of the date of the approval or within an alternate timeframe approved by the Secretary. The work plan shall be implemented under the supervision of an environmental professional.
(c) Any deviations to the approved work plan dictated by site conditions during site investigation implementation shall be approved by the Secretary prior to the change.
507 Additional Site Investigation Report Submission and Review
(a) An additional site investigation report shall be submitted within 90 days of receipt of laboratory data or in accordance with an alternate schedule approved by the Secretary. The additional site investigation report shall include the elements of a site investigation report in § 35-306(b) that were approved by the Secretary per § 35-506(a).
(b) Upon review of the additional site investigation report, the Secretary shall, in writing, notify the PRP of one of the following conclusions:
(1) The additional site investigation has adequately defined the degree and extent of contamination and risks to sensitive receptors have been appropriately managed. No further action will be required following proper decommissioning of any monitoring wells or other remedial equipment.
(2) The additional site investigation has not adequately defined the degree and extent of contamination and the PRP is required to conduct additional investigation of the site in accordance with Subchapter 3.
(3) The additional site investigation has adequately defined the degree and extent of contamination but risks to sensitive receptors have not been mitigated, and the PRP shall develop a corrective action plan in accordance with Subchapter 6 of this rule.
(4) The additional site investigation has adequately defined the degree and extent of contamination exceeding applicable environmental media standards and risks to sensitive receptors have been appropriately managed. An institutional control will be required in accordance with Subchapter 9.
(5) The additional site investigation report is inadequate and requires revisions. The Secretary shall identify the inadequacies and a revised report and any additional information shall be submitted within 30 days or an alternate schedule approved by the Secretary.
508 Review and Final Decision of Corrective Action Construction Completion Report
(a) The Secretary shall review the corrective action completion report and determine whether the corrective action conforms to the CAP approved by the Secretary.
(b) If the Secretary concludes that the corrective action undertaken by the PRP fails to implement the approved CAP, the Secretary may require a supplemental corrective action completion report, additional investigation, or additional corrective action at the site.
509 Long Term Monitoring
(a) All sampling points shall be monitored at a frequency defined in the approved CAP. Any adjustment shall be approved by the Secretary in writing.
(b) The long-term monitoring report, including analytical results, shall be submitted to the Secretary no later than 45 days from the receipt of analytical results from the laboratory or within an alternate schedule approved by the Secretary, except in the following circumstances, in which case the results shall be reported immediately:
(1) Drinking water supply laboratory analytical results which report an exceedance of the groundwater enforcement standards shall be submitted verbally within 24 hours and written analytical results shall be provided to the Secretary within five business days.
(2) Indoor air quality laboratory analytical results that report an exceedance of vapor intrusion target indoor air concentrations shall be submitted verbally within 24 hours and written analytical results shall be provided to the Secretary within five business days.
(c) If site conditions have changed such that the monitoring work plan cannot be carried out as originally approved, then the Secretary shall be notified immediately.
(d) The Secretary may modify the number of wells sampled or frequency of sampling based on data collected through the site investigation, through long term monitoring, and the Secretary's understanding of site conditions.
(e) A long-term monitoring report shall include the following:
(1) Updated executive summary. Brief summary of findings, conclusions, and recommendations based upon the data collected during the monitoring event.
(2) An updated CSM in accordance with § 35-302.
(3) Contaminated media characterization in accordance with § 35-305(b)(11).
(4) Updated site maps in accordance with § 35-305(b)(13).
(5) Documentation of the sample location and method in accordance with the consultant's standard operating procedures (SOP). Justification for deviations from the SOPs shall be described.
(6) Any deviations from the approved work plan shall be identified and justified.
(7) A descriptive analysis of how the data gathered supports the CSM, and whether the corrective action objectives continue to be achieved. The discussion must also establish that the data collected are suitable to determine the risk posed by the hazardous materials, the need for further characterization, and the potential remedial actions. Only data that passes Quality Assurance/Quality Control criteria will be acceptable.
(8) All collected data shall be organized in narrative, tabular, and graphical form, including maps and cross sections. Graphs of hazardous material concentration versus time; including results from discontinued monitoring locations. All detected hazardous material concentrations shall be reported. Detection limits shall be provided along with analytical results. Detection limits shall be below the environmental media standards. Hazardous materials that are not detected shall be reported as 'ND'.
(9) NAPL recovery results, when applicable.
(10) Field screening results from contaminated stockpiled soils in tabular format, with a map showing the locations of the screened samples and the stockpile location in reference to other pertinent physical features including buildings, roadways, and surface water bodies.
(11) A description of the current condition of the monitoring network, any maintenance activities conducted since the last monitoring event, and any required maintenance that must be completed with a schedule to complete the work.
(12) Observable changes in site and neighboring property conditions which may affect site management. These changes may include change in property use, change in property occupancy, water supply changes, and construction.
(13) Any observable changes to the property that conflict with any institutional controls developed as part of the response to contamination.
(14) Documentation of the handling of any investigation and remediation derived waste, which shall be dealt with in accordance with § 35-505(5)(c).
(15) A discussion of the findings of the investigation that substantiate the revised CSM, and, specifically, the risk hazardous materials pose to identified receptors, completed exposure pathways, the identification of data gaps, potentially appropriate corrective actions, proposed monitoring frequency, and need for further investigation, additional corrective action, or site closure.
(16) The report shall be signed by an environmental professional and certified in accordance with § 35-104.
510 Non-Hazardous Waste Contaminated Soil
(a) Except as provided in subsection (d) of this section, off site stockpiling of any contaminated soil is prohibited.
(b) On-site treatment; non-hazardous waste petroleum contamination in soil -- polyencapsulation:
(1) Excavated and stockpiled soils shall be completely contained or encapsulated within a polyethylene plastic liner, which shall be a minimum thickness of 6 mils or another containment method determined by the Secretary to be equally protective.
(2) The integrity of the polyethylene liner shall be maintained throughout treatment.
(3) The soils shall remain polyencapsulated on-site until vapor levels are non-detectable (< 1 parts per million by volume (ppmv) headspace) using a field screening instrument, and there is no olfactory or visual evidence of contamination. Aerating the soil pile to accelerate remediation is prohibited.
(4) No additional soil may be added to the existing soil stockpile, unless approved by the Secretary.
(5) Polyencapsulated soils shall be periodically monitored at a frequency defined in an approved corrective action plan to track the rate of biodegradation and to ensure the integrity of the soil pile.
(6) The location of the polyencapsulated soil shall be in an area where:
(A) there are no public water systems or potable water supplies within a minimum 300-foot radius. This limit may need to be extended if water supplies are shown to be hydraulically downgradient;
(B) There are no sensitive environments including a stream, river, lake, pond, state or federally listed threatened or endangered species or habitat, wetland, floodplain, Class I or II groundwater, residence, property boundary, or other similar areas, within 100 feet of the treatment location;
(C) The treatment location is not within zone one or two of a groundwater source protection area;
(7) Public access to the location where polyencapsulated soils are stockpiled shall be prohibited through posting no trespassing and other means;
(8) If the landowner of the property where polyencapsulated soils are stockpiled is different from soil generator, written approval for the soil treatment that also grants access for the Secretary, has been obtained before treatment begins;
(9) The location where polyencapsulated soils are stockpiled shall be depicted on the site map; and
(10) Failure to adequately maintain polyencapsulated soil piles will result in a new release subject to investigation and corrective action.
(11) Thin-spreading. The following requirements shall be met prior to thin-spreading non-hazardous petroleum contaminated soil stockpiles:
(A) Vapor levels are less than 1.0 parts ppmv when measured with a VOC field screening instrument;
(B) Soils contain no olfactory or visual evidence of contamination;
(C) Confirmatory lab samples as required by the approved corrective action plan;
(D) Results of laboratory analysis shall be below SSVs;
(E) There are no public water systems or potable water supplies within a 300-foot radius of the location where soils are thin-spread. This limit may need to be extended if water supplies are shown to be hydraulically downgradient;
(F) There are no sensitive environments including a stream, river, lake, pond, state or federally listed threatened or endangered species or designated or identified habitat, wetland, floodplain, Class I groundwater zone, residence, property boundary, or other similar areas, within 100 feet of the treatment location;
(G) The thin-spread location is not within zone one or two of a groundwater source protection area; and
(H) Thinspreading has been approved by the Secretary.
(c) Additional on-site treatment options for non-hazardous contaminated soil shall be approved by the Secretary.
(d) Off-site treatment; non-hazardous waste petroleum contamination in soil. The off-site treatment of soil under this section shall be preapproved by the Secretary prior to the shipment off-site. The local municipality shall be notified in writing of the polyencapsulated soil. If applicable, local permits have been obtained. In addition to meeting the requirements of subsection (b) of this section, the PRP shall provide the Secretary with the following:
(1) The amount of soil that is to be transported to the off-site location; and
(2) The latitude and longitude of the exact location where the soil was stockpiled.
(e) On-site soil management. Non-hazardous contaminated soil may be managed on the site where the release occurred and within the area of contamination, provided all the following have been demonstrated:
(1) The proposed management area meets the siting criteria of subsection (b)(6) of this section;
(2) Management will occur above the seasonal high water table;
(3) An engineered soil cap shall be installed following the management to eliminate contact risk. The engineered soil cap shall be:
(A) If not covered by an impervious surface, a minimum of 18" thick; or
(B) If covered by an impervious surface, 6" thick of fill or sub-base material under the impervious surface.
(C) Alternate cap thicknesses may be utilized, providing additional institutional controls are placed on the property to ensure protection of human health and the environment, and pre-approval is granted by the Secretary.
(4) The engineered soil cap shall be clearly marked with a material that distinguishes the divide between the non-hazardous contaminated soils and the clean backfill;
(5) Soils managed under this subsection shall be shown not to be a risk to groundwater, by appropriate sampling method.
(6) A draft institutional control plan has been included part of the corrective action plan.
(f) Off-site management.
(1) Non-hazardous contaminated soil may be treated or disposed at the following locations:
(A) An in-state or out of state solid waste disposal facility;
(B) An in-state or out of state treatment facility; or
(C) As provided in § 35-512 for development soils.
(2) Non-hazardous contaminated soil may be temporarily stockpiled at an offsite location providing pre-approval is granted by the Secretary, and the following criteria are met:
(A) Excavated and stockpiled soils shall be completely contained or encapsulated within a polyethylene plastic liner, which shall be a minimum thickness of 6 mils or another containment method determined by the Secretary to be equally protective.
(B) The integrity of the polyethylene liner shall be maintained.
(C) No additional soil may be added to the existing soil stockpile, unless approved by the Secretary.
(D) The location of the poly encapsulated soil shall be in an area where:
(i) there are no public water systems or potable water supplies within a minimum 300-foot radius. This limit may need to be extended if water supplies are shown to be hydraulically downgradient;
(ii) There are no sensitive environments including a stream, river, lake, pond, state or federally listed threatened or endangered species or identified or designated habitat, wetland, floodplain, Class I or II groundwater, residence, property boundary, or other similar areas, within 100 feet of the stockpile location; and
(iii) The stockpile location is not within zone one or two of a groundwater source protection area.
(E) Public access to the location where polyencapsulated soils are stockpiled shall be prohibited through posting no trespassing and other means;
(F) If the landowner of the property where polyencapsulated soils are stockpiled is different from soil generator, written approval for the soil stockpile that also grants access for the Secretary, has been obtained before stockpiling begins;
(G) The location where polyencapsulated soils are stockpiled shall be depicted on the site map;
(H) Failure to adequately maintain polyencapsulated soil piles will result in a new release subject to investigation and corrective action;
(I) Soils may only be temporarily stockpiled for up to 90 days, or under an alternate schedule approved by the Secretary; and
(J) Temporary stockpiling may not occur between December 1 [st ] and April 1 [st. ]
(3) For soils that meet the levels established for urban background in Appendix B of this Rule, those soils may be managed in an area designated as urban within the ANR Atlas.
511 Site Generated Hazardous Wastes
(a) Site generated hazardous waste shall be managed in accordance with the Vermont Hazardous Waste Management Rules unless managed in an area of contamination under the approval of the Secretary.
(b) Contained-in determination. On-site media that contain listed hazardous waste identified in the Vermont Hazardous Waste Management Regulations shall be managed as hazardous waste until the media no longer contains the waste. This may be demonstrated by providing the Secretary with data demonstrating that:
(1) The source of the contamination is known and meets the definition of a listed waste;
(2) The media of concern does not contain hazardous constituents in concentrations that exceed the characteristic hazardous waste concentrations;
(3) The media of concern has been appropriately characterized by representative sampling;
(4) Concentrations of contaminants do not present a threat to human health or the environment at final disposition; and
(5) Concentrations of the listed waste do not exceed federal land disposal restrictions.
(c) Prior to managing hazardous wastes under subsection (b) of this section, the Secretary shall determine that the elements of (b)(1) -- (5) have been met.
512 Development Soils
(a) A person who applies to manage development soils under this section shall have completed a site investigation pursuant to Subchapter 3 of this rule prior to the excavation of the development soils. In addition to the requirements contained in Subchapter 3, a work plan shall be submitted for approval which includes the following:
(1) Soil sample collection methods, which shall consist of one of the following methods:
(A) Discrete sampling methodology in a grid pattern. The sampling grid shall be appropriately scaled in order to cover the entire proposed area of excavation, and sample points shall be co-located in areas of concern;
(B) Application of Incremental Sampling Methodology consistent with the Interstate Technology and Regulatory Council's (ITRC) Incremental Sampling Methodology (February 2012); or
(C) Other soil characterization methods, as approved by the Secretary
(2) If soil is proposed to be disposed of in accordance with § 35-512(b)(3) (receiving site), the number and location of soil samples that will be analyzed using Synthetic Precipitation Leaching Procedure (EPA Method 1312) (SPLP). The number of locations shall be based on the volume of soils planned for management and there shall be minimum one sample for every 200 tons of soil. Samples shall be taken from the soils most likely to leach contaminants and from the most impacted soil locations based on laboratory analysis, field screening, and visual and olfactory evidence.
(b) Disposal of Development Soils. Upon a determination by the Secretary, in writing, that the soils proposed for management are development soils, those soils may be disposed at:
(1) A categorical solid waste facility that is permitted to receive development soils;
(2) A solid waste facility for use as alternate daily cover; or
(3) An approved receiving site that meets the requirements of subsection (c) of this section.
(c) Receiving site.
(1) The receiving site shall meet the siting requirements established in § 35-510(b)(6);
(2) Prior to receiving development soils, a work plan shall be submitted for approval which includes the following:
(A) Soil sample collection methods which shall consist of one of the following methods:
(i) Discrete sampling methodology in a grid pattern. The sampling grid shall be appropriately scaled in order to cover the entire area proposed for deposition of development soils and shall include information regarding seasonal groundwater elevations determined through subsurface characterization; or
(ii) Application of Incremental Sampling Methodology consistent with ITRC Incremental Sampling Methodology (February, 2012) and shall include information regarding seasonal groundwater elevations determined through subsurface characterization.
(B) The address of the proposed receiving site location and the GIS coordinates of the area where the development soils are proposed to be disposed.
(3) The receiving site shall have concentrations of arsenic, lead, and PAH's that are equal to or greater than the concentrations from the site undergoing redevelopment.
(4) Receiving sites that have concentrations of arsenic, lead and PAH's in excess of industrial risk-based standards will be required to conduct a site investigation in accordance with Subchapter 3.
(5) The receiving site has an approved institutional control plan in accordance with § 35-601 that addresses potential direct contact with development soils by the public, including appropriate capping and establishment of land use restrictions.
SUBCHAPTER 6 CORRECTIVE ACTION
601 Applicability

Except as exempted in § 35-602 of this section, a PRP shall initiate corrective action upon a finding by the Secretary that a site investigation has adequately defined the extent of contamination but risks to sensitive receptors have not been appropriately managed.

602 Exemptions
(a) The following are exempt from the requirements of § 35-604, § 35-606, § 35-608, and § 35-610 in this Subchapter:
(1) An emergency response performed pursuant to § 35-102 of this rule.
(2) A response action to address the release of heating fuels pursuant to Subchapter 5 of this rule.
(3) Following approval from the Secretary, removal of petroleum contaminated soils during the closure or replacement of an underground storage tank.
(4) Management of contaminated soils under an approved soil management plan per Section § 35-804 of this rule.
(b) A PRP shall not be required to conduct corrective action in accordance with this Subchapter upon conclusion of a site investigation report that:
(A) there are no exceedances of any applicable Vermont Groundwater Quality Standards (Vermont Groundwater Enforcement Standards or Vermont Action Levels) at drinking water sources, vapor intrusion is not occurring and there are no other impacts that may present a threat to human health or the environment;
(B) groundwater contamination is confined to the same property where the release occurred;
(C) a demonstration that contamination will not migrate at concentrations exceeding standards, given the current data that is available, and concentrations are stable or declining;
(D) the hazardous material release has been addressed through a removal of a limited amount of contaminated material;
(E) the site investigation demonstrates that there are no direct contact threats; and
(F) the Secretary has approved an institutional control plan that meets the requirements of Subchapter 9 of this rule.
603 Objectives of Corrective Action
(a) Corrective actions shall be designed to mitigate the impact of hazardous materials to sensitive receptors to the maximum extent practicable by implementing the following approaches, in order of priority:
(1) Treatment of environmental media to the maximum extent practicable, or to levels where the risk may be managed via engineered controls or institutional controls;
(2) Removal and proper disposal of environmental media impacted by hazardous materials;
(3) Use of engineered and other controls to contain hazardous materials and to mitigate impacts to environmental media and sensitive receptors; and
(4) Use of institutional controls to mitigate exposure to sensitive receptors.
604 Evaluation of Corrective Action Alternatives
(a) Evaluation required. At sites that are not exempt in accordance with § 35-602 or subsection (b) of this section, the PRP shall evaluate corrective action alternatives prior to submitting a corrective action plan to the Secretary. If pilot testing or additional data collection is necessary as part of the evaluation, a work plan shall be submitted for approval by the Secretary.
(b) Exemption. A PRP may submit a corrective action plan without conducting an evaluation of corrective action alternatives pursuant to this section, provided all the following have been demonstrated to the satisfaction of the Secretary:
(1) The site investigation report demonstrates that there are no impacts to drinking water sources and vapor intrusion is not occurring.
(2) For impacted groundwater, the site investigation report demonstrates that the groundwater contamination meets Vermont Groundwater Enforcement Standards at established compliance points or will meet VGES at established compliance points within ten years as established in the Vermont Groundwater Protection Rule and Strategy.
(3) Any direct contact threats to sensitive receptors can be addressed through removal of a limited amount of source material or capping with an engineered barrier.
(4) A corrective action plan will document that the proposed remedy, with respect to the hazardous material in question, has been utilized at other sites and has been demonstrated to be reliable, cost effective, and effective in addressing remediation of the hazardous material.
(5) For development soil receiving sites, all requirements in § 35-805(d) have been met, and a corrective action plan which addresses potential direct contact with development soils by the public, including capping and land use restrictions, has been approved by the Secretary.
(c) Identification of corrective action alternatives. The PRP shall identify corrective action alternatives that will eliminate exposure pathways to sensitive receptors. The number and type of alternatives to be considered shall be determined by taking into account the scope, characteristics, and complexity of the problem being addressed. At each site, at least the following alternatives shall be considered:
(1) An alternative that reduces the toxicity, mobility, or volume of the hazardous materials released to the extent feasible. This alternative shall minimize the need for long term management at the site; and
(2) An alternative that involves little or no treatment, but controls impacts to sensitive receptors through engineered controls, containment, long term monitoring, and institutional controls.
(d) Evaluation of corrective action alternatives (ECAA). For each proposed corrective action alternative, the PRP shall evaluate and document the following:
(1) Overall protection of human health and the environment. Alternatives shall be assessed to determine whether they can adequately protect human health and the environment, by either eliminating, reducing, or controlling exposures to levels established by the corrective action objectives consistent with § 35-603. Overall protection of sensitive receptors shall also assess long-term effectiveness and permanence, short-term effectiveness, and compliance with federal, state, and local laws.
(2) Compliance with legal requirements. Alternatives shall be evaluated to determine whether the PRP can obtain all federal, state, and local permits for the proposed alternative as well as describe how the alternative will meet those regulatory requirements.
(3) Long-term effectiveness and permanence. Alternatives shall be assessed for long-term effectiveness and permanence. Adequacy and reliability of the proposed alternative such as containment systems and institutional controls that are necessary to manage treatment residuals and untreated waste. This factor addresses the uncertainties and risks associated with long term management of the remedy.
(4) Land use restrictions. Alternatives shall identify whether and what type of land use restrictions are required following implementation of the remedy.
(5) Reducing toxicity, mobility, or volume through treatment. The degree to which alternatives reduce toxicity, mobility, or volume shall be assessed, including how treatment is used to address the principal threats posed by the site. Factors that shall be considered include the following:
(A) The treatment or recycling processes the alternatives employ and materials they will treat;
(B) The amount of hazardous materials that will be destroyed, treated, or recycled;
(C) The degree of expected reduction in toxicity, mobility, or volume of the hazardous materials due to treatment or recycling and the specification of which reduction(s) are occurring;
(D) The degree to which rebound of contaminants may occur;
(E) The type and quantity of residual contamination that will remain following treatment, considering the toxicity, mobility, propensity to bioaccumulate, and persistence of such hazardous materials and their constituents; and
(F) The degree to which treatment reduces the inherent hazards posed by principal threats at the site.
(6) Short-term effectiveness. The short-term impacts of alternatives shall be assessed by considering the following:
(A) Short-term risks that might be posed to sensitive receptors during implementation of an alternative;
(B) Potential impacts to workers during corrective action and the effectiveness and reliability of protective measures; and
(C) Potential environmental impacts of the corrective action and the effectiveness and reliability of mitigation measures during implementation.
(7) Implementability. The relative degree of difficulty in implementing the alternatives shall be assessed by considering the following:
(A) Technical feasibility, including technical difficulties and uncertainty associated with construction and operation of a corrective action, the reliability of the technology, ease of undertaking additional corrective actions, and the ability to monitor the corrective action's effectiveness;
(B) Administrative feasibility, including activities needed to coordinate with other offices and agencies and the need to obtain any necessary approvals and permits; and
(C) Availability of services and materials, including the adequate off-site treatment, storage capacity, and disposal capacity and services; the availability of necessary equipment and subcontractors, and any necessary additional resources.
(8) Cost. The types of costs that shall be assessed include the following:
(A) Capital costs;
(B) Annual operation and maintenance (O&M) costs;
(C) Costs to implement land use restrictions; and
(D) Net present value of capital and O&M costs.
(9) Environmental impact and sustainability. Include a discussion of waste generation and disposal requirements, as well as a discussion of methods to implement best management practices to reduce the environmental impact of the proposed remedies in accordance with US EPA guidance or ASTM Standard Guide for Greener Cleanups.
(10) Community acceptance. This assessment includes determining which components of the alternatives interested persons in the community may support, have reservations about, or oppose. The Secretary may require a public comment period and informational meeting on the alternatives or consider community acceptance in the context of public input on the corrective action plan.
(e) Required elements. The PRP shall provide the Secretary with an ECAA report that contains the following:
(1) An executive summary of the corrective action alternatives considered, including a recommended alternative, based on criteria in subsection (d) of this section.
(2) Tabulated results and a narrative discussion of any pilot testing completed during the evaluation.
(3) A proposal for any site-specific background standards that the PRP proposes to apply to the site in accordance with Appendix B of this rule.
(4) A proposal for any waiver that the PRP proposes to apply to the site in accordance with Appendix C of this rule.
(5) A detailed evaluation of the criteria established under subsection (d) of this section for each remedial option selected under subsection (c) of this section.
(6) A proposal for additional pilot testing or data collection to refine the remedial design for the selected remedy.
(7) A detailed justification for the selected remedy.
605 Secretary Evaluation of Corrective Action Alternatives
(a) The Secretary shall evaluate each corrective action alternative presented in the evaluation of corrective action alternative report utilizing the criteria of § 35-604(d).
(b) The Secretary shall provide a written response to the PRP that:
(1) Approves the corrective action alternative recommended in the report;
(2) Approves an alternate alternative that was considered but not recommended;
(3) Requires additional alternatives to be evaluated;
(4) Requires additional analysis, pilot testing, or data collection to support further evaluation of the alternatives reviewed as a part of the report; or
(5) The report is inadequate and will be returned to the PRP and the environmental professional for revisions.
(c) The PRP shall, within 30 days of the Secretary's response or within an alternate schedule approved by the Secretary), provide the Secretary with a response to any comment provided by the Secretary including a revised evaluation of corrective action alternatives or a corrective action plan for the selected alternative.
606 Corrective Action Plan
(a) Except as exempted in § 35-602 of this section, a PRP shall submit a corrective action plan to address impacts or risks to sensitive receptors that are not managed.
(b) A corrective action plan shall include the following:
(1) Executive summary. An executive summary that includes a description of the contamination, a review of the results of the investigation, remediation and remedial objectives, a summary of the alternatives considered, a description of the chosen corrective action technology, a statement of site operations and monitoring activities, and an estimate of the duration of the remedial action.
(2) Site history and updated Conceptual Site Model.
(3) Public notice; parcel map. A list of the persons who will receive notice under § 35 - 607(b)(1), including contact names, addresses, email addresses, and phone numbers. A parcel boundary map shall be included showing all such parcels.
(4) Performance standards, to include the following:
(A) A discussion of how the corrective action achieves the corrective action objectives identified in § 35-603.
(B) A list of environmental media standards that apply to the site.
(C) A map identifying the compliance points that will be used to monitor compliance with the environmental media standards.
(D) A narrative explanation as to why these compliance points were chosen.
(E) A narrative explanation as to how any corrective action will ensure that there are no completed pathways that would result in an impact to a sensitive receptor.
(F) An estimate of the contaminant mass or volume and expected removal rates.
(G) Identify performance standards for demonstrating substantial completion of the corrective action for sites receiving a Certificate of Completion.
(H) Estimated duration of active remediation and transition to long-term monitoring or site closure.
(5) Permits. A list of all local, state, and federal permits required for the project, and the contacts necessary to obtain these permits and a demonstration of compliance with all local, state, and federal rules and regulation.
(6) Remedial construction plan. Any corrective action involving construction of a treatment system, engineered system, including a cap, a containment system, or any other control that requires an engineered design, shall include the following:
(A) Detailed plans and specifications of the corrective action remedial design and related calculations.
(B) Tabulated results and narrative discussion of any additional analysis or pilot testing performed.
(C) A Vermont licensed professional engineer's signature of review of the remedial system design.
(7) Waste management; contaminated soil plan. A discussion of any waste material that will be generated by the corrective action, including a hazardous waste determination. If managing contaminated soil, the plan shall also include a plan for managing contaminated soil in accordance with Subchapter 8 and § 35-611.
(8) Implementation schedule. An implementation schedule that contains milestones for implementing the corrective action and dates for when those milestones will be reached. The schedule shall include proposed deliverables including the CACCR report and initial performance monitoring or operation and maintenance reporting, as applicable.
(9) Corrective action operation and maintenance plan. The plan shall describe the following:
(A) A description of how any engineered solution will be monitored and maintained to ensure that it continues to operate as designed.
(B) A discussion of the performance monitoring and data collection strategy during active remediation.
(C) A description of how any institutional controls will be monitored and maintained.
(D) As requested by the Secretary, a cost estimate for the implementation of the corrective action maintenance plan and a financial responsibility instrument to assure the implementation of the corrective action stewardship plan. Financial assurance under this rule shall be accomplished in the same manner as financial assurance under 40 C.F.R. Part 264 Subpart H.
(E) A discussion of the operation and maintenance of any active remedial option after its construction until it attains the corrective action objectives established in § 35-603.
(F) A discussion of how any treatment system will be deconstructed or decommissioned once remedial objectives have been met.
(10) Institutional control plan. The corrective action plan shall include an institutional control plan in accordance with § 35-901, unless the Secretary determines that no residual contamination remains in exceedance of any applicable environmental media standards.
(11) Long term monitoring plan. Where long term monitoring is the remedy or will be required following the completion of corrective action, a long-term monitoring work plan in accordance with § 35-702 will be required.
(12) Redevelopment and Reuse Plan. If applicable, the corrective action plan shall include the redevelopment and reuse plan for the property following implementation of the corrective action. Changes or modifications to this plan may require an amendment to the corrective action plan to ensure that sensitive receptors are not adversely impacted.
(13) Quality Assurance and Quality Control (QA/QC) Plan. The corrective action plan shall contain the following:
(A) A list of the Standard Operating Procedures (SOPs) appropriate to the technologies being proposed for the corrective action. The SOP's shall be provided to the Secretary upon request.
(B) A Quality Assurance/Quality Control plan. What methods will be employed to ensure the validity and accuracy of the data and technologies implemented.
(14) Cost Estimate.
(A) Applicability. A corrective action plan shall include a cost estimate if State or federal funding will be utilized, if the project is enrolled in the BRELLA program, or if requested by the Secretary.
(B) Contents. A cost estimate shall be broken down by task, materials, labor costs, sub-contractor costs, and equipment costs. Estimates for subcontractors shall also be itemized into labor, materials, and equipment costs when available. The cost estimate shall contain a separate itemized cost estimate for Corrective Action Plan implementation and system operations and maintenance (O&M).
(15) An updated set of maps as per § 35-306(b)(14).
(16) Tabular, time series summaries of contaminant concentrations in environmental media in accordance with § 35-305(b)(16).
(17) Cross-sections of the contaminated zone depicting well or boring depths, soil stratigraphy, recent soil contaminant concentrations, and recent water levels as appropriate to site-specific conditions.
(18) A list of all proposed contractors, sub-contractors, including contacts, addresses, email addresses, and phone numbers.
607 Corrective Action Plan Review; Public Notice; Final Decision
(a) Review of draft corrective action plan. The Secretary shall approve a proposed corrective action plan upon finding:
(1) That the corrective action plan demonstrates that the proposed corrective action meets the criteria of § 35-603 and § 35-606, and that the proposed corrective action either:
(A) ensures that no sensitive receptor will be adversely impacted by the corrective action; or
(B) that the corrective action is an interim measure that addresses a portion of the release and that further corrective action is planned to ensure that no sensitive receptor will be adversely impacted; and
(2) The applicable requirements of 10 V.S.A. chapter 170 (pertaining to public notice) have been satisfied.
(b) Public notice of administratively complete draft corrective action plan.
(1) Upon a determination by the Secretary that the corrective action plan is administratively complete, a PRP shall provide notice of the draft corrective action plan to all property owners impacted by the release and to all impacted adjoining property owners on a form provided by the Secretary.
(2) The applicant shall provide signed certification to the Secretary that all adjoining property owners have been notified of the corrective action plan.
(3) The Secretary will post a copy of the draft corrective action plan electronically on the Environmental Notice Bulletin for public comment in accordance with 10 V.S.A. chapter 170.
(c) The Secretary will approve the draft corrective action plan upon a finding that the requirements of § 35-607(a) have been met. The Secretary shall provide notice, in writing, to the potentially responsible party and other interested parties of the final corrective action plan approval.
(d) Corrective action plan. The corrective action plan shall be implemented within 90 days of the approval or in accordance with a schedule approved by the Secretary.
(e) Amendments to a corrective action plan.
(1) Major amendments. All amendments that necessitate technical review shall be noticed in the same manner as required by subsection (b) of this section.
(2) Minor amendments. All amendments that require a change in a condition or requirement but do not necessitate technical review and are not administrative amendments shall be processed pursuant to 10 V.S.A. § 7715 (Type 4), except the Secretary need not provide notice of an administratively complete plan.
(3) Administrative amendments. All amendments that correct typographical errors, changes the name or mailing address of an individual, or makes other similar changes to a plan that do not require technical review or the imposition of new conditions or requirements shall not require review under 10 V.S.A. chapter 170.
608 Corrective Action Construction Completion Report
(a) A corrective action completion report shall be submitted within 90 days of completing the construction of any remedy, as applicable, or in accordance with the schedule approved in the corrective action plan.
(b) A corrective action completion report shall include the following elements, as applicable:
(1) Corrective Action Objectives.
(2) Description of work performed including preliminary data collection.
(3) Description of remedial system installed.
(4) A description of any field-based minor amendments to the corrective action and a justification for them.
(5) Site plans reflecting post-CAP implementation conditions.
(6) Mechanical system layout and list of major components with serial numbers.
(7) Piping, control, and instrumentation diagrams along with any modifications to the O&M chapters of the corrective action plan for the installed system.
(8) Photo documentation, including:
(A) contamination encountered during the corrective action;
(B) the installed remedy; and
(C) the site before and after implementation of the CAP.
(9) Initial remedial system operation data, including:
(A) Flow rate;
(B) Pressure or vacuum radius of influence;
(C) Contaminant removal rates; and
(D) Treatment system influent and effluent sample results.
(10) Injection program specifications, including:
(A) Reagent mixing data;
(B) Flow rates and pressures;
(C) Volume of injected material;
(D) Amendment distribution; and
(E) Initial post-injection data.
(11) Documentation that the site has been stabilized, physical hazards have been minimized, restored to the restoration plan included in the approved corrective plan;
(12) Recovery or injection well boring logs;
(13) Copies of all federal, state, and local permits;
(14) Waste disposal manifests and bills of lading;
(15) Applicable inspection results including building, zoning, plumbing, and electrical;
(16) Recommendations for additional work; and
(17) A certification that the activities were performed in accordance with the Corrective Action Plan.
609 Review and Final Decision of Corrective Action Construction Completion Report
(a) The Secretary shall review a corrective action completion report and determine whether the corrective action conforms to the CAP approved by the Secretary. The Secretary will respond, in writing, that either:
(1) The corrective action conforms to the CAP;
(2) The corrective action does not conform to the CAP and that additional work is required to bring the corrective action into compliance with the CAP; or
(3) The corrective action is not functioning as designed and additional investigation is required to determine the cause, to develop an effective remedy, or to implement additional corrective action at the site.
610 Corrective Action Performance Monitoring and O&M
(a) In accordance with the schedule approved by Secretary, periodic performance monitoring and O & M reports shall be submitted to the Secretary.
(b) As applicable, performance monitoring or O & M reports shall include a recommendation for:
(1) continued performance monitoring or O & M;
(2) discontinuance of corrective action due to poor system performance;
(3) modifications to the approved corrective action plan; or
(4) cessation of corrective action when the objectives specified in § 35-603 have been met.
(c) The Secretary shall provide a written response to the PRP in response to recommendations outlined in the report.
611 Site Generated Wastes
(a) Unless approved by the Secretary for management in an Area of Contamination, site generated hazardous waste shall be managed in accordance with the Vermont Hazardous Waste Management Rules.
(b) The Secretary may allow for the on-site remediation of a site contaminated with a hazardous material without requiring hazardous waste certification and permitting provided such activity is conducted in accordance with an approved Corrective Action Plan.
(c) Investigation derived wastes shall be managed and disposed as follows:
(1) If a hazardous waste, in accordance with the Vermont Hazardous Waste Management Regulations.
(2) If the waste contains polychlorinated biphenyls (PCBs) in excess of 50 parts per million (ppm), it shall be managed in accordance with the Toxic Substance Control Act (TSCA). Such waste also shall be managed as a hazardous waste in accordance with the Vermont Hazardous Waste Management Regulations (VT01 hazardous waste code). If PCBs are present at concentrations below 50 ppm, the waste may also be subject to management under TSCA.
(3) If the waste does not meet the criteria of subdivisions (c)(1) or (c)(2) of this subsection, the waste shall be disposed of:
(A) in accordance with the Solid Waste Management Rules, or
(B) under a waste management plan approved as a part of the site investigation work plan, provided no investigation derived waste containing a hazardous material above an environmental standard is transported off the site.
(4) Petroleum contaminated purge water from groundwater monitoring wells and equipment decontamination water may be returned to the ground within the area where it was extracted as approved by the Secretary.
(5) Non-petroleum, non-hazardous waste contaminated purge water may be returned to the ground within the area where it was extracted as approved by the Secretary.
SUBCHAPTER 7 LONG TERM MONITORING
701 Applicability

All required long term monitoring shall be performed in accordance with this subchapter. Long term monitoring of environmental media shall be conducted to evaluate the effectiveness of the remedial goals outlined in the corrective action plan and until the site meets the conditions for Subchapter 10 (site closure), or as required by the Secretary.

702 Long Term Monitoring Work Plan
(a) A PRP shall submit an initial long term monitoring work plan within 30 days of receiving Secretary approval of a CAP where long term monitoring is a remedy or will be required following the completion of corrective action. Subsequent long term monitoring work plans may be required as requested by the Secretary.
(b) A long term monitoring workplan shall be approved by the Secretary prior to the initiation of monitoring work.
703 General Requirements for Long Term Monitoring
(a) Monitoring shall be conducted in accordance with an approved CAP, or as approved by the Secretary prior to July 27, 2017 if the site investigation has demonstrated that all requirements presented in § 35-304(b) are met. Any change to the plan shall be approved by the Secretary in writing.
(b) The Secretary shall be notified immediately if a change in site conditions affect the performance of an approved work plan. The Secretary may require revisions to the monitoring work plan based on site condition changes.
704 Reporting
(a) A long-term monitoring report shall be submitted on an annual basis, or on a schedule approved by the Secretary.
(b) Except as provided by subsection (c) of this section, the long-term monitoring report, including analytical results, shall be submitted to the Secretary no later than 45 days from the receipt of analytical results from the laboratory or within an alternate schedule approved by the Secretary.
(c) In the following circumstances, results shall be reported as indicated:
(1) Drinking water supply laboratory analytical results which report an exceedance of the groundwater enforcement standards shall be submitted verbally within 24 hours and written analytical results shall be provided to the Secretary within five business days thereafter.
(2) Indoor air quality laboratory analytical results that report an exceedance of an indoor air standard shall be submitted verbally within 24 hours and written analytical results shall be provided to the Secretary within five business days thereafter.
(d) A long-term monitoring report shall include the following, as applicable:
(1) Updated executive summary. Brief summary of findings, conclusions, and recommendations based upon the data collected during the monitoring event.
(2) An updated CSM in accordance with § 35-303.
(3) Contaminated media characterization in accordance with § 35-306(b)(12).
(4) Updated site maps in accordance with § 35-306(b)(14).
(5) Documentation of the sample location and method in accordance with the consultant's standard operating procedures (SOP). Justification for deviations from the SOPs shall be described.
(6) A discussion of first-time detections of contaminant concentrations or NAPL in any monitoring point. Also, include a discussion of significant changes in concentrations in any monitoring point if applicable.
(7) Any deviations from the approved work plan shall be identified and justified.
(8) A descriptive analysis of how the data gathered supports the CSM, and whether the corrective action or site investigation objectives continue to be achieved. The discussion must also establish that the data collected are suitable to determine the risk posed by the hazardous materials, the need for further characterization, and the potential remedial actions. Only data that passes Quality Assurance/Quality Control criteria will be acceptable.
(9) All collected data shall be organized in narrative, tabular, and graphical form, and shall include all appropriate historical site data. Graphs of hazardous material concentration versus time; including results from discontinued monitoring locations if necessary to support the conclusions in the report. All detected hazardous material concentrations shall be reported. Hazardous materials that are not detected shall be reported as less than the numerical detection limit. Detection limits shall be below the environmental media standards and shall be provided in tabular format with the analytical results. All laboratory data qualifications must be included in tabulated data presentations.
(10) Data used in spreadsheets or models shall be submitted if requested by the Secretary.
(11) NAPL recovery results, when applicable.
(12) Field screening results from contaminated stockpiled soils in tabular format, with a map showing the locations of the screened samples and the stockpile location in reference to other pertinent physical features including buildings, roadways, and surface water bodies.
(13) A description of the current site conditions, condition of the monitoring network, remediation system, soil stockpile, any maintenance activities conducted since the last monitoring event, and any required maintenance that must be completed with a schedule to complete the work.
(14) Observable changes in site and neighboring property conditions which may affect site management. These changes may include change in property use, change in property occupancy, water supply changes, and construction.
(15) Compliance with any institutional controls developed as part of the response to contamination.
(16) Documentation of the handling of any investigation derived waste, which shall be dealt with in accordance with § 35-611(c).
(17) Conclusions and Recommendations. A discussion of the findings of the investigation that substantiate the revised CSM, and, specifically, the risk hazardous materials pose to identified receptors, completed exposure pathways, the identification of data gaps, potentially appropriate corrective actions, proposed monitoring frequency, and need for further investigation, additional corrective action, or site closure.
(18) The report shall be signed by an environmental professional and certified in accordance with § 35-104.
(e) If required by the Secretary, interim data transmittals shall be used to submit results of monitoring events between long term monitoring reports. Interim data transmittals shall include:
(1) Contaminated media characterization in accordance with § 35-306(b)(12);
(2) Updated site maps in accordance with § 35-306(b)(14);
(3) Laboratory analytical reports; and
(4) If applicable;
(A) NAPL recovery results; and
(B) Photographic documentation.
705 Secretary Review of Long Term Monitoring Report
(a) The Secretary shall review the long term monitoring report for completeness and shall provide written notification to the RPP that:
(1) The long term monitoring report demonstrates that the site has met the corrective action objectives and the site can be closed in accordance with Subchapter 10;
(2) Long term monitoring shall continue at the sampling locations and monitoring frequency established in the site investigation or corrective action plan, or at an alternate frequency based on site conditions as approved by the Secretary; or
(3) Additional site investigation or corrective action is required.
SUBCHAPTER 8 CONTAMINATED SOIL
801 Applicability
(a) The following soils containing hazardous materials at concentrations exceeding the applicable Vermont Soil Standards shall be managed in accordance with this section:
(1) Non-hazardous waste contaminated soil.
(2) Development soils.
(3) Petroleum contaminated soils that are exempted from management under VHWMR § 7-203(p).
802 Exemptions
(a) Petroleum contaminated soil that is excavated and then backfilled into a tank grave during an UST closure or replacement are exempt from management under this Subchapter. These soils may require future site investigation or corrective action.
(b) Petroleum contaminated soils excavated during an emergency response or UST closure or replacement are exempt from § 35-803(a) unless required by the Secretary.
803 Non-Hazardous Waste Contaminated Soil
(a) Approval of management. All management of contaminated soil under this Subchapter shall be pre-approved by the Secretary.
(b) VHWMR petroleum-contaminated soil. Petroleum contaminated soils are not hazardous in accordance with the Vermont Hazardous Waste Regulations.
(c) On-site soil management and treatment.
(1) Soil Stockpiling. Non-hazardous waste contaminated soil may be stockpiled on the site where the release occurred in accordance with this section.
(A) Non-hazardous waste, non-petroleum soils may be temporarily stockpiled for up to 90 days. Stockpiling may not occur between December 1 [st ] and April 1 [st, ] unless under an alternate schedule or work plan that is approved by the Secretary. A final offsite disposal and treatment plan and request form shall be submitted and approved by the Secretary.
(B) On-site soil stockpiles shall meet the following criteria:
(i) Soils shall be completely contained or encapsulated within a polyethylene plastic liner, which shall be a minimum thickness of 6 mils or another containment method determined by the Secretary to be at least as effective in isolating the soils from impacting the environment.
(ii) The integrity of the polyethylene liner shall be maintained throughout stockpiling.
(iii) No additional soil may be added to the existing soil stockpile, unless first approved by the Secretary.
(iv) Soils shall be monitored at a frequency approved by the Secretary to ensure the integrity of the encapsulated soil pile.
(v) Unless otherwise approved by the Secretary, the location of the stockpiled soil shall be in an area where:
(I) There are no sources for public water systems or potable water supplies within a minimum 300-foot radius. This limit may need to be extended if water supply sources are shown to be hydraulically downgradient;
(II) There are no sensitive environments including a stream, river, lake, pond, state or federally listed threatened or endangered species or habitat, wetland, floodplain, Class I or II groundwater, residence, property boundary, or other similar areas, within 100 feet of the treatment location;
(III) The location is not within zone one or two of a groundwater source protection area;
(vi) Public access to the location where soils are stockpiled shall be prohibited through posting no trespassing signs and other appropriate means as approved by the Secretary;
(vii) If the landowner of the property where soils are to be stockpiled is different from the soil generator, written approval from the landowner that also grants access to the Secretary, has been obtained before stockpiling begins;
(viii) The location where soils are stockpiled shall be depicted on the site map;
(ix) Failure to adequately maintain soil may require additional investigation and corrective action as a new release as required by the Secretary.
(2) Soil Treatment.
(A) Polyencapsulation. Non-hazardous waste petroleum contaminated soil may be treated onsite by polyencapsulation following approval from the Secretary. Such treatment shall be subject to the following requirements:
(i) The soils shall remain polyencapsulated on-site until vapor levels are non-detectable (less than 1.0 parts per million by volume (ppmv) headspace) using a field screening instrument, and there is no olfactory or visual evidence of contamination.
(ii) Aerating the soil pile to accelerate remediation is prohibited.
(iii) Soils shall be periodically monitored at a frequency approved by the Secretary to track the rate of biodegradation using a VOC field screening instrument and to ensure the integrity of the encapsulated soil pile.
(iv) Amendments shall be added to the soil stockpile only upon approval by the Secretary.
(B) Thin-spreading. Thin-spreading of non-hazardous waste petroleum contaminated soils shall be approved by the Secretary. Such treatment shall be subject to the following requirements:
(i) Vapor levels are less than 1.0 ppmv in discrete soil samples when measured with a VOC field screening instrument;
(ii) Soils contain no olfactory or visual evidence of contamination;
(iii) Confirmatory lab samples as required by the approved corrective action or soil management plan;
(iv) Results of laboratory analysis shall be below Vermont Residential Soil Standards;
(v) Thin-spreading shall be in an area that complies with § 35-803(c)(1)(B)(v).
(3) Additional treatment. Additional on-site treatment options for non-hazardous waste contaminated soil are only allowable following approval from the Secretary.
(4) On-site soil capping. Non-hazardous waste contaminated soil may be capped on the property where the release occurred and within the area of contamination, provided all the following have been demonstrated:
(A) The proposed capping area meets the siting criteria of § 35-803(c)(1)(B)(v).
(B) Capped soils shall be located above the seasonal high-water table.
(C) An engineered soil cap shall be installed to eliminate contact risk. The engineered soil cap shall be:
(i) If not covered by an impervious surface, a minimum of 18" thick; or
(ii) If covered by an impervious surface, 6" thick of fill or sub-base material under the impervious surface.
(iii) Alternate cap thicknesses may be utilized, provided additional institutional controls are placed on the property to ensure protection of human health and the environment, and approval is granted by the Secretary.
(iv) Clearly marked with a material that distinguishes the divide between the non-hazardous contaminated soils and the clean backfill;
(D) Soils managed under this subsection shall be shown not to be a risk to sensitive receptors, by appropriate sampling methodology.
(E) An institutional control plan has been approved by the Secretary.
(d) Off-site soil management and treatment.
(1) Off-site stockpiling or treatment of non-hazardous waste contaminated soil. The off-site stockpiling of soil under this section shall be approved by the Secretary prior to the shipment off-site. In addition to meeting the requirements of § 35-803(c)(1)(B)(v), the following are required:
(A) PRP shall provide the Secretary with the following:
(i) the contaminant concentrations and amount of soil that is to be transported to the off-site location;
(ii) an ANR Atlas generated map including the latitude and longitude of the exact location where the soil will be stockpiled, referenced to the WGS1984 coordinate system (Mercator), in decimal degrees. Minimum acceptable accuracy is plus-or-minus 15 feet; and
(iii) A completed ANR Off-site Soil Treatment form.
(B) The municipality in which the soil will be stockpiled or treated shall be notified in writing of the soil stockpile or treatment location. If applicable, local permits have been obtained. All required local permits must be obtained prior to off-site management, or a demonstration made that no local permits are required.
(2) Off-site disposal. Non-hazardous waste contaminated soil may be treated or disposed at an off-site location. This soil may shipped to one of the following locations following approval by the Secretary:
(A) An in-state or out of state solid waste disposal facility;
(B) An in-state or out of state treatment facility; or
(C) For development soils, a location that meets the requirements of § 35-805(c).
804 Soil Management Plans
(a) Applicability. A soil management plan may be required by the Secretary in the following instances:
(1) When soil management is necessary prior to meeting the objectives of Subchapter 3.
(2) The site is exempt from corrective action in accordance with § 35-602, and a project is being conducted where contaminated soil may be encountered or generated.
(3) The site has received a Site Management Activity Completed designation or Certificate of Completion that includes a land use restriction in a designated area. A project is being conducted in the designated area where residual contamination may be encountered.
(4) A public works or linear construction project is being proposed where contaminated soil may be encountered or generated.
(5) A construction or redevelopment project is being conducted by an impacted third party who is not a PRP under 10 V.S.A. § 6615 and contaminated soil may be encountered.
(6) A construction or redevelopment project is being conducted in an area with historical fill.
(7) When source removal is determined to be feasible during a UST removal.
(b) Plan content requirements. A soil management plan shall include the following:
(1) Description of project.
(2) Goals and objectives.
(3) Description of contamination (source, type, volume, area) to be encountered during the project.
(4) A discussion of any waste material that will be generated by the project
(5) A plan for managing contaminated soil in accordance with § 35-803.
(6) Excavation oversight and soil stockpile inspection frequency.
(7) Project schedule.
(8) Description of how the site will be restored upon project completion.
(9) An updated set of maps per § 35-306(b)(14) or as otherwise directed by the Secretary.
(10) List of contractors and contact information.
(c) Plan approval. A soil management plan shall be approved by the Secretary prior to implementation. The Secretary shall only approve, in writing, a soil management plan upon finding:
(1) The degree and extent of contaminated soil, in the area requiring excavation for proper treatment or disposal, has been delineated in a pre-characterization or site investigation report and has been determined to be non-hazardous. The precharacterization report shall include the elements as outlined in § 35-306(b), or as directed by the Secretary. Additional site investigation and corrective action may be required.
(2) The planned construction or redevelopment project/ activity will not worsen any existing contamination on the site, or cause impacts to receptors.
(d) Certification of completion. Following implementation of the soil management plan the PRP shall, within 90 days of completion, provide documentation to the Secretary demonstrating that the work has been completed in accordance with § 35-804(b). If soils were transported offsite, the PRP shall also provide disposal documentation including waste manifest and bill of lading.
805 Development Soils
(a) Applicability. Soils exhibiting concentrations of contaminants limited to lead, arsenic, and/or PAHs in exceedance of Vermont Soil Standards may be managed in accordance with this section upon approval by the Secretary.
(b) Sampling work plan; content requirements. A person who proposes to manage development soils shall develop and submit a sampling work plan that includes the following:
(1) Soil sample collection methods shall consist of one of the following:
(A) Discrete sampling methodology in a grid pattern, which shall be appropriately scaled in order to cover the entire proposed area of excavation, and sample points shall be co-located in areas of concern;
(B) Application of Incremental Sampling Methodology consistent with the Interstate Technology and Regulatory Council's (ITRC) Incremental Sampling Methodology; or
(C) Other soil characterization methods, as approved by the Secretary.
(2) If soil is proposed to be disposed of in accordance with § 35-805(d), the number and location of soil samples that will be analyzed using Synthetic Precipitation Leaching Procedure (EPA Method 1312) (SPLP) to determine if there is a potential for contaminants to impact groundwater. The number of locations shall be based on the volume of soils planned for management and there shall be minimum one sample for every 200 tons of soil, or as approved by the Secretary. Samples shall be taken from the soils most likely to leach contaminants and from the most impacted soil locations based on laboratory analysis, field screening, and visual and olfactory evidence.
(c) Disposal of development soils. Upon approval by the Secretary, these soils may be disposed at:
(1) A categorical solid waste facility that is permitted to receive development soils;
(2) A solid waste facility for use as alternate daily cover; or
(3) An approved receiving site that meets the requirements of subsection (d) of this section.
(d) Receiving site.
(1) Work plan. Prior to receiving development soils, a work plan for sampling of the receiving site shall be submitted for approval which includes the following:
(A) Soil sample collection methods which shall consist of one of the following methods:
(i) Discrete sampling methodology in a grid pattern. The sampling grid shall be appropriately scaled in order to cover the entire area proposed for deposition of development soils and shall include information regarding seasonal groundwater elevations determined through subsurface characterization; or
(ii) Application of Incremental Sampling Methodology consistent with ITRC Incremental Sampling Methodology and shall include information regarding seasonal groundwater elevations determined through subsurface characterization.
(B) The address of the proposed receiving site location and the GIS coordinates of the area where the development soils are proposed to be disposed.
(2) General requirements. The following shall apply to management of development soils at a receiving site:
(A) A receiving site shall meet the siting requirements established in § 35-803(c)(1)(B)(v).
(B) The receiving site shall have concentrations of arsenic, lead, and PAHs that are equal to or greater than the concentrations of the development soils proposed to be received.
(C) Receiving sites that have concentrations of hazardous materials in exceedance of residential soil standards will be required to conduct a site investigation in accordance with Subchapter 3.
(D) The receiving site has an approved institutional control plan in accordance with § 35-901 that addresses potential direct contact with development soils by the public, including appropriate capping and establishment of land use restrictions.

Appendix A Environmental Media Standards

(see notes at end of table)

EPA Regional Screening Levels (TR=1E-06, HQ=1.0)

Vermont Screening Levels (TR=1E-06, HQ=1.0)

VT DEC Background Soil Concentrations

Analyte

CAS Number

Resident Soil (mg/kg)

Industrial Soil (mg/kg)

Resident Soil (mg/kg)

Rural (mg/kg)

Urban (mg/kg)

Acephate

30560-19-1

62

260

Acetaldehyde

75-07-0

11

49

Acetochlor

34256-82-1

16,000

1,270

Acetone

67-64-1

670,000

39,900

Acetone Cyanohydrin

75-86-5

2,800,000

12,000,000

Acetonitrile

75-05-8

810

3,400

Acetophenone

98-86-2

7,800

120,000

Acetylaminofluorene, 2-

53-96-3

0.14

0.6

Acrolein

107-02-8

0.14

0.6

Acrylamide

79-06-1

0.24

4.6

Acrylic Acid

79-10-7

99

420

Acrylonitrile

107-13-1

0.25

1.1

Adiponitrile

111-69-3

8,500,000

36,000,000

Alachlor

15972-60-8

9.7

41

Aldicarb

116-06-3

63

820

Aldicarb Sulfone

1646-88-4

63

820

Aldrin

309-00-2

0.18

0.0202

Allyl Alcohol

107-18-6

3.5

15

Allyl Chloride

107-05-1

0.72

3.2

Aluminum

7429-90-5

1,100,000

75,600

Aluminum Phosphide

20859-73-8

31

470

Ametryn

834-12-8

570

7,400

Aminobiphenyl, 4-

92-67-1

0.026

0.11

Aminophenol, m-

591-27-5

5,100

66,000

Aminophenol, p-

123-30-8

1,300

16,000

Amitraz

33089-61-1

160

2,100

Ammonium Sulfamate

7773-06-0

16,000

230,000

Amyl Alcohol, tert-

75-85-4

82

340

Aniline

62-53-3

95

400

Anthraquinone, 9,10-

84-65-1

14

57

Antimony (metallic)

7440-36-0

470

27.1

Antimony Pentoxide

1314-60-9

39

580

Antimony Tetroxide

1332-81-6

31

470

Antimony Trioxide

1309-64-4

280,000

1,200,000

Arsenic, Inorganic

7440-38-2

16

Arsine

7784-42-1

0.27

4.1

Asulam

3337-71-1

3,200

41,000

Atrazine

1912-24-9

2.4

10

Auramine

492-80-8

0.62

2.6

Avermectin B1

65195-55-3

25

330

Azinphos-methyl

86-50-0

190

2500

Azobenzene

103-33-3

5.6

26

Azodicarbonamide

123-77-3

8,600

40,000

Barium

7440-39-3

220,000

11,700

Barium Chromate

10294-40-3

0.3

6.2

Benfluralin

1861-40-1

23,000

350,000

Benomyl

17804-35-2

41,000

121

Bensulfuron-methyl

83055-99-6

13,000

160,000

Bentazon

25057-89-0

1,900

25,000

Benzaldehyde

100-52-7

170

820

Benzene

71-43-2

5.1

0.442

Benzenediamine-2-methyl sulfate, 1,4-

6369-59-1

5.4

23

Benzenethiol

108-98-5

78

1200

Benzidine

92-87-5

0.00053

0.01

Benzoic Acid

65-85-0

250,000

3,300,000

Benzotrichloride

98-07-7

0.053

0.25

Benzyl Alcohol

100-51-6

6,300

82,000

Benzyl Chloride

100-44-7

1.1

4.8

Beryllium and compounds

7440-41-7

2,300

36.0

Bifenox

42576-02-3

570

7,400

Biphenthrin

82657-04-3

950

12,000

Biphenyl, 1,1'-

92-52-4

47

200

Bis(2-chloro-1-methylethyl) ether

108-60-1

47,000

2,920

Bis(2-chloroethoxy)methane

111-91-1

190

2500

Bis(2-chloroethyl)ether

111-44-4

0.23

1

Bis(chioromethyl)ether

542-88-1

0.000083

0.00036

Bisphenol A

80-05-7

3,200

41,000

Boron And Borates Only

7440-42-8

230,000

15,300

Boron Trichloride

10294-34-5

160,000

2,300,000

Boron Trifluoride

7637-07-2

3,100

47,000

Bromate

15541-45-4

4.7

0.559

Bromo-2-chloroethane, 1-

107-04-0

0.026

0.11

Bromobenzene

108-86-1

290

1,800

Bromochloromethane

74-97-5

630

129

Bromodichloromethane

75-27-4

0.29

1.3

Bromoform

75-25-2

19

86

Bromomethane

74-83-9

6.8

30

Bromophos

2104-96-3

390

5,800

Bromoxynil

1689-84-5

16,000

2.81

Bromoxynil Octanoate

1689-99-2

1,600

23,000

Butadiene, 1,3-

106-99-0

0.058

0.26

Butanol, N-

71-36-3

7,800

120,000

Butyl alcohol, sec-

78-92-2

130,000

1,500,000

Butylate

2008-41-5

3,900

58,000

Butylated hydroxyanisole

25013-16-5

2,700

11,000

Butylated hydroxytoluene

128-37-0

150

640

Butylbenzene, n-

104-51-8

3,900

58,000

Butylbenzene, sec-

135-98-8

7,800

120,000

Butylbenzene, tert-

98-06-6

7,800

120,000

Cacodylic Acid

75-60-5

1,300

16,000

Cadmium (Diet)

7440-43-9

980

7.15

Calcium Chromate

13765-19-0

0.3

6.2

Caprolactam

105-60-2

31,000

400,000

Captafol

2425-06-1

3.6

15

Captan

133-06-2

240

1000

Carbaryl

63-25-2

82,000

331

Carbofuran

1563-66-2

320

4,100

Carbon Disulfide

75-15-0

770

3,500

Carbon Tetrachloride

56-23-5

2.9

0.247

Carbonyl Sulfide

463-58-1

67

280

Carbosulfan

55285-14-8

630

8,200

Carboxin

5234-68-4

6,300

82,000

Ceric oxide

1306-38-3

1,300,000

5,400,000

Chloral Hydrate

302-17-0

7,800

120,000

Chloramben

133-90-4

950

12,000

Chloranil

118-75-2

1.3

5.7

Chlordane

12789-03-6

1.7

7.7

Chlordecone (Kepone)

143-50-0

0.054

0.23

Chlorfenvinphos

470-90-6

44

570

Chlorimuron, Ethyl-

90982-32-4

1,300

16,000

Chlorine

7782-50-5

0.18

0.78

Chlorine Dioxide

10049-04-4

2,300

34,000

Chlorite (Sodium Salt)

7758-19-2

2,300

35,000

Chloro-1,1-difluoroethane, 1-

75-68-3

54,000

230,000

Chloro-1,3-butadiene, 2-

126-99-8

0.01

0.044

Chloro-2-methylaniline HCl, 4-

3165-93-3

1.2

5

Chloro-2-methylaniline, 4-

95-69-2

5.4

23

Chloroacetaldehyde, 2-

107-20-0

2.6

12

Chloroacetophenone, 2-

532-27-4

43,000

180,000

Chloroaniline, p-

106-47-8

2.7

11

Chlorobenzene

108-90-7

1,300

273

Chlorobenzilate

510-15-6

4.9

21

Chlorobenzoic Acid, p-

74-11-3

1,900

25,000

Chlorobenzotrifluoride, 4-

98-56-6

210

2,500

Chlorobutane, 1-

109-69-3

3,100

47,000

Chlorodifluoromethane

75-45-6

49,000

210,000

Chloroethanol, 2-

107-07-3

1,600

23,000

Chloroform

67-66-3

0.32

1.4

Chloromethane

74-87-3

110

460

Chloromethyl Methyl Ether

107-30-2

0.02

0.089

Chloronitrobenzene, o-

88-73-3

1.8

7.7

Chloronitrobenzene, p-

100-00-5

9

38

Chlorophenol, 2-

95-57-8

390

5,800

Chloropicrin

76-06-2

2

8.2

Chlorothalonil

1897-45-6

180

740

Chlorotoluene, o-

95-49-8

1600

23000

Chlorotoluene, p-

106-43-4

1600

23000

Chlorozotocin

54749-90-5

0.0023

0.0096

Chlorpropham

101-21-3

13,000

160,000

Chlorpyrifos

2921-88-2

63

820

Chlorpyrifos Methyl

5598-13-0

630

8,200

Chlorsulfuron

64902-72-3

3,200

41,000

Chlorthal-dimethyl

1861-32-1

630

8,200

Chlorthiophos

60238-56-4

51

660

Chromium(III), Insoluble Salts

16065-83-1

1,800,000

41,900

Chromium(VI)

18540-29-9

6.3

0.0945

Clofentezine

74115-24-5

820

11,000

Cobalt

7440-48-4

350

22.9

Copper

7440-50-8

3,100

47,000

Cresol, m-

108-39-4

3,200

41,000

Cresol, o-

95-48-7

3,200

41,000

Cresol, p-

106-44-5

6,300

82,000

Cresol, p-chloro-m-

59-50-7

6,300

82,000

Cresols

1319-77-3

6,300

82,000

Crotonaldehyde, trans-

123-73-9

0.37

1.7

Cumene

98-82-8

1,900

9,900

Cupferron

135-20-6

2.5

10

Cyanazine

21725-46-2

0.65

2.7

Cyanides$(/td$)

~Calcium Cyanide

592-01-8

78

1,200

~Copper Cyanide

544-92-3

390

5,800

~Cyanide (CN-)

57-12-5

23

150

~Cyanogen

460-19-5

78

1,200

~Cyanogen Bromide

506-68-3

7,000

110,000

~Cyanogen Chloride

506-77-4

3,900

58,000

~Hydrogen Cyanide

74-90-8

23

150

~Potassium Cyanide

151-50-8

160

2,300

~Potassium Silver Cyanide

506-61-6

390

5,800

~Silver Cyanide

506-64-9

7,800

120,000

~Sodium Cyanide

143-33-9

78

1,200

~Thiocyanates

NA

16

230

~Thiocyanic Acid

463-56-9

16

230

~Zinc Cyanide

557-21-1

3,900

58,000

Cyclohexane

110-82-7

6,500

27,000

Cyclohexane, 1,2,3,4,5-pentabromo-6-chloro-

87-84-3

24

100

Cyclohexanone

108-94-1

28,000

130,000

Cyclohexene

110-83-8

310

3,100

Cyclohexylamine

108-91-8

16,000

230,000

Cyfluthrin

68359-37-5

1,600

21,000

Cyhalothrin

68085-85-8

320

4.100

Cypermethrin

52315-07-8

630

8,200

Cyromazine

66215-27-8

470

6,200

DDD

72-54-8

2.3

9.6

DDE, p,p'-

72-55-9

2

9.3

DDT

50-29-3

1.9

8.5

Dalapon

75-99-0

1,900

25,000

Daminozide

1596-84-5

30

130

Decabromodiphenyl ether, 2,2',3,3',4,4',5,5',6,6'- (BDE-209)

1163-19-5

440

3,300

Demeton

8065-48-3

2.5

33

Di(2-ethylhexyl)adipate

103-23-1

450

1,900

Diallate

2303-16-4

8.9

38

Diazinon

333-41-5

44

570

Dibenzothiophene

132-65-0

780

12,000

Dibromo-3-chloropropane, 1,2-

96-12-8

0.064

0.00327

Dibromobenzene, 1,3-

108-36-1

31

470

Dibromobenzene, 1,4-

106-37-6

780

12,000

Dibromochloromethane

124-48-1

8.3

39

Dibromoethane, 1,2-

106-93-4

0.036

0.16

Dibromomethane (Methylene Bromide)

74-95-3

24

99

Dibutyltin Compounds

NA

19

250

Dicamba

1918-00-9

1,900

25,000

Dichloro-2-butene, 1,4-

764-41-0

0.0021

0.0094

Dichloro-2-butene, cis-1,4-

1476-11-5

0.0074

0.032

Dichloro-2-butene, trans-1,4-

110-57-6

0.0074

0.032

Dichloroacetic Acid

79-43-6

11

46

Dichlorobenzene, 1,2-

95-50-1

1,800

9,300

Dichlorobenzene, 1,4-

106-46-7

2.6

11

Dichlorobenzidine, 3,3'-

91-94-1

1.2

5.1

Dichlorobenzophenone, 4,4'-

90-98-2

570

7,400

Dichlorodifluoromethane

75-71-8

87

370

Dichloroethane, 1,1-

75-34-3

3.6

16

Dichloroethane, 1,2-

107-06-2

2

0.175

Dichloroethylene, 1,1-

75-35-4

230

1,000

Dichloroethylene, 1,2-cis-

156-59-2

2,300

146

Dichloroethylene, 1,2-trans-

156-60-5

23,000

1,460

Dichlorophenol, 2,4-

120-83-2

190

2,500

Dichlorophenoxy Acetic Acid, 2,4-

94-75-7

700

9,600

Dichlorophenoxy)butyric Acid, 4-(2,4-

94-82-6

510

6,600

Dichloropropane, 1,2-

78-87-5

1

4.4

Dichloropropane, 1,3-

142-28-9

1,600

23,000

Dichloropropanol, 2,3-

616-23-9

190

2,500

Dichloropropene, 1,3-

542-75-6

1.8

8.2

Dichlorvos

62-73-7

1.9

7.9

Dicrotophos

141-66-2

6.3

82

Dicyclopentadiene

77-73-6

1.3

5.4

Dieldrin

60-57-1

0.034

0.14

Diethanolamine

111-42-2

130

1,600

Diethylene Glycol Monobutyl Ether

112-34-5

1,900

24,000

Diethylene Glycol Monoethyl Ether

111-90-0

3,800

48,000

Diethylformamide

617-84-5

78

1,200

Diethylstilbestrol

56-53-1

0.0016

0.0066

Difenzoquat

43222-48-6

5,100

66,000

Diflubenzuron

35367-38-5

1,300

16,000

Difluoroethane, 1,1-

75-37-6

48,000

200,000

Dihydrosafrole

94-58-6

9.9

45

Diisopropyl Ether

108-20-3

2,200

9,400

Diisopropyl Methylphosphonate

1445-75-6

6,300

93,000

Dimethipin

55290-64-7

1,300

16,000

Dimethoate

60-51-5

13

160

Dimethoxybenzidine, 3,3'-

119-90-4

0.34

1.4

Dimethyl methylphosphonate

756-79-6

320

1,400

Dimethylamino azobenzene $(p-$)

60-11-7

0.12

0.5

Dimethylaniline HCl, 2,4-

21436-96-4

0.94

4

Dimethylaniline, 2,4-

95-68-1

2.7

11

Dimethylaniline, N,N-

121-69-7

160

2,300

Dimethylbenzidine, 3,3'-

119-93-7

0.049

0.21

Dimethylformamide

68-12-2

2,600

15,000

Dimethylhydrazine, 1,1-

57-14-7

0.057

0.24

Dimethylhydrazine, 1,2-

540-73-8

0.00088

0.0041

Dimethylphenol, 2,4-

105-67-9

1,300

16,000

Dimethylphenol, 2,6-

576-26-1

38

490

Dimethylphenol, 3,4-

95-65-8

63

820

Dimethylvinylchloride

513-37-1

1.1

4.8

Dinitro-o-cresol, 4,6-

534-52-1

5.1

66

Dinitro-o-cyclohexyl Phenol, 4,6-

131-89-5

130

1,600

Dinitrobenzene, 1,2-

528-29-0

6.3

82

Dinitrobenzene, 1,3-

99-65-0

6.3

82

Dinitrobenzene, 1,4-

100-25-4

6.3

82

Dlnitrophenol, 2,4-

51-28-5

130

1,600

Dinitrotoluene Mixture, 2,4/2,6-

NA

0.8

3.4

Dinitrotoluene, 2,4-

121-14-2

1.7

7.4

Dinitrotoluene, 2,6-

606-20-2

0.36

1.5

Dinitrotoluene, 2-Amino-4,6-

35572-78-2

150

2,300

Dinitrotoluene, 4-Amino-2,6-

19406-51-0

150

2,300

Dinitrotoluene, Technical grade

25321-14-6

1.2

5.1

Dinoseb

88-85-7

63

820

Dioxane, 1,4-

123-91-1

24

2.52

Dioxins$(/td$)

~Hexachlorodibenzo-p-dioxin, Mixture

NA

0.0001

0.00047

TCDD, 2,3,7,8-

1746-01-6

0.000022

0.00000233

Diphenamid

957-51-7

1,900

25,000

Diphenyl Sulfone

127-63-9

51

660

Diphenylamine

122-39-4

1,600

21,000

Diphenylhydrazine, 1,2-

122-66-7

0.68

2.9

Diquat

85-00-7

140

1,800

Direct Black 38

1937-37-7

0.076

0.32

Direct Blue 6

2602-46-2

0.073

0.31

Direct Brown 95

16071-86-6

0.081

0.34

Disulfoton

298-04-4

2.5

33

Dithiane, 1,4-

505-29-3

780

12,000

Diuron

330-54-1

130

1,600

Dodine

2439-10-3

250

3,300

EPTC

759-94-4

2,000

29,000

Endosulfan

115-29-7

470

7,000

Endothall

145-73-3

1,300

16,000

Endrin

72-20-8

19

250

Epichlorohydrin

106-89-8

19

82

Epoxybutane, 1,2-

106-88-7

160

670

Ethanol, 2-(2-methoxyethoxy)-

111-77-3

2,500

33,000

Ethephon

16672-87-0

320

4,100

Ethion

563-12-2

32

410

Ethoxyethanol Acetate, 2-

111-15-9

2,600

14,000

Ethoxyethanol, 2-

110-80-5

5,200

47,000

Ethyl Acetate

141-78-6

620

2,600

Ethyl Acrylate

140-88-5

47

210

Ethyl Chloride (Chloroethane)

75-00-3

14,000

57,000

Ethyl Ether

60-29-7

16,000

230,000

Ethyl Methacrylate

97-63-2

1,800

7,600

Ethyl-p-nitrophenyl Phosphonate

2104-64-5

0.63

8.2

Ethylbenzene

100-41-4

25

2.21

Ethylene Cyanohydrin

109-78-4

4,400

57,000

Ethylene Diamine

107-15-3

7,000

110,000

Ethylene Glycol

107-21-1

130,000

1,600,000

Ethylene Glycol Monobutyl Ether

111-76-2

6,300

82,000

Ethylene Oxide

75-21-8

0.18

0.79

Ethylene Thiourea

96-45-7

5.1

51

Ethyleneimine

151-56-4

0.0027

0.012

Ethylphthalyl Ethyl Glycolate

84-72-0

190,000

2,500,000

Fenamiphos

22224-92-6

16

210

Fenpropathrin

39515-41-8

1,600

21,000

Fenvalerate

51630-58-1

1,600

21,000

Fluometuron

2164-17-2

820

11,000

Fluoride

16984-48-8

3,100

47,000

Fluorine (Soluble Fluoride)

7782-41-4

4,700

70,000

Fluridone

59756-60-4

5,100

66,000

Flurprimidol

56425-91-3

1,300

16,000

Flusilazole

85509-19-9

44

570

Flutolanil

66332-96-5

3,800

49,000

Fluvalinate

69409-94-5

630

8,200

Folpet

133-07-3

160

660

Fomesafen

72178-02-0

2.9

12

Fonofos

944-22-9

130

1,600

Formaldehyde

50-00-0

17

73

Formic Acid

64-18-6

29

120

Fosetyl-AL

39148-24-8

190,000

2,500,000

Furans$(/td$)

~Dibenzofuran

132-64-9

73

1,000

~Furan

110-00-9

73

1,000

~Tetrahydrofuran

109-99-9

18,000

94,000

Furazolidone

67-45-8

0.14

0.6

Furfural

98-01-1

210

2,600

Furium

531-82-8

0.36

1.5

Furmecyclox

60568-05-0

18

77

Glufosinate, Ammonium

77182-82-2

25

330

Glutaraldehyde

111-30-8

110,000

480,000

Glycidyl

765-34-4

23

210

Glyphosate

1071-83-6

6,300

82,000

Guanidine

113-00-8

780

12,000

Guanidine Chloride

50-01-1

1,300

16,000

Haloxyfop, Methyl

69806-40-2

3.2

41

Heptachlor

76-44-8

0.13

0.63

Heptachlor Epoxide

1024-57-3

0.07

0.33

Hexabromobenzene

87-82-1

160

2,300

Hexabromodiphenyl ether, 2,2',4,4',5,5'- (BDE-153)

68631-49-2

13

160

Hexachlorobenzene

118-74-1

0.96

0.0918

Hexachlorobutadiene

87-68-3

1.2

5.3

Hexachlorocyclohexane, Alpha-

319-84-6

0.086

0.36

Hexachlorocyclohexane, Beta-

319-85-7

0.3

1.3

Hexachlorocyclohexane, Gamma- (Lindane)

58-89-9

0.57

2.5

Hexachlorocyclohexane, Technical

608-73-1

0.3

1.3

Hexachlorocyclopentadiene

77-47-4

1.8

7.5

Hexachloroethane

67-72-1

1.8

8

Hexachlorophene

70-30-4

19

250

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)

121-82-4

28

3.49

Hexamethylene Diisocyanate, 1,6-

822-06-0

3.1

13

Hexamethylphosphoramide

680-31-9

25

330

Hexane, N-

110-54-3

610

2,500

Hexanedioic Acid

124-04-9

130,000

1,600,000

Hexanone, 2-

591-78-6

200

1,300

Hexazinone

51235-04-2

2,100

27,000

Hexythiazox

78587-05-0

1,600

21,000

Hydramethylnon

67485-29-4

19

250

Hydrazine

302-01-2

0.23

1.1

Hydrazine Sulfate

10034-93-2

0.23

1.1

Hydrogen Chloride

7647-01-0

28,000,000

120,000,000

Hydrogen Fluoride

7664-39-3

3,100

47,000

Hydrogen Sulfide

7783-06-4

2,800,000

12,000,000

Hydroquinone

123-31-9

9

38

Imazalil

35554-44-0

820

11,000

Imazaquin

81335-37-7

16,000

210,000

Imazethapyr

81335-77-5

16,000

210,000

Iodine

7553-56-2

780

12,000

Iprodione

36734-19-7

2,500

33,000

Iron

7439-89-6

820,000

53,500

Isobutyl Alcohol

78-83-1

23,000

350,000

Isophorone

78-59-1

570

2,400

Isopropalin

33820-53-0

1,200

18,000

Isopropanol

67-63-0

5,600

24,000

Isopropyl Methyl Phosphonic Acid

1832-54-8

6,300

82,000

Isoxaben

82558-50-7

3,200

41,000

JP-7

NA

430,000,000

1,800,000,000

Lactofen

77501-63-4

130

1,600

Lead Compounds$(/td$)

~Lead Chromate

7758-97-6

0.3

6.2

~Lead Phosphate

7446-27-7

82

380

~Lead acetate

301-04-2

64

270

~Lead and Compounds

7439-92-1

400

800

41

111

~Lead subacetate

1335-32-6

64

270

~Tetraethyl Lead

78-00-2

0.0078

0.12

Lewisite

541-25-3

0.39

5.8

Linuron

330-55-2

130

1,600

Lithium

7439-93-2

160

2,300

MCPA

94-74-6

32

410

MCPB

94-81-5

630

8,200

MCPP

93-65-2

63

820

Malathion

121-75-5

1,300

16,000

Maleic Anhydride

108-31-6

6,300

80,000

Maleic Hydrazide

123-33-1

32,000

410,000

Malononitrile

109-77-3

6.3

82

Mancozeb

8018-01-7

1,900

25,000

Maneb

12427-38-2

320

4,100

Manganese (Non-diet)

7439-96-5

26,000

1,170

Mephosfolan

950-10-7

5.7

74

Mepiquat Chloride

24307-26-4

1,900

25,000

Mercury Compounds$(/td$)

~Mercuric Chloride (and other Mercury salts)

7487-94-7

23

350

Mercury (elemental)

7439-97-6

46

10.9

~Methyl Mercury

22967-92-6

7.8

120

~Phenylmercuric Acetate

62-38-4

5.1

66

Merphos

150-50-5

2.3

35

Merphos Oxide

78-48-8

1.9

25

Metalaxyl

57837-19-1

3,800

49,000

Methacrylonitrile

126-98-7

7.5

100

Methamidophos

10265-92-6

3.2

41

Methanol

67-56-1

120,000

1,200,000

Methidathion

950-37-8

63

820

Methomyl

16752-77-5

1,600

21,000

Methoxy-5-nitroaniline, 2-

99-59-2

11

47

Methoxychlor

72-43-5

320

4,100

Methoxyethanol Acetate, 2-

110-49-6

110

510

Methoxyethanol, 2-

109-86-4

330

3,500

Methyl Acetate

79-20-9

78,000

1,200,000

Methyl Acrylate

96-33-3

150

610

Methyl Ethyl Ketone (2-Butanone)

78-93-3

190,000

26,000

Methyl Hydrazine

60-34-4

0.14

0.62

Methyl Isobutyl Ketone (4-methyl-2-pentanone)

108-10-1

33,000

140,000

Methyl Isocyanate

624-83-9

4.6

19

Methyl Methacrylate

80-62-6

4,400

19,000

Methyl Parathion

298-00-0

16

210

Methyl Phosphonic Acid

993-13-5

3,800

49,000

Methyl Styrene (Mixed Isomers)

25013-15-4

320

2,600

Methyl methanesulfonate

66-27-3

5.5

23

Methyl tert-Butyl Ether (MTBE)

1634-04-4

47

210

Methyl-1,4-benzenediamine dihydrochloride, 2-

615-45-2

19

250

Methyl-5-Nitroaniline, 2-

99-55-8

60

260

Methyl-N-nitro-N-nitrosoguanidine, N-

70-25-7

0.065

0.28

Methylaniline Hydrochloride, 2-

636-21-5

4.2

18

Methylarsonic acid

124-58-3

630

8,200

Methylbenzene,1-4-diamine monohydrochloride, 2-

74612-12-7

13

160

Methylbenzene-1,4-diamine sulfate, 2-

615-50-9

5.4

23

Methylcholanthrene, 3-

56-49-5

0.0055

0.1

Methylene Chloride

75-09-2

57

1,000

Methylene-bis(2-chioroaniline), 4,4'-

101-14-4

1.2

23

Methylene-bis(N,N-dimethyl) Aniline, 4,4'-

101-61-1

12

50

Methylenebisbenzenamine, 4,4'-

101-77-9

0.34

1.4

Methylenediphenyl Diisocyanate

101-68-8

850,000

3,600,000

Methylstyrene, Alpha-

98-83-9

5,500

82,000

Metolachlor

51218-45-2

9,500

120,000

Metribuzin

21087-64-9

1,600

21,000

Metsulfuron-methyl

74223-64-6

16,000

210,000

Mineral oils

8012-95-1

230,000

3,500,000

Mirex

2385-85-5

0.036

0.17

Molinate

2212-67-1

130

1,600

Molybdenum

7439-98-7

5,800

382

Monochloramine

10599-90-3

7,800

120,000

Monomethylaniline

100-61-8

130

1,600

Myclobutanil

88671-89-0

1,600

21,000

N,N'-Diphenyl-1,4-benzenediamine

74-31-7

19

250

Naled

300-76-5

160

2,300

Naphtha, High Flash Aromatic (HFAN)

64742-95-6

2,300

35,000

Naphthylamine, 2-

91-59-8

0.3

1.3

Napropamide

15299-99-7

6,300

82,000

Nickel Acetate

373-02-4

670

8,100

Nickel Carbonate

3333-67-3

670

8,100

Nickel Carbonyl

13463-39-3

820

11,000

Nickel Hydroxide

12054-48-7

820

11,000

Nickel Oxide

1313-99-1

840

12,000

Nickel Refinery Dust

NA

820

11,000

Nickel Soluble Salts

7440-02-0

22,000

980

Nickel Subsulfide

12035-72-2

0.41

1.9

Nickelocene

1271-28-9

670

8,100

Nitrate

14797-55-8

130,000

1,900,000

Nitrite

14797-65-0

7,800

120,000

Nitroaniline, 2-

88-74-4

630

8,000

Nitroaniline, 4-

100-01-6

27

110

Nitrobenzene

98-95-3

5.1

22

Nitrocellulose

9004-70-0

190,000,000

2,500,000,000

Nitrofurantoin

67-20-9

4,400

57,000

Nitrofurazone

59-87-0

0.42

1.8

Nitroglycerin

55-63-0

6.3

82

Nitroguanidine

556-88-7

6,300

82,000

Nitromethane

75-52-5

5.4

24

Nitropropane, 2-

79-46-9

0.014

0.06

Nitroso-N-ethylurea, N-

759-73-9

0.0045

0.085

Nitroso-N-methylurea, N-

684-93-5

0.001

0.019

Nitroso-di-N-butylamine, N-

924-16-3

0.099

0.46

Nitroso-di-N-propylamine, N-

621-64-7

0.078

0.33

Nitrosodiethanolamine, N-

1116-54-7

0.19

0.82

Nitrosodiethylamine, N-

55-18-5

0.00081

0.015

Nitrosodimethylamine, N-

62-75-9

0.002

0.034

Nitrosodiphenylamine, N-

86-30-6

110

470

Nitrosomethylethylamine, N-

10595-95-6

0.02

0.091

Nitrosomorpholine $(N-$)

59-89-2

0.081

0.34

Nitrosopiperidine $(N-$)

100-75-4

0.058

0.24

Nitrosopyrrolidine, N-

930-55-2

0.26

1.1

Nitrotoluene, m-

99-08-1

6.3

82

Nitrotoluene, o-

88-72-2

3.2

15

Nitrotoluene, p-

99-99-0

34

140

Nonane, n-

111-84-2

11

72

Norflurazon

27314-13-2

2,500

33,000

Octabromodiphenyl Ether

32536-52-0

190

2500

Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)

2691-41-0

57,000

3,860

Octamethylpyrophosphoramide

152-16-9

130

1,600

Oryzalin

19044-88-3

3,200

41,000

Oxadiazon

19666-30-9

320

4,100

Oxamyl

23135-22-0

1,600

21,000

Oxyfluorfen

42874-03-3

190

2,500

Paclobutrazol

76738-62-0

820

11,000

Paraquat Dichloride

1910-42-5

280

3,700

Parathion

56-38-2

380

4,900

Pebulate

1114-71-2

3,900

58,000

Pendimethalin

40487-42-1

2,500

33,000

Pentabromodiphenyl Ether

32534-81-9

160

2,300

Pentabromodiphenyl ether, 2,2',4,4',5- (BDE-99)

60348-60-9

6.3

82

Pentachiorobenzene

608-93-5

63

930

Pentachloroethane

76-01-7

7.7

36

Pentachloronitrobenzene

82-68-8

2.7

13

Pentachlorophenol

87-86-5

4

0.504

Pentaerythritol tetranitrate (PETN)

78-11-5

570

127

Pentane, n-

109-66-0

810

3,400

Perchlorates$(/td$)

~Ammonium Perchlorate

7790-98-9

55

820

~Lithium Perchlorate

7791-03-9

55

820

Perchlorate and Perchlorate Salts

14797-73-0

820

53.5

~Potassium Perchlorate

7778-74-7

55

820

~Sodium Perchlorate

7601-89-0

55

820

Perfluorobutane Sulfonate

375-73-5

1,600

23,000

Perfluorooctanic Acid

335-67-1

0.30

Permethrin

52645-53-1

3,200

41,000

Phenacetin

62-44-2

250

1,000

Phenmedipham

13684-63-4

16,000

210,000

Phenol

108-95-2

19,000

250,000

Phenol, 2-(1-methylethoxy)- Methylcarbamate, (Baygon, Propoxur)

114-26-1

3,300

82.2

Phenothiazine

92-84-2

32

410

Phenylenediamine, m-

108-45-2

380

4,900

Phenylenediamine, o-

95-54-5

12

49

Phenylenediamine, p-

106-50-3

12,000

160,000

Phenylphenol, 2-

90-43-7

280

1,200

Phorate

298-02-2

13

160

Phosgene

75-44-5

0.31

1.3

Phosmet

732-11-6

1,300

16,000

Phosphates, Inorganic$(/td$)

~Aluminum metaphosphate

13776-88-0

3,800,000

57,000,000

~Ammonium polyphosphate

68333-79-9

3,800,000

57,000,000

~Calcium pyrophosphate

7790-76-3

3,800,000

57,000,000

~Diammonium phosphate

7783-28-0

3,800,000

57,000,000

~Dicalcium phosphate

7757-93-9

3,800,000

57,000,000

~Dimagnesium phosphate

7782-75-4

3,800,000

57,000,000

~Dipotassium phosphate

7758-11-4

3,800,000

57,000,000

~Disodium phosphate

7558-79-4

3,800,000

57,000,000

~Monoaluminum phosphate

13530-50-2

3,800,000

57,000,000

~Monoammonium phosphate

7722-76-1

3,800,000

57,000,000

~Monocalcium phosphate

7758-23-8

3,800,000

57,000,000

~Monomagnesium phosphate

7757-86-0

3,800,000

57,000,000

~Monopotassium phosphate

7778-77-0

3,800,000

57,000,000

~Monosodium phosphate

7558-80-7

3,800,000

57,000,000

~Polyphosphoric acid

8017-16-1

3,800,000

57,000,000

~Potassium tripolyphosphate

13845-36-8

3,800,000

57,000,000

~Sodium acid pyrophosphate

7758-16-9

3,800,000

57,000,000

~Sodium aluminum phosphate (acidic)

7785-88-8

3,800,000

57,000,000

~Sodium aluminum phosphate (anhydrous)

10279-59-1

3,800,000

57,000,000

~Sodium aluminum phosphate (tetrahydrate)

10305-76-7

3,800,000

57,000,000

~Sodium hexametaphosphate

10124-56-8

3,800,000

57,000,000

~Sodium polyphosphate

68915-31-1

3,800,000

57,000,000

~Sodium trimetaphosphate

7785-84-4

3,800,000

57,000,000

~Sodium tripolyphosphate

7758-29-4

3,800,000

57,000,000

~Tetrapotassium phosphate

7320-34-5

3,800,000

57,000,000

~Tetrasodium pyrophosphate

7722-88-5

3,800,000

57,000,000

decahydrogenoctaorthophosphate (dihydrate)

15136-87-5

3,800,000

57,000,000

~Tricalcium phosphate

7758-87-4

3,800,000

57,000,000

~Trimagnesium phosphate

7757-87-1

3,800,000

57,000,000

~Tripotassium phosphate

7778-53-2

3,800,000

57,000,000

~Trisodium phosphate

7601-54-9

3,800,000

57,000,000

Phosphine

7803-51-2

23

350

Phosphoric Acid

7664-38-2

3,000,000

29,000,000

Phosphorus, White

7723-14-0

1.6

23

Phthalates$(/td$)

Bis(2-ethylhexyl)phthalate

117-81-7

160

20.7

~Butyl Benzyl Phthalate

85-68-7

290

1,200

~Butylphthalyl Butylglycolate

85-70-1

63,000

820,000

~Dibutyl Phthalate

84-74-2

6,300

82,000

~Diethyl Phthalate

84-66-2

51,000

660,000

~Dimethylterephthalate

120-61-6

7,800

120,000

~Octyl Phthalate, di-N-

117-84-0

630

8,200

~PhthalicAcid, P-

100-21-0

63,000

820,000

~Phthalic Anhydride

85-44-9

130,000

1,600,000

Picloram

1918-02-1

4,400

57,000

Picramic Acid (2-Amino-4,6-dinitrophenol)

96-91-3

6.3

82

Picric Acid (2,4,6-Trinitrophenol)

88-89-1

57

740

Pirimiphos, Methyl

29232-93-7

630

8,200

Polybrominated Biphenyls

59536-65-1

0.018

0.077

Polychlorinated Biphenyls (PCBs)$(/td$)

~Aroclor 1016

12674-11-2

4.1

27

~Aroclor 1221

11104-28-2

0.2

0.83

~Aroclor 1232

11141-16-5

0.17

0.72

~Aroclor 1242

53469-21-9

0.23

0.95

~Aroclor 1248

12672-29-6

0.23

0.95

~Aroclor 1254

11097-69-1

0.97

0.120

~Aroclor 1260

11096-82-5

0.24

0.99

~Aroclor 5460

11126-42-4

35

440

~Heptachlorobiphenyl, 2,3,3'4,4',5,5'- (PCB 189)

39635-31-9

0.13

0.52

~Hexachlorobiphenyl, 2,3',4,4',5,5'- (PCB 167)

52663-72-6

0.12

0.51

~Hexachlorobiphenyl, 2,3,3',4,4',5'- (PCB 157)

69782-90-7

0.12

0.5

~Hexachlorobiphenyl, 2,3,3',4,4',5- (PCB 156)

38380-08-4

0.12

0.5

~Hexachlorobiphenyl, 3,3',4,4',5,5'- (PCB 169)

32774-16-6

0.00012

0.00051

~Pentachlorobiphenyl, 2',3,4,4',5- (PCB 123)

65510-44-3

0.12

0.49

~Pentachlorobiphenyl, 2,3',4,4',5- (PCB 118)

31508-00-6

0.12

0.49

~Pentachlorobiphenyl, 2,3,3',4,4'- (PCB 105)

32598-14-4

0.12

0.49

~Pentachlorobiphenyl, 2,3,4,4',5- (PCB 114)

74472-37-0

0.12

0.5

~Pentachlorobiphenyl, 3,3',4,4',5- (PCB 126)

57465-28-8

0.000036

0.00015

~Polychlorinated Biphenyls (high risk)

1336-36-3

0.94

0.114

~Tetrachlorobiphenyl, 3,3',4,4'- (PCB 77)

32598-13-3

0.038

0.16

~Tetrachlorobiphenyl, 3,4,4',5- (PCB 81)

70362-50-4

0.012

0.048

Polymeric Methylene Diphenyl Diisocyanate (PMDI)

9016-87-9

850,000

3,600,000

Polynuclear Aromatic Hydrocarbons (PAHs)$(/td$)

0.026

0.58

~Acenaphthene

83-32-9

3,600

45,000

~Anthracene

120-12-7

18,000

230,000

~Benz$(a$)anthracene

56-55-3

0.16

2.9

~Benzo(j)fluoranthene

205-82-3

0.42

1.8

~Benzo$(a$)pyrene

50-32-8

0.076/1.54 ï¿1/2

~Benzo$(b$)fluoranthene

205-99-2

0.16

2.9

~Benzo$(k$)fluoranthene

207-08-9

1.6

29

~Chloronaphthalene, Beta-

91-58-7

4,800

60,000

~Chrysene

218-01-9

16

290

~Dibenz$(a,h$)anthracene

53-70-3

0.016

0.29

~Dibenzo(a,e)pyrene

192-65-4

0.042

0.18

~Dimethylbenz(a)anthracene, 7,12-

57-97-6

0.00046

0.0084

~Fluoranthene

206-44-0

2,400

30,000

~Fluorene

86-73-7

2,400

30,000

~Indeno$(1,2,3-cd$)pyrene

193-39-5

0.16

2.9

~Methylnaphthalene, 1-

90-12-0

18

73

~Methylnaphthalene, 2-

91-57-6

240

3,000

~Naphthalene

91-20-3

17

1.42

~Nitropyrene, 4-

57835-92-4

0.42

1.8

~Pyrene

129-00-0

1,800

23,000

Potassium Perfluorobutane Sulfonate

29420-49-3

1,300

16,000

Prochloraz

67747-09-5

3.6

15

Profluralin

26399-36-0

470

7,000

Prometon

1610-18-0

950

12,000

Prometryn

7287-19-6

250

3,300

Propachlor

1918-16-7

820

11,000

Propanil

709-98-8

320

4,100

Propargite

2312-35-8

1,300

16,000

Propargyl Alcohol

107-19-7

160

2,300

Propazine

139-40-2

1,300

16,000

Propham

122-42-9

1,300

16,000

Propiconazole

60207-90-1

820

11,000

Propionaldehyde

123-38-6

75

310

Propyl benzene

103-65-1

3,800

24,000

Propylene

115-07-1

2,200

9,300

Propylene Glycol

57-55-6

1,300,000

16,000,000

Propylene Glycol Dinitrate

6423-43-4

390,000

1,600,000

Propylene Glycol Monomethyl Ether

107-98-2

41,000

370,000

Propylene Oxide

75-56-9

2.1

9.7

Propyzamide

23950-58-5

4,700

62,000

Pyridine

110-86-1

78

1,200

Quinalphos

13593-03-8

32

410

Quinoline

91-22-5

0.18

0.77

Quizalofop-ethyl

76578-14-8

570

7,400

Refractory Ceramic Fibers

NA

43,000,000

180,000,000

Resmethrin

10453-86-8

1,900

25,000

Ronnel

299-84-3

3,900

58,000

Rotenone

83-79-4

250

3,300

Safrole

94-59-7

0.55

10

Selenious Acid

7783-00-8

390

5,800

Selenium

7782-49-2

5,800

382

Selenium Sulfide

7446-34-6

390

5,800

Sethoxydim

74051-80-2

5,700

74,000

Silica (crystalline, respirable)

7631-86-9

4,300,000

18,000,000

Silver

7440-22-4

5,800

247

Simazine

122-34-9

4.5

19

Sodium Acifluorfen

62476-59-9

820

11,000

Sodium Azide

26628-22-8

310

4,700

Sodium Dichromate

10588-01-9

0.3

6.2

Sodium Diethyldithiocarbamate

148-18-5

2

8.5

Sodium Fluoride

7681-49-4

3,900

58,000

Sodium Fluoroacetate

62-74-8

1.3

16

Sodium Metavanadate

13718-26-8

78

1,200

Sodium Tungstate

13472-45-2

63

930

Sodium Tungstate Dihydrate

10213-10-2

63

930

Stirofos (Tetrachlorovinphos)

961-11-5

23

96

Strontium Chromate

7789-06-2

0.3

6.2

Strontium, Stable

7440-24-6

47,000

700,000

Strychnine

57-24-9

19

250

Styrene

100-42-5

6,000

35,000

Styrene-Acrylonitrile (SAN) Trimer

NA

190

2,500

Sulfolane

126-33-0

63

820

Sulfonylbis(4-chlorobenzene), 1,1'-

80-07-9

51

660

Sulfur Trioxide

7446-11-9

1,400,000

6,000,000

Sulfuric Acid

7664-93-9

1,400,000

6,000,000

Sulfurous acid, 2-chloroethyl 2-$(4-(1,1- dimethylethyl)phenoxy$)-1 -methylethyl ester

140-57-8

22

92

TCMTB

21564-17-0

1,900

25,000

Tebuthiuron

34014-18-1

4,400

57,000

Temephos

3383-96-8

1,300

16,000

Terbacil

5902-51-2

820

11,000

Terbufos

13071-79-9

2

29

Terbutryn

886-50-0

63

820

Tetrabromodiphenyl ether, 2,2',4,4'- (BDE-47)

5436-43-1

6.3

82

Tetrachlorobenzene, 1,2,4,5-

95-94-3

23

350

Tetrachloroethane, 1,1,1,2-

630-20-6

2

8.8

Tetrachloroethane, 1,1,2,2-

79-34-5

0.6

2.7

Tetrachloroethylene

127-18-4

100

1.46

Tetrachlorophenol, 2,3,4,6-

58-90-2

1,900

25,000

Tetrachlorotoluene, p- alpha, alpha, alpha-

5216-25-1

0.035

0.16

Tetraethyl Dithiopyrophosphate

3689-24-5

32

410

Tetrafluoroethane, 1,1,1,2-

811-97-2

100,000

430,000

Tetryl (Trinitrophenylmethylnitramine)

479-45-8

160

2,300

Thallic Oxide

1314-32-5

1.6

23

Thallium (I) Nitrate

10102-45-1

0.78

12

Thallium (Soluble Salts)

7440-28-0

12

0.764

Thallium Acetate

563-68-8

0.78

12

Thallium Carbonate

6533-73-9

1.6

23

Thallium Chloride

7791-12-0

0.78

12

Thallium Selenite

12039-52-0

0.78

12

Thallium Sulfate

7446-18-6

1.6

23

Thifensulfuron-methyl

79277-27-3

820

11,000

Thiobencarb

28249-77-6

630

8,200

Thiodiglycol

111-48-8

5,400

79,000

Thiofanox

39196-18-4

19

250

Thiophanate, Methyl

23564-05-8

5,100

66,000

Thiram

137-26-8

320

4.100

Tin

7440-31-5

47,000

700,000

Titanium Tetrachloride

7550-45-0

140,000

600,000

Toluene

108-88-3

47,000

4,640

Toluene-2,4-diisocyante

584-84-9

6.4

27

Toluene-2,5-diamine

95-70-5

3

13

Toluene-2,6-diisocyante

91-08-7

5.3

22

Toluidine, o- (Methylaniline, 2-)

95-53-4

34

140

Toluidine, p-

106-49-0

18

77

Total Petroleum Hydrocarbons (Aliphatic High)

NA

230,000

3,500,000

Total Petroleum Hydrocarbons (Aliphatic Low)

NA

520

2,200

Total Petroleum Hydrocarbons (Aliphatic Medium)

NA

96

440

Total Petroleum Hydrocarbons (Aromatic High)

NA

2,500

33,000

Total Petroleum Hydrocarbons (Aromatic Low)

NA

82

420

Total Petroleum Hydrocarbons (Aromatic Medium)

NA

110

600

Toxaphene

8001-35-2

0.49

2.1

Tralomethrin

66841-25-6

470

6,200

Tri-n-butyltin

688-73-3

23

350

Triacetin

102-76-1

5,100,000

66,000,000

Triadimefon

43121-43-3

1,900

25,000

Triallate

2303-17-5

1,000

15,000

Triasulfuron

82097-50-5

630

8,200

Tribenuron-methyl

101200-48-0

510

6,600

Tribromobenzene, 1,2,4-

615-54-3

390

5,800

Tributyl Phosphate

126-73-8

60

260

Tributyltin Compounds

NA

19

250

Tributyltin Oxide

56-35-9

19

250

Trichloro-1,2,2-trifluoroethane, 1,1,2-

76-13-1

40,000

170,000

Trichloroacetic Acid

76-03-9

7.8

33

Trichloroaniline HCl, 2,4,6-

33663-50-2

19

79

Trichloroaniline, 2,4,6-

634-93-5

1.9

25

Trichlorobenzene, 1,2,3-

87-61-6

63

930

Trichlorobenzene, 1,2,4-

120-82-1

24

110

Trichloroethane, 1,1,1-

71-55-6

8,100

36,000

Trichloroethane, 1,1,2-

79-00-5

1.1

5

Trichloroethylene

79-01-6

6

0.442

Trichlorofluoromethane

75-69-4

23,000

350,000

Trichlorophenol, 2,4,5-

95-95-4

6,300

82,000

Trichlorophenol, 2,4,6-

88-06-2

49

210

Trichlorophenoxyacetic Acid, 2,4,5-

93-76-5

630

8,200

Trichlorophenoxypropionic acid, -2,4,5

93-72-1

510

6,600

Trichloropropane, 1,1,2-

598-77-6

390

5,800

Trichloropropane, 1,2,3-

96-18-4

0.11

0.00324

Trichloropropene, 1,2,3-

96-19-5

0.73

3.1

Tricresyl Phosphate (TCP)

1330-78-5

1,300

16,000

Tridiphane

58138-08-2

190

2,500

Triethylamine

121-44-8

120

480

Triethylene Glycol

112-27-6

130,000

1,600,000

Trifluoroethane, 1,1,1-

420-46-2

15,000

62,000

Trifluralin

1582-09-8

90

420

Trimethyl Phosphate

512-56-1

27

110

Trimethylbenzene, 1,2,3-

526-73-8

210

264 (Sum of isomers)

Trimethylbenzene, 1,2,4-

95-63-6

240

Trimethylbenzene, 1,3,5-

108-67-8

12,000

Trimethylpentene, 2,4,4-

25167-70-8

780

12,000

Trinitrobenzene, 1,3,5-

99-35-4

2,200

32,000

Trinitrotoluene, 2,4,6-

118-96-7

96

12.0

Triphenylphosphine Oxide

791-28-6

1,300

16,000

Tris(1,3-Dichloro-2-propyl) Phosphate

13674-87-8

1,300

16,000

Tris(1-chloro-2-propyl)phosphate

13674-84-5

630

8,200

Tris(2,3-dibromopropyl) phosphate

126-72-7

0.28

1.3

Tris(2-chloroethyi)phosphate

115-96-8

27

110

Tris(2-ethylhexyl)phosphate

78-42-2

170

720

Tungsten

7440-33-7

.63

930

Uranium (Soluble Salts)

NA

3,500

45.9

Urethane

51-79-6

0.12

2.3

Vanadium Pentoxide

1314-62-1

460

2,000

Vanadium and Compounds

7440-62-2

5,800

2.88

Vernolate

1929-77-7

78

1,200

Vinclozolin

50471-44-8

1,600

21,000

Vinyl Acetate

108-05-4

910

3,800

Vinyl Bromide

593-60-2

0.12

0.52

Vinyl Chloride

75-01-4

0.059

1.7

Warfarin

81-81-2

19

250

Xylene, P-

106-42-3

560

2,400

Xylene, m-

108-38-3

550

2,400

Xylene, o-

95-47-6

650

2,800

Xylenes

1330-20-7

2,500

575

Zinc Phosphide

1314-84-7

23

350

Zinc and Compounds

7440-66-6

350,000

22,900

Zineb

12122-67-7

3,200

41,000

Zirconium

7440-67-7

6.3

93

Notes:

1. The USEPA values listed are reflective of the Regional Screening Levels (RSL) Summary Table May 2016.
2. The Agency will be using EPA Regional Screening Levels (RSLs) and Vermont Screening Levels (VSLs) for residential soil concentrations. The VSLs and the RSLs employ a hazard index of 1 and are based on a de minimus incremental lifetime carcinogenic risk of one in one million (10-6) and assume a 70 year residential exposure duration. For industrial soil scenarios, the industrial EPA RSL must be used. The VT DEC Background Soil Concentration values are to be used when the background value for benzo(a)pyrene (TEQ) or arsenic is greater than the VSL.
3. The VT DEC Background Soil Concentrations for Polynuclear Aromatic Hydrocarbons are expressed as the TEQ value for Benzo[a]pyrene.

Key:

= Contains residential and industrial B(a)P soil screening values

Blank cell = no screening level (EPA Residential RSLs not shown when VSL Residential value is present)

NA = not applicable

A1 SOIL SCREENING VALUES

(see notes at end of table)

EPA Regional Screening Levels (TR=1E-06, HQ=1.0)

Vermont Screening Levels (TR=1E-06, HQ=1.0)

VT DEC Background Soil Concentrations

Analyte

CAS Number

Resident Soil (mg/kg)

Industrial Soil (mg/kg)

Resident Soil (mg/kg)

Rural (mg/kg)

Urban (mg/kg)

Acephate

30560-19-1

62

260

Acetaldehyde

75-07-0

11

49

Acetochlor

34256-82-1

16,000

1,270

Acetone

67-64-1

670,000

39,900

Acetone Cyanohydrin

75-86-5

2,800,000

12,000,000

Acetonitrile

75-05-8

810

3,400

Acetophenone

98-86-2

7,800

120,000

Acetylaminofluorene, 2-

53-96-3

0.14

0.6

Acrolein

107-02-8

0.14

0.6

Acrylamide

79-06-1

0.24

4.6

Acrylic Acid

79-10-7

99

420

Acrylonitrile

107-13-1

0.25

1.1

Adiponitrile

111-69-3

8,500,000

36,000,000

Alachlor

15972-60-8

9.7

41

Aldicarb

116-06-3

63

820

Aldicarb Sulfone

1646-88-4

63

820

Aldrin

309-00-2

0.18

0.0202

Allyl Alcohol

107-18-6

3.5

15

Allyl Chloride

107-05-1

0.72

3.2

Aluminum

7429-90-5

1,100,000

75,600

Aluminum Phosphide

20859-73-8

31

470

Ametryn

834-12-8

570

7,400

Aminobiphenyl, 4-

92-67-1

0.026

0.11

Aminophenol, m-

591-27-5

5,100

66,000

Aminophenol, p-

123-30-8

1,300

16,000

Amitraz

33089-61-1

160

2,100

Ammonium Sulfamate

7773-06-0

16,000

230,000

Amyl Alcohol, tert-

75-85-4

82

340

Aniline

62-53-3

95

400

Anthraquinone, 9,10-

84-65-1

14

57

Antimony (metallic)

7440-36-0

470

27.1

Antimony Pentoxide

1314-60-9

39

580

Antimony Tetroxide

1332-81-6

31

470

Antimony Trioxide

1309-64-4

280,000

1,200,000

Arsenic, Inorganic

7440-38-2

16

Arsine

7784-42-1

0.27

4.1

Asulam

3337-71-1

3,200

41,000

Atrazine

1912-24-9

2.4

10

Auramine

492-80-8

0.62

2.6

Avermectin B1

65195-55-3

25

330

Azinphos-methyl

86-50-0

190

2500

Azobenzene

103-33-3

5.6

26

Azodicarbonamide

123-77-3

8,600

40,000

Barium

7440-39-3

220,000

11,700

Barium Chromate

10294-40-3

0.3

6.2

Benfluralin

1861-40-1

23,000

350,000

Benomyl

17804-35-2

41,000

121

Bensulfuron-methyl

83055-99-6

13,000

160,000

Bentazon

25057-89-0

1,900

25,000

Benzaldehyde

100-52-7

170

820

Benzene

71-43-2

5.1

0.442

Benzenediamine-2-methyl sulfate, 1,4-

6369-59-1

5.4

23

Benzenethiol

108-98-5

78

1200

Benzidine

92-87-5

0.00053

0.01

Benzoic Acid

65-85-0

250,000

3,300,000

Benzotrichloride

98-07-7

0.053

0.25

Benzyl Alcohol

100-51-6

6,300

82,000

Benzyl Chloride

100-44-7

1.1

4.8

Beryllium and compounds

7440-41-7

2,300

36.0

Bifenox

42576-02-3

570

7,400

Biphenthrin

82657-04-3

950

12,000

Biphenyl, 1,1'-

92-52-4

47

200

Bis(2-chloro-1-methylethyl) ether

108-60-1

47,000

2,920

Bis(2-chloroethoxy)methane

111-91-1

190

2500

Bis(2-chloroethyl)ether

111-44-4

0.23

1

Bis(chioromethyl)ether

542-88-1

0.000083

0.00036

Bisphenol A

80-05-7

3,200

41,000

Boron And Borates Only

7440-42-8

230,000

15,300

Boron Trichloride

10294-34-5

160,000

2,300,000

Boron Trifluoride

7637-07-2

3,100

47,000

Bromate

15541-45-4

4.7

0.559

Bromo-2-chloroethane, 1-

107-04-0

0.026

0.11

Bromobenzene

108-86-1

290

1,800

Bromochloromethane

74-97-5

630

129

Bromodichloromethane

75-27-4

0.29

1.3

Bromoform

75-25-2

19

86

Bromomethane

74-83-9

6.8

30

Bromophos

2104-96-3

390

5,800

Bromoxynil

1689-84-5

16,000

2.81

Bromoxynil Octanoate

1689-99-2

1,600

23,000

Butadiene, 1,3-

106-99-0

0.058

0.26

Butanol, N-

71-36-3

7,800

120,000

Butyl alcohol, sec-

78-92-2

130,000

1,500,000

Butylate

2008-41-5

3,900

58,000

Butylated hydroxyanisole

25013-16-5

2,700

11,000

Butylated hydroxytoluene

128-37-0

150

640

Butylbenzene, n-

104-51-8

3,900

58,000

Butylbenzene, sec-

135-98-8

7,800

120,000

Butylbenzene, tert-

98-06-6

7,800

120,000

Cacodylic Acid

75-60-5

1,300

16,000

Cadmium (Diet)

7440-43-9

980

7.15

Calcium Chromate

13765-19-0

0.3

6.2

Caprolactam

105-60-2

31,000

400,000

Captafol

2425-06-1

3.6

15

Captan

133-06-2

240

1000

Carbaryl

63-25-2

82,000

331

Carbofuran

1563-66-2

320

4,100

Carbon Disulfide

75-15-0

770

3,500

Carbon Tetrachloride

56-23-5

2.9

0.247

Carbonyl Sulfide

463-58-1

67

280

Carbosulfan

55285-14-8

630

8,200

Carboxin

5234-68-4

6,300

82,000

Ceric oxide

1306-38-3

1,300,000

5,400,000

Chloral Hydrate

302-17-0

7,800

120,000

Chloramben

133-90-4

950

12,000

Chloranil

118-75-2

1.3

5.7

Chlordane

12789-03-6

1.7

7.7

Chlordecone (Kepone)

143-50-0

0.054

0.23

Chlorfenvinphos

470-90-6

44

570

Chlorimuron, Ethyl-

90982-32-4

1,300

16,000

Chlorine

7782-50-5

0.18

0.78

Chlorine Dioxide

10049-04-4

2,300

34,000

Chlorite (Sodium Salt)

7758-19-2

2,300

35,000

Chloro-1,1-difluoroethane, 1-

75-68-3

54,000

230,000

Chloro-1,3-butadiene, 2-

126-99-8

0.01

0.044

Chloro-2-methylaniline HCl, 4-

3165-93-3

1.2

5

Chloro-2-methylaniline, 4-

95-69-2

5.4

23

Chloroacetaldehyde, 2-

107-20-0

2.6

12

Chloroacetophenone, 2-

532-27-4

43,000

180,000

Chloroaniline, p-

106-47-8

2.7

11

Chlorobenzene

108-90-7

1,300

273

Chlorobenzilate

510-15-6

4.9

21

Chlorobenzoic Acid, p-

74-11-3

1,900

25,000

Chlorobenzotrifluoride, 4-

98-56-6

210

2,500

Chlorobutane, 1-

109-69-3

3,100

47,000

Chlorodifluoromethane

75-45-6

49,000

210,000

Chloroethanol, 2-

107-07-3

1,600

23,000

Chloroform

67-66-3

0.32

1.4

Chloromethane

74-87-3

110

460

Chloromethyl Methyl Ether

107-30-2

0.02

0.089

Chloronitrobenzene, o-

88-73-3

1.8

7.7

Chloronitrobenzene, p-

100-00-5

9

38

Chlorophenol, 2-

95-57-8

390

5,800

Chloropicrin

76-06-2

2

8.2

Chlorothalonil

1897-45-6

180

740

Chlorotoluene, o-

95-49-8

1600

23000

Chlorotoluene, p-

106-43-4

1600

23000

Chlorozotocin

54749-90-5

0.0023

0.0096

Chlorpropham

101-21-3

13,000

160,000

Chlorpyrifos

2921-88-2

63

820

Chlorpyrifos Methyl

5598-13-0

630

8,200

Chlorsulfuron

64902-72-3

3,200

41,000

Chlorthal-dimethyl

1861-32-1

630

8,200

Chlorthiophos

60238-56-4

51

660

Chromium(III), Insoluble Salts

16065-83-1

1,800,000

41,900

Chromium(VI)

18540-29-9

6.3

0.0945

Clofentezine

74115-24-5

820

11,000

Cobalt

7440-48-4

350

22.9

Copper

7440-50-8

3,100

47,000

Cresol, m-

108-39-4

3,200

41,000

Cresol, o-

95-48-7

3,200

41,000

Cresol, p-

106-44-5

6,300

82,000

Cresol, p-chloro-m-

59-50-7

6,300

82,000

Cresols

1319-77-3

6,300

82,000

Crotonaldehyde, trans-

123-73-9

0.37

1.7

Cumene

98-82-8

1,900

9,900

Cupferron

135-20-6

2.5

10

Cyanazine

21725-46-2

0.65

2.7

Cyanides$(/td$)

~Calcium Cyanide

592-01-8

78

1,200

~Copper Cyanide

544-92-3

390

5,800

~Cyanide (CN-)

57-12-5

23

150

~Cyanogen

460-19-5

78

1,200

~Cyanogen Bromide

506-68-3

7,000

110,000

~Cyanogen Chloride

506-77-4

3,900

58,000

~Hydrogen Cyanide

74-90-8

23

150

~Potassium Cyanide

151-50-8

160

2,300

~Potassium Silver Cyanide

506-61-6

390

5,800

~Silver Cyanide

506-64-9

7,800

120,000

~Sodium Cyanide

143-33-9

78

1,200

~Thiocyanates

NA

16

230

~Thiocyanic Acid

463-56-9

16

230

~Zinc Cyanide

557-21-1

3,900

58,000

Cyclohexane

110-82-7

6,500

27,000

Cyclohexane, 1,2,3,4,5-pentabromo-6-chloro-

87-84-3

24

100

Cyclohexanone

108-94-1

28,000

130,000

Cyclohexene

110-83-8

310

3,100

Cyclohexylamine

108-91-8

16,000

230,000

Cyfluthrin

68359-37-5

1,600

21,000

Cyhalothrin

68085-85-8

320

4.100

Cypermethrin

52315-07-8

630

8,200

Cyromazine

66215-27-8

470

6,200

DDD

72-54-8

2.3

9.6

DDE, p,p'-

72-55-9

2

9.3

DDT

50-29-3

1.9

8.5

Dalapon

75-99-0

1,900

25,000

Daminozide

1596-84-5

30

130

Decabromodiphenyl ether, 2,2',3,3',4,4',5,5',6,6'- (BDE-209)

1163-19-5

440

3,300

Demeton

8065-48-3

2.5

33

Di(2-ethylhexyl)adipate

103-23-1

450

1,900

Diallate

2303-16-4

8.9

38

Diazinon

333-41-5

44

570

Dibenzothiophene

132-65-0

780

12,000

Dibromo-3-chloropropane, 1,2-

96-12-8

0.064

0.00327

Dibromobenzene, 1,3-

108-36-1

31

470

Dibromobenzene, 1,4-

106-37-6

780

12,000

Dibromochloromethane

124-48-1

8.3

39

Dibromoethane, 1,2-

106-93-4

0.036

0.16

Dibromomethane (Methylene Bromide)

74-95-3

24

99

Dibutyltin Compounds

NA

19

250

Dicamba

1918-00-9

1,900

25,000

Dichloro-2-butene, 1,4-

764-41-0

0.0021

0.0094

Dichloro-2-butene, cis-1,4-

1476-11-5

0.0074

0.032

Dichloro-2-butene, trans-1,4-

110-57-6

0.0074

0.032

Dichloroacetic Acid

79-43-6

11

46

Dichlorobenzene, 1,2-

95-50-1

1,800

9,300

Dichlorobenzene, 1,4-

106-46-7

2.6

11

Dichlorobenzidine, 3,3'-

91-94-1

1.2

5.1

Dichlorobenzophenone, 4,4'-

90-98-2

570

7,400

Dichlorodifluoromethane

75-71-8

87

370

Dichloroethane, 1,1-

75-34-3

3.6

16

Dichloroethane, 1,2-

107-06-2

2

0.175

Dichloroethylene, 1,1-

75-35-4

230

1,000

Dichloroethylene, 1,2-cis-

156-59-2

2,300

146

Dichloroethylene, 1,2-trans-

156-60-5

23,000

1,460

Dichlorophenol, 2,4-

120-83-2

190

2,500

Dichlorophenoxy Acetic Acid, 2,4-

94-75-7

700

9,600

Dichlorophenoxy)butyric Acid, 4-(2,4-

94-82-6

510

6,600

Dichloropropane, 1,2-

78-87-5

1

4.4

Dichloropropane, 1,3-

142-28-9

1,600

23,000

Dichloropropanol, 2,3-

616-23-9

190

2,500

Dichloropropene, 1,3-

542-75-6

1.8

8.2

Dichlorvos

62-73-7

1.9

7.9

Dicrotophos

141-66-2

6.3

82

Dicyclopentadiene

77-73-6

1.3

5.4

Dieldrin

60-57-1

0.034

0.14

Diethanolamine

111-42-2

130

1,600

Diethylene Glycol Monobutyl Ether

112-34-5

1,900

24,000

Diethylene Glycol Monoethyl Ether

111-90-0

3,800

48,000

Diethylformamide

617-84-5

78

1,200

Diethylstilbestrol

56-53-1

0.0016

0.0066

Difenzoquat

43222-48-6

5,100

66,000

Diflubenzuron

35367-38-5

1,300

16,000

Difluoroethane, 1,1-

75-37-6

48,000

200,000

Dihydrosafrole

94-58-6

9.9

45

Diisopropyl Ether

108-20-3

2,200

9,400

Diisopropyl Methylphosphonate

1445-75-6

6,300

93,000

Dimethipin

55290-64-7

1,300

16,000

Dimethoate

60-51-5

13

160

Dimethoxybenzidine, 3,3'-

119-90-4

0.34

1.4

Dimethyl methylphosphonate

756-79-6

320

1,400

Dimethylamino azobenzene $(p-$)

60-11-7

0.12

0.5

Dimethylaniline HCl, 2,4-

21436-96-4

0.94

4

Dimethylaniline, 2,4-

95-68-1

2.7

11

Dimethylaniline, N,N-

121-69-7

160

2,300

Dimethylbenzidine, 3,3'-

119-93-7

0.049

0.21

Dimethylformamide

68-12-2

2,600

15,000

Dimethylhydrazine, 1,1-

57-14-7

0.057

0.24

Dimethylhydrazine, 1,2-

540-73-8

0.00088

0.0041

Dimethylphenol, 2,4-

105-67-9

1,300

16,000

Dimethylphenol, 2,6-

576-26-1

38

490

Dimethylphenol, 3,4-

95-65-8

63

820

Dimethylvinylchloride

513-37-1

1.1

4.8

Dinitro-o-cresol, 4,6-

534-52-1

5.1

66

Dinitro-o-cyclohexyl Phenol, 4,6-

131-89-5

130

1,600

Dinitrobenzene, 1,2-

528-29-0

6.3

82

Dinitrobenzene, 1,3-

99-65-0

6.3

82

Dinitrobenzene, 1,4-

100-25-4

6.3

82

Dlnitrophenol, 2,4-

51-28-5

130

1,600

Dinitrotoluene Mixture, 2,4/2,6-

NA

0.8

3.4

Dinitrotoluene, 2,4-

121-14-2

1.7

7.4

Dinitrotoluene, 2,6-

606-20-2

0.36

1.5

Dinitrotoluene, 2-Amino-4,6-

35572-78-2

150

2,300

Dinitrotoluene, 4-Amino-2,6-

19406-51-0

150

2,300

Dinitrotoluene, Technical grade

25321-14-6

1.2

5.1

Dinoseb

88-85-7

63

820

Dioxane, 1,4-

123-91-1

24

2.52

Dioxins$(/td$)

~Hexachlorodibenzo-p-dioxin, Mixture

NA

0.0001

0.00047

TCDD, 2,3,7,8-

1746-01-6

0.000022

0.00000233

Diphenamid

957-51-7

1,900

25,000

Diphenyl Sulfone

127-63-9

51

660

Diphenylamine

122-39-4

1,600

21,000

Diphenylhydrazine, 1,2-

122-66-7

0.68

2.9

Diquat

85-00-7

140

1,800

Direct Black 38

1937-37-7

0.076

0.32

Direct Blue 6

2602-46-2

0.073

0.31

Direct Brown 95

16071-86-6

0.081

0.34

Disulfoton

298-04-4

2.5

33

Dithiane, 1,4-

505-29-3

780

12,000

Diuron

330-54-1

130

1,600

Dodine

2439-10-3

250

3,300

EPTC

759-94-4

2,000

29,000

Endosulfan

115-29-7

470

7,000

Endothall

145-73-3

1,300

16,000

Endrin

72-20-8

19

250

Epichlorohydrin

106-89-8

19

82

Epoxybutane, 1,2-

106-88-7

160

670

Ethanol, 2-(2-methoxyethoxy)-

111-77-3

2,500

33,000

Ethephon

16672-87-0

320

4,100

Ethion

563-12-2

32

410

Ethoxyethanol Acetate, 2-

111-15-9

2,600

14,000

Ethoxyethanol, 2-

110-80-5

5,200

47,000

Ethyl Acetate

141-78-6

620

2,600

Ethyl Acrylate

140-88-5

47

210

Ethyl Chloride (Chloroethane)

75-00-3

14,000

57,000

Ethyl Ether

60-29-7

16,000

230,000

Ethyl Methacrylate

97-63-2

1,800

7,600

Ethyl-p-nitrophenyl Phosphonate

2104-64-5

0.63

8.2

Ethylbenzene

100-41-4

25

2.21

Ethylene Cyanohydrin

109-78-4

4,400

57,000

Ethylene Diamine

107-15-3

7,000

110,000

Ethylene Glycol

107-21-1

130,000

1,600,000

Ethylene Glycol Monobutyl Ether

111-76-2

6,300

82,000

Ethylene Oxide

75-21-8

0.18

0.79

Ethylene Thiourea

96-45-7

5.1

51

Ethyleneimine

151-56-4

0.0027

0.012

Ethylphthalyl Ethyl Glycolate

84-72-0

190,000

2,500,000

Fenamiphos

22224-92-6

16

210

Fenpropathrin

39515-41-8

1,600

21,000

Fenvalerate

51630-58-1

1,600

21,000

Fluometuron

2164-17-2

820

11,000

Fluoride

16984-48-8

3,100

47,000

Fluorine (Soluble Fluoride)

7782-41-4

4,700

70,000

Fluridone

59756-60-4

5,100

66,000

Flurprimidol

56425-91-3

1,300

16,000

Flusilazole

85509-19-9

44

570

Flutolanil

66332-96-5

3,800

49,000

Fluvalinate

69409-94-5

630

8,200

Folpet

133-07-3

160

660

Fomesafen

72178-02-0

2.9

12

Fonofos

944-22-9

130

1,600

Formaldehyde

50-00-0

17

73

Formic Acid

64-18-6

29

120

Fosetyl-AL

39148-24-8

190,000

2,500,000

Furans$(/td$)

~Dibenzofuran

132-64-9

73

1,000

~Furan

110-00-9

73

1,000

~Tetrahydrofuran

109-99-9

18,000

94,000

Furazolidone

67-45-8

0.14

0.6

Furfural

98-01-1

210

2,600

Furium

531-82-8

0.36

1.5

Furmecyclox

60568-05-0

18

77

Glufosinate, Ammonium

77182-82-2

25

330

Glutaraldehyde

111-30-8

110,000

480,000

Glycidyl

765-34-4

23

210

Glyphosate

1071-83-6

6,300

82,000

Guanidine

113-00-8

780

12,000

Guanidine Chloride

50-01-1

1,300

16,000

Haloxyfop, Methyl

69806-40-2

3.2

41

Heptachlor

76-44-8

0.13

0.63

Heptachlor Epoxide

1024-57-3

0.07

0.33

Hexabromobenzene

87-82-1

160

2,300

Hexabromodiphenyl ether, 2,2',4,4',5,5'- (BDE-153)

68631-49-2

13

160

Hexachlorobenzene

118-74-1

0.96

0.0918

Hexachlorobutadiene

87-68-3

1.2

5.3

Hexachlorocyclohexane, Alpha-

319-84-6

0.086

0.36

Hexachlorocyclohexane, Beta-

319-85-7

0.3

1.3

Hexachlorocyclohexane, Gamma- (Lindane)

58-89-9

0.57

2.5

Hexachlorocyclohexane, Technical

608-73-1

0.3

1.3

Hexachlorocyclopentadiene

77-47-4

1.8

7.5

Hexachloroethane

67-72-1

1.8

8

Hexachlorophene

70-30-4

19

250

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)

121-82-4

28

3.49

Hexamethylene Diisocyanate, 1,6-

822-06-0

3.1

13

Hexamethylphosphoramide

680-31-9

25

330

Hexane, N-

110-54-3

610

2,500

Hexanedioic Acid

124-04-9

130,000

1,600,000

Hexanone, 2-

591-78-6

200

1,300

Hexazinone

51235-04-2

2,100

27,000

Hexythiazox

78587-05-0

1,600

21,000

Hydramethylnon

67485-29-4

19

250

Hydrazine

302-01-2

0.23

1.1

Hydrazine Sulfate

10034-93-2

0.23

1.1

Hydrogen Chloride

7647-01-0

28,000,000

120,000,000

Hydrogen Fluoride

7664-39-3

3,100

47,000

Hydrogen Sulfide

7783-06-4

2,800,000

12,000,000

Hydroquinone

123-31-9

9

38

Imazalil

35554-44-0

820

11,000

Imazaquin

81335-37-7

16,000

210,000

Imazethapyr

81335-77-5

16,000

210,000

Iodine

7553-56-2

780

12,000

Iprodione

36734-19-7

2,500

33,000

Iron

7439-89-6

820,000

53,500

Isobutyl Alcohol

78-83-1

23,000

350,000

Isophorone

78-59-1

570

2,400

Isopropalin

33820-53-0

1,200

18,000

Isopropanol

67-63-0

5,600

24,000

Isopropyl Methyl Phosphonic Acid

1832-54-8

6,300

82,000

Isoxaben

82558-50-7

3,200

41,000

JP-7

NA

430,000,000

1,800,000,000

Lactofen

77501-63-4

130

1,600

Lead Compounds$(/td$)

~Lead Chromate

7758-97-6

0.3

6.2

~Lead Phosphate

7446-27-7

82

380

~Lead acetate

301-04-2

64

270

~Lead and Compounds

7439-92-1

400

800

41

111

~Lead subacetate

1335-32-6

64

270

~Tetraethyl Lead

78-00-2

0.0078

0.12

Lewisite

541-25-3

0.39

5.8

Linuron

330-55-2

130

1,600

Lithium

7439-93-2

160

2,300

MCPA

94-74-6

32

410

MCPB

94-81-5

630

8,200

MCPP

93-65-2

63

820

Malathion

121-75-5

1,300

16,000

Maleic Anhydride

108-31-6

6,300

80,000

Maleic Hydrazide

123-33-1

32,000

410,000

Malononitrile

109-77-3

6.3

82

Mancozeb

8018-01-7

1,900

25,000

Maneb

12427-38-2

320

4,100

Manganese (Non-diet)

7439-96-5

26,000

1,170

Mephosfolan

950-10-7

5.7

74

Mepiquat Chloride

24307-26-4

1,900

25,000

Mercury Compounds$(/td$)

~Mercuric Chloride (and other Mercury salts)

7487-94-7

23

350

Mercury (elemental)

7439-97-6

46

10.9

~Methyl Mercury

22967-92-6

7.8

120

~Phenylmercuric Acetate

62-38-4

5.1

66

Merphos

150-50-5

2.3

35

Merphos Oxide

78-48-8

1.9

25

Metalaxyl

57837-19-1

3,800

49,000

Methacrylonitrile

126-98-7

7.5

100

Methamidophos

10265-92-6

3.2

41

Methanol

67-56-1

120,000

1,200,000

Methidathion

950-37-8

63

820

Methomyl

16752-77-5

1,600

21,000

Methoxy-5-nitroaniline, 2-

99-59-2

11

47

Methoxychlor

72-43-5

320

4,100

Methoxyethanol Acetate, 2-

110-49-6

110

510

Methoxyethanol, 2-

109-86-4

330

3,500

Methyl Acetate

79-20-9

78,000

1,200,000

Methyl Acrylate

96-33-3

150

610

Methyl Ethyl Ketone (2-Butanone)

78-93-3

190,000

26,000

Methyl Hydrazine

60-34-4

0.14

0.62

Methyl Isobutyl Ketone (4-methyl-2-pentanone)

108-10-1

33,000

140,000

Methyl Isocyanate

624-83-9

4.6

19

Methyl Methacrylate

80-62-6

4,400

19,000

Methyl Parathion

298-00-0

16

210

Methyl Phosphonic Acid

993-13-5

3,800

49,000

Methyl Styrene (Mixed Isomers)

25013-15-4

320

2,600

Methyl methanesulfonate

66-27-3

5.5

23

Methyl tert-Butyl Ether (MTBE)

1634-04-4

47

210

Methyl-1,4-benzenediamine dihydrochloride, 2-

615-45-2

19

250

Methyl-5-Nitroaniline, 2-

99-55-8

60

260

Methyl-N-nitro-N-nitrosoguanidine, N-

70-25-7

0.065

0.28

Methylaniline Hydrochloride, 2-

636-21-5

4.2

18

Methylarsonic acid

124-58-3

630

8,200

Methylbenzene,1-4-diamine monohydrochloride, 2-

74612-12-7

13

160

Methylbenzene-1,4-diamine sulfate, 2-

615-50-9

5.4

23

Methylcholanthrene, 3-

56-49-5

0.0055

0.1

Methylene Chloride

75-09-2

57

1,000

Methylene-bis(2-chioroaniline), 4,4'-

101-14-4

1.2

23

Methylene-bis(N,N-dimethyl) Aniline, 4,4'-

101-61-1

12

50

Methylenebisbenzenamine, 4,4'-

101-77-9

0.34

1.4

Methylenediphenyl Diisocyanate

101-68-8

850,000

3,600,000

Methylstyrene, Alpha-

98-83-9

5,500

82,000

Metolachlor

51218-45-2

9,500

120,000

Metribuzin

21087-64-9

1,600

21,000

Metsulfuron-methyl

74223-64-6

16,000

210,000

Mineral oils

8012-95-1

230,000

3,500,000

Mirex

2385-85-5

0.036

0.17

Molinate

2212-67-1

130

1,600

Molybdenum

7439-98-7

5,800

382

Monochloramine

10599-90-3

7,800

120,000

Monomethylaniline

100-61-8

130

1,600

Myclobutanil

88671-89-0

1,600

21,000

N,N'-Diphenyl-1,4-benzenediamine

74-31-7

19

250

Naled

300-76-5

160

2,300

Naphtha, High Flash Aromatic (HFAN)

64742-95-6

2,300

35,000

Naphthylamine, 2-

91-59-8

0.3

1.3

Napropamide

15299-99-7

6,300

82,000

Nickel Acetate

373-02-4

670

8,100

Nickel Carbonate

3333-67-3

670

8,100

Nickel Carbonyl

13463-39-3

820

11,000

Nickel Hydroxide

12054-48-7

820

11,000

Nickel Oxide

1313-99-1

840

12,000

Nickel Refinery Dust

NA

820

11,000

Nickel Soluble Salts

7440-02-0

22,000

980

Nickel Subsulfide

12035-72-2

0.41

1.9

Nickelocene

1271-28-9

670

8,100

Nitrate

14797-55-8

130,000

1,900,000

Nitrite

14797-65-0

7,800

120,000

Nitroaniline, 2-

88-74-4

630

8,000

Nitroaniline, 4-

100-01-6

27

110

Nitrobenzene

98-95-3

5.1

22

Nitrocellulose

9004-70-0

190,000,000

2,500,000,000

Nitrofurantoin

67-20-9

4,400

57,000

Nitrofurazone

59-87-0

0.42

1.8

Nitroglycerin

55-63-0

6.3

82

Nitroguanidine

556-88-7

6,300

82,000

Nitromethane

75-52-5

5.4

24

Nitropropane, 2-

79-46-9

0.014

0.06

Nitroso-N-ethylurea, N-

759-73-9

0.0045

0.085

Nitroso-N-methylurea, N-

684-93-5

0.001

0.019

Nitroso-di-N-butylamine, N-

924-16-3

0.099

0.46

Nitroso-di-N-propylamine, N-

621-64-7

0.078

0.33

Nitrosodiethanolamine, N-

1116-54-7

0.19

0.82

Nitrosodiethylamine, N-

55-18-5

0.00081

0.015

Nitrosodimethylamine, N-

62-75-9

0.002

0.034

Nitrosodiphenylamine, N-

86-30-6

110

470

Nitrosomethylethylamine, N-

10595-95-6

0.02

0.091

Nitrosomorpholine $(N-$)

59-89-2

0.081

0.34

Nitrosopiperidine $(N-$)

100-75-4

0.058

0.24

Nitrosopyrrolidine, N-

930-55-2

0.26

1.1

Nitrotoluene, m-

99-08-1

6.3

82

Nitrotoluene, o-

88-72-2

3.2

15

Nitrotoluene, p-

99-99-0

34

140

Nonane, n-

111-84-2

11

72

Norflurazon

27314-13-2

2,500

33,000

Octabromodiphenyl Ether

32536-52-0

190

2500

Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)

2691-41-0

57,000

3,860

Octamethylpyrophosphoramide

152-16-9

130

1,600

Oryzalin

19044-88-3

3,200

41,000

Oxadiazon

19666-30-9

320

4,100

Oxamyl

23135-22-0

1,600

21,000

Oxyfluorfen

42874-03-3

190

2,500

Paclobutrazol

76738-62-0

820

11,000

Paraquat Dichloride

1910-42-5

280

3,700

Parathion

56-38-2

380

4,900

Pebulate

1114-71-2

3,900

58,000

Pendimethalin

40487-42-1

2,500

33,000

Pentabromodiphenyl Ether

32534-81-9

160

2,300

Pentabromodiphenyl ether, 2,2',4,4',5- (BDE-99)

60348-60-9

6.3

82

Pentachiorobenzene

608-93-5

63

930

Pentachloroethane

76-01-7

7.7

36

Pentachloronitrobenzene

82-68-8

2.7

13

Pentachlorophenol

87-86-5

4

0.504

Pentaerythritol tetranitrate (PETN)

78-11-5

570

127

Pentane, n-

109-66-0

810

3,400

Perchlorates$(/td$)

~Ammonium Perchlorate

7790-98-9

55

820

~Lithium Perchlorate

7791-03-9

55

820

Perchlorate and Perchlorate Salts

14797-73-0

820

53.5

~Potassium Perchlorate

7778-74-7

55

820

~Sodium Perchlorate

7601-89-0

55

820

Perfluorobutane Sulfonate

375-73-5

1,600

23,000

Perfluorooctanic Acid

335-67-1

0.30

Permethrin

52645-53-1

3,200

41,000

Phenacetin

62-44-2

250

1,000

Phenmedipham

13684-63-4

16,000

210,000

Phenol

108-95-2

19,000

250,000

Phenol, 2-(1-methylethoxy)- Methylcarbamate, (Baygon, Propoxur)

114-26-1

3,300

82.2

Phenothiazine

92-84-2

32

410

Phenylenediamine, m-

108-45-2

380

4,900

Phenylenediamine, o-

95-54-5

12

49

Phenylenediamine, p-

106-50-3

12,000

160,000

Phenylphenol, 2-

90-43-7

280

1,200

Phorate

298-02-2

13

160

Phosgene

75-44-5

0.31

1.3

Phosmet

732-11-6

1,300

16,000

Phosphates, Inorganic$(/td$)

~Aluminum metaphosphate

13776-88-0

3,800,000

57,000,000

~Ammonium polyphosphate

68333-79-9

3,800,000

57,000,000

~Calcium pyrophosphate

7790-76-3

3,800,000

57,000,000

~Diammonium phosphate

7783-28-0

3,800,000

57,000,000

~Dicalcium phosphate

7757-93-9

3,800,000

57,000,000

~Dimagnesium phosphate

7782-75-4

3,800,000

57,000,000

~Dipotassium phosphate

7758-11-4

3,800,000

57,000,000

~Disodium phosphate

7558-79-4

3,800,000

57,000,000

~Monoaluminum phosphate

13530-50-2

3,800,000

57,000,000

~Monoammonium phosphate

7722-76-1

3,800,000

57,000,000

~Monocalcium phosphate

7758-23-8

3,800,000

57,000,000

~Monomagnesium phosphate

7757-86-0

3,800,000

57,000,000

~Monopotassium phosphate

7778-77-0

3,800,000

57,000,000

~Monosodium phosphate

7558-80-7

3,800,000

57,000,000

~Polyphosphoric acid

8017-16-1

3,800,000

57,000,000

~Potassium tripolyphosphate

13845-36-8

3,800,000

57,000,000

~Sodium acid pyrophosphate

7758-16-9

3,800,000

57,000,000

~Sodium aluminum phosphate (acidic)

7785-88-8

3,800,000

57,000,000

~Sodium aluminum phosphate (anhydrous)

10279-59-1

3,800,000

57,000,000

~Sodium aluminum phosphate (tetrahydrate)

10305-76-7

3,800,000

57,000,000

~Sodium hexametaphosphate

10124-56-8

3,800,000

57,000,000

~Sodium polyphosphate

68915-31-1

3,800,000

57,000,000

~Sodium trimetaphosphate

7785-84-4

3,800,000

57,000,000

~Sodium tripolyphosphate

7758-29-4

3,800,000

57,000,000

~Tetrapotassium phosphate

7320-34-5

3,800,000

57,000,000

~Tetrasodium pyrophosphate

7722-88-5

3,800,000

57,000,000

decahydrogenoctaorthophosphate (dihydrate)

15136-87-5

3,800,000

57,000,000

~Tricalcium phosphate

7758-87-4

3,800,000

57,000,000

~Trimagnesium phosphate

7757-87-1

3,800,000

57,000,000

~Tripotassium phosphate

7778-53-2

3,800,000

57,000,000

~Trisodium phosphate

7601-54-9

3,800,000

57,000,000

Phosphine

7803-51-2

23

350

Phosphoric Acid

7664-38-2

3,000,000

29,000,000

Phosphorus, White

7723-14-0

1.6

23

Phthalates$(/td$)

Bis(2-ethylhexyl)phthalate

117-81-7

160

20.7

~Butyl Benzyl Phthalate

85-68-7

290

1,200

~Butylphthalyl Butylglycolate

85-70-1

63,000

820,000

~Dibutyl Phthalate

84-74-2

6,300

82,000

~Diethyl Phthalate

84-66-2

51,000

660,000

~Dimethylterephthalate

120-61-6

7,800

120,000

~Octyl Phthalate, di-N-

117-84-0

630

8,200

~PhthalicAcid, P-

100-21-0

63,000

820,000

~Phthalic Anhydride

85-44-9

130,000

1,600,000

Picloram

1918-02-1

4,400

57,000

Picramic Acid (2-Amino-4,6-dinitrophenol)

96-91-3

6.3

82

Picric Acid (2,4,6-Trinitrophenol)

88-89-1

57

740

Pirimiphos, Methyl

29232-93-7

630

8,200

Polybrominated Biphenyls

59536-65-1

0.018

0.077

Polychlorinated Biphenyls (PCBs)$(/td$)

~Aroclor 1016

12674-11-2

4.1

27

~Aroclor 1221

11104-28-2

0.2

0.83

~Aroclor 1232

11141-16-5

0.17

0.72

~Aroclor 1242

53469-21-9

0.23

0.95

~Aroclor 1248

12672-29-6

0.23

0.95

~Aroclor 1254

11097-69-1

0.97

0.120

~Aroclor 1260

11096-82-5

0.24

0.99

~Aroclor 5460

11126-42-4

35

440

~Heptachlorobiphenyl, 2,3,3'4,4',5,5'- (PCB 189)

39635-31-9

0.13

0.52

~Hexachlorobiphenyl, 2,3',4,4',5,5'- (PCB 167)

52663-72-6

0.12

0.51

~Hexachlorobiphenyl, 2,3,3',4,4',5'- (PCB 157)

69782-90-7

0.12

0.5

~Hexachlorobiphenyl, 2,3,3',4,4',5- (PCB 156)

38380-08-4

0.12

0.5

~Hexachlorobiphenyl, 3,3',4,4',5,5'- (PCB 169)

32774-16-6

0.00012

0.00051

~Pentachlorobiphenyl, 2',3,4,4',5- (PCB 123)

65510-44-3

0.12

0.49

~Pentachlorobiphenyl, 2,3',4,4',5- (PCB 118)

31508-00-6

0.12

0.49

~Pentachlorobiphenyl, 2,3,3',4,4'- (PCB 105)

32598-14-4

0.12

0.49

~Pentachlorobiphenyl, 2,3,4,4',5- (PCB 114)

74472-37-0

0.12

0.5

~Pentachlorobiphenyl, 3,3',4,4',5- (PCB 126)

57465-28-8

0.000036

0.00015

~Polychlorinated Biphenyls (high risk)

1336-36-3

0.94

0.114

~Tetrachlorobiphenyl, 3,3',4,4'- (PCB 77)

32598-13-3

0.038

0.16

~Tetrachlorobiphenyl, 3,4,4',5- (PCB 81)

70362-50-4

0.012

0.048

Polymeric Methylene Diphenyl Diisocyanate (PMDI)

9016-87-9

850,000

3,600,000

Polynuclear Aromatic Hydrocarbons (PAHs)$(/td$)

0.026

0.58

~Acenaphthene

83-32-9

3,600

45,000

~Anthracene

120-12-7

18,000

230,000

~Benz$(a$)anthracene

56-55-3

0.16

2.9

~Benzo(j)fluoranthene

205-82-3

0.42

1.8

~Benzo$(a$)pyrene

50-32-8

0.076/1.54 ï¿1/2

~Benzo$(b$)fluoranthene

205-99-2

0.16

2.9

~Benzo$(k$)fluoranthene

207-08-9

1.6

29

~Chloronaphthalene, Beta-

91-58-7

4,800

60,000

~Chrysene

218-01-9

16

290

~Dibenz$(a,h$)anthracene

53-70-3

0.016

0.29

~Dibenzo(a,e)pyrene

192-65-4

0.042

0.18

~Dimethylbenz(a)anthracene, 7,12-

57-97-6

0.00046

0.0084

~Fluoranthene

206-44-0

2,400

30,000

~Fluorene

86-73-7

2,400

30,000

~Indeno$(1,2,3-cd$)pyrene

193-39-5

0.16

2.9

~Methylnaphthalene, 1-

90-12-0

18

73

~Methylnaphthalene, 2-

91-57-6

240

3,000

~Naphthalene

91-20-3

17

1.42

~Nitropyrene, 4-

57835-92-4

0.42

1.8

~Pyrene

129-00-0

1,800

23,000

Potassium Perfluorobutane Sulfonate

29420-49-3

1,300

16,000

Prochloraz

67747-09-5

3.6

15

Profluralin

26399-36-0

470

7,000

Prometon

1610-18-0

950

12,000

Prometryn

7287-19-6

250

3,300

Propachlor

1918-16-7

820

11,000

Propanil

709-98-8

320

4,100

Propargite

2312-35-8

1,300

16,000

Propargyl Alcohol

107-19-7

160

2,300

Propazine

139-40-2

1,300

16,000

Propham

122-42-9

1,300

16,000

Propiconazole

60207-90-1

820

11,000

Propionaldehyde

123-38-6

75

310

Propyl benzene

103-65-1

3,800

24,000

Propylene

115-07-1

2,200

9,300

Propylene Glycol

57-55-6

1,300,000

16,000,000

Propylene Glycol Dinitrate

6423-43-4

390,000

1,600,000

Propylene Glycol Monomethyl Ether

107-98-2

41,000

370,000

Propylene Oxide

75-56-9

2.1

9.7

Propyzamide

23950-58-5

4,700

62,000

Pyridine

110-86-1

78

1,200

Quinalphos

13593-03-8

32

410

Quinoline

91-22-5

0.18

0.77

Quizalofop-ethyl

76578-14-8

570

7,400

Refractory Ceramic Fibers

NA

43,000,000

180,000,000

Resmethrin

10453-86-8

1,900

25,000

Ronnel

299-84-3

3,900

58,000

Rotenone

83-79-4

250

3,300

Safrole

94-59-7

0.55

10

Selenious Acid

7783-00-8

390

5,800

Selenium

7782-49-2

5,800

382

Selenium Sulfide

7446-34-6

390

5,800

Sethoxydim

74051-80-2

5,700

74,000

Silica (crystalline, respirable)

7631-86-9

4,300,000

18,000,000

Silver

7440-22-4

5,800

247

Simazine

122-34-9

4.5

19

Sodium Acifluorfen

62476-59-9

820

11,000

Sodium Azide

26628-22-8

310

4,700

Sodium Dichromate

10588-01-9

0.3

6.2

Sodium Diethyldithiocarbamate

148-18-5

2

8.5

Sodium Fluoride

7681-49-4

3,900

58,000

Sodium Fluoroacetate

62-74-8

1.3

16

Sodium Metavanadate

13718-26-8

78

1,200

Sodium Tungstate

13472-45-2

63

930

Sodium Tungstate Dihydrate

10213-10-2

63

930

Stirofos (Tetrachlorovinphos)

961-11-5

23

96

Strontium Chromate

7789-06-2

0.3

6.2

Strontium, Stable

7440-24-6

47,000

700,000

Strychnine

57-24-9

19

250

Styrene

100-42-5

6,000

35,000

Styrene-Acrylonitrile (SAN) Trimer

NA

190

2,500

Sulfolane

126-33-0

63

820

Sulfonylbis(4-chlorobenzene), 1,1'-

80-07-9

51

660

Sulfur Trioxide

7446-11-9

1,400,000

6,000,000

Sulfuric Acid

7664-93-9

1,400,000

6,000,000

Sulfurous acid, 2-chloroethyl 2-$(4-(1,1- dimethylethyl)phenoxy$)-1 -methylethyl ester

140-57-8

22

92

TCMTB

21564-17-0

1,900

25,000

Tebuthiuron

34014-18-1

4,400

57,000

Temephos

3383-96-8

1,300

16,000

Terbacil

5902-51-2

820

11,000

Terbufos

13071-79-9

2

29

Terbutryn

886-50-0

63

820

Tetrabromodiphenyl ether, 2,2',4,4'- (BDE-47)

5436-43-1

6.3

82

Tetrachlorobenzene, 1,2,4,5-

95-94-3

23

350

Tetrachloroethane, 1,1,1,2-

630-20-6

2

8.8

Tetrachloroethane, 1,1,2,2-

79-34-5

0.6

2.7

Tetrachloroethylene

127-18-4

100

1.46

Tetrachlorophenol, 2,3,4,6-

58-90-2

1,900

25,000

Tetrachlorotoluene, p- alpha, alpha, alpha-

5216-25-1

0.035

0.16

Tetraethyl Dithiopyrophosphate

3689-24-5

32

410

Tetrafluoroethane, 1,1,1,2-

811-97-2

100,000

430,000

Tetryl (Trinitrophenylmethylnitramine)

479-45-8

160

2,300

Thallic Oxide

1314-32-5

1.6

23

Thallium (I) Nitrate

10102-45-1

0.78

12

Thallium (Soluble Salts)

7440-28-0

12

0.764

Thallium Acetate

563-68-8

0.78

12

Thallium Carbonate

6533-73-9

1.6

23

Thallium Chloride

7791-12-0

0.78

12

Thallium Selenite

12039-52-0

0.78

12

Thallium Sulfate

7446-18-6

1.6

23

Thifensulfuron-methyl

79277-27-3

820

11,000

Thiobencarb

28249-77-6

630

8,200

Thiodiglycol

111-48-8

5,400

79,000

Thiofanox

39196-18-4

19

250

Thiophanate, Methyl

23564-05-8

5,100

66,000

Thiram

137-26-8

320

4.100

Tin

7440-31-5

47,000

700,000

Titanium Tetrachloride

7550-45-0

140,000

600,000

Toluene

108-88-3

47,000

4,640

Toluene-2,4-diisocyante

584-84-9

6.4

27

Toluene-2,5-diamine

95-70-5

3

13

Toluene-2,6-diisocyante

91-08-7

5.3

22

Toluidine, o- (Methylaniline, 2-)

95-53-4

34

140

Toluidine, p-

106-49-0

18

77

Total Petroleum Hydrocarbons (Aliphatic High)

NA

230,000

3,500,000

Total Petroleum Hydrocarbons (Aliphatic Low)

NA

520

2,200

Total Petroleum Hydrocarbons (Aliphatic Medium)

NA

96

440

Total Petroleum Hydrocarbons (Aromatic High)

NA

2,500

33,000

Total Petroleum Hydrocarbons (Aromatic Low)

NA

82

420

Total Petroleum Hydrocarbons (Aromatic Medium)

NA

110

600

Toxaphene

8001-35-2

0.49

2.1

Tralomethrin

66841-25-6

470

6,200

Tri-n-butyltin

688-73-3

23

350

Triacetin

102-76-1

5,100,000

66,000,000

Triadimefon

43121-43-3

1,900

25,000

Triallate

2303-17-5

1,000

15,000

Triasulfuron

82097-50-5

630

8,200

Tribenuron-methyl

101200-48-0

510

6,600

Tribromobenzene, 1,2,4-

615-54-3

390

5,800

Tributyl Phosphate

126-73-8

60

260

Tributyltin Compounds

NA

19

250

Tributyltin Oxide

56-35-9

19

250

Trichloro-1,2,2-trifluoroethane, 1,1,2-

76-13-1

40,000

170,000

Trichloroacetic Acid

76-03-9

7.8

33

Trichloroaniline HCl, 2,4,6-

33663-50-2

19

79

Trichloroaniline, 2,4,6-

634-93-5

1.9

25

Trichlorobenzene, 1,2,3-

87-61-6

63

930

Trichlorobenzene, 1,2,4-

120-82-1

24

110

Trichloroethane, 1,1,1-

71-55-6

8,100

36,000

Trichloroethane, 1,1,2-

79-00-5

1.1

5

Trichloroethylene

79-01-6

6

0.442

Trichlorofluoromethane

75-69-4

23,000

350,000

Trichlorophenol, 2,4,5-

95-95-4

6,300

82,000

Trichlorophenol, 2,4,6-

88-06-2

49

210

Trichlorophenoxyacetic Acid, 2,4,5-

93-76-5

630

8,200

Trichlorophenoxypropionic acid, -2,4,5

93-72-1

510

6,600

Trichloropropane, 1,1,2-

598-77-6

390

5,800

Trichloropropane, 1,2,3-

96-18-4

0.11

0.00324

Trichloropropene, 1,2,3-

96-19-5

0.73

3.1

Tricresyl Phosphate (TCP)

1330-78-5

1,300

16,000

Tridiphane

58138-08-2

190

2,500

Triethylamine

121-44-8

120

480

Triethylene Glycol

112-27-6

130,000

1,600,000

Trifluoroethane, 1,1,1-

420-46-2

15,000

62,000

Trifluralin

1582-09-8

90

420

Trimethyl Phosphate

512-56-1

27

110

Trimethylbenzene, 1,2,3-

526-73-8

210

264 (Sum of isomers)

Trimethylbenzene, 1,2,4-

95-63-6

240

Trimethylbenzene, 1,3,5-

108-67-8

12,000

Trimethylpentene, 2,4,4-

25167-70-8

780

12,000

Trinitrobenzene, 1,3,5-

99-35-4

2,200

32,000

Trinitrotoluene, 2,4,6-

118-96-7

96

12.0

Triphenylphosphine Oxide

791-28-6

1,300

16,000

Tris(1,3-Dichloro-2-propyl) Phosphate

13674-87-8

1,300

16,000

Tris(1-chloro-2-propyl)phosphate

13674-84-5

630

8,200

Tris(2,3-dibromopropyl) phosphate

126-72-7

0.28

1.3

Tris(2-chloroethyi)phosphate

115-96-8

27

110

Tris(2-ethylhexyl)phosphate

78-42-2

170

720

Tungsten

7440-33-7

.63

930

Uranium (Soluble Salts)

NA

3,500

45.9

Urethane

51-79-6

0.12

2.3

Vanadium Pentoxide

1314-62-1

460

2,000

Vanadium and Compounds

7440-62-2

5,800

2.88

Vernolate

1929-77-7

78

1,200

Vinclozolin

50471-44-8

1,600

21,000

Vinyl Acetate

108-05-4

910

3,800

Vinyl Bromide

593-60-2

0.12

0.52

Vinyl Chloride

75-01-4

0.059

1.7

Warfarin

81-81-2

19

250

Xylene, P-

106-42-3

560

2,400

Xylene, m-

108-38-3

550

2,400

Xylene, o-

95-47-6

650

2,800

Xylenes

1330-20-7

2,500

575

Zinc Phosphide

1314-84-7

23

350

Zinc and Compounds

7440-66-6

350,000

22,900

Zineb

12122-67-7

3,200

41,000

Zirconium

7440-67-7

6.3

93

Notes:

1. The USEPA values listed are reflective of the Regional Screening Levels (RSL) Summary Table May 2016.
2. The Agency will be using EPA Regional Screening Levels (RSLs) and Vermont Screening Levels (VSLs) for residential soil concentrations. The VSLs and the RSLs employ a hazard index of 1 and are based on a de minimus incremental lifetime carcinogenic risk of one in one million (10-6) and assume a 70 year residential exposure duration. For industrial soil scenarios, the industrial EPA RSL must be used. The VT DEC Background Soil Concentration values are to be used when the background value for benzo(a)pyrene (TEQ) or arsenic is greater than the VSL.
3. The VT DEC Background Soil Concentrations for Polynuclear Aromatic Hydrocarbons are expressed as the TEQ value for Benzo[a]pyrene.

Key:

= Contains residential and industrial B(a)P soil screening values

Blank cell = no screening level (EPA Residential RSLs not shown when VSL Residential value is present)

NA = not applicable

A2 VAPOR INTRUSION VALUES

(see notes at end of table)

EPA Regional Air Screening Levels (TR=1E-06, HQ=1.0)

Vermont Air Screening Levels (TR=1E-06, HQ=1.0)

Vapor Intrusion Screening Values - Sub-slab Soil Gas

Vapor Intrusion Screening Values - Groundwater

Analyte

CAS Number

Resident Air ($(mu$)g/m3)

Industrial Air ($(mu$)g/m3)

Resident Air ($(mu$)g/m3)

Industrial Air ($(mu$)g/m3)

Residential ($(mu$)g/m3)

Industrial ($(mu$)g/m3)

Residential ($(mu$)g/L)

Industrial ($(mu$)g/L)

Acetaldehyde

75-07-0

1.3

5.6

43

190

670

2,900

Acetone

67-64-1

32,000

140,000

1,100,000

4,500,000

35,000,000

150,000,000

Acetone Cyanohydrin

75-86-5

2.1

8.8

Acetonitrile

75-05-8

63

260

2,100

8,800

69,000

290,000

Acetylaminofluorene, 2-

53-96-3

0.0022

0.0094

Acrolein

107-02-8

0.021

0.088

0.7

2.9

6.4

27

Acrylamide

79-06-1

0.01

0.12

Acrylic Acid

79-10-7

1.0

4.4

35

150

150,000

630,000

Acrylonitrile

107-13-1

0.041

0.18

1.4

6.0

12

54

Adiponitrile

111-69-3

6.3

26

Aldrin

309-00-2

0.00057

0.0025

0.019

0.083

0.92

4.0

Allyl Alcohol

107-18-6

0.1

0.44

3.5

15

980

4,100

Allyl Chloride

107-05-1

0.47

2

16

68

1.6

7.0

Aluminum

7429-90-5

5.2

22

Aminobiphenyl, 4-

92-67-1

0.00047

0.002

Ammonia

7664-41-7

100

440

3,500

15,000

210,000

890,000

Amyl Alcohol, tert-

75-85-4

3.1

13

100

440

11,000

45,000

Aniline

62-53-3

1

4.4

Antimony Trioxide

1309-64-4

0.21

0.88

Arsenic, Inorganic

7440-38-2

0.00065

0.0029

Arsine

7784-42-1

0.052

0.22

Auramine

492-80-8

0.011

0.049

Azinphos-methyl

86-50-0

10

44

Azobenzene

103-33-3

0.091

0.4

3.0

13

160

720

Azodicarbonamide

123-77-3

0.0073

0.031

Barium

7440-39-3

0.52

2.2

Barium Chromate

10294-40-3

0.0000068

0.000082

Benzene*

71-43-2

0.13

1.05

4.3

35

0.92

7.4

Benzidine

92-87-5

0.000015

0.00018

Benzyl Chloride

100-44-7

0.057

0.25

1.9

8.3

6.4

28

Beryllium and compounds

7440-41-7

0.0012

0.0051

Biphenyl, 1,1'-

92-52-4

0.42

1.8

14

58

75

320

Bis(2-chloroethyl)ether

111-44-4

0.0085

0.037

0.28

1.2

27

120

Bis(chloromethyl)ether

542-88-1

0.000045

0.0002

0.0015

0.0066

0.00025

0.0011

Boron And Borates Only

7440-42-8

21

88

Boron Trichloride

10294-34-5

21

88

700

2,900

Boron Trifluoride

7637-07-2

14

57

450

1,900

Bromo-2-chloroethane, 1-

107-04-0

0.0047

0.02

0.16

0.68

0.23

1.0

Bromobenzene

108-86-1

63

260

2,100

8,800

1,300

5,400

Bromochloromethane

74-97-5

42

180

1,400

5,800

1,100

4,700

Bromodichloromethane

75-27-4

0.076

0.33

2.5

11

1.5

6.3

Bromoform

75-25-2

2.6

11

85

370

230

990

Bromomethane

74-83-9

5.2

22

170

730

24

100

Butadiene, 1,3-

106-99-0

0.094

0.41

3.1

14

0.042

0.18

Butyl alcohol, sec-

78-92-2

31,000

130,000

1,000,000

4,400,000

NVT

NVT

Butylated hydroxyanisole

25013-16-5

49

220

Cadmium (Water)

7440-43-9

0.0016

0.0068

Calcium Chromate

13765-19-0

0.0000068

0.000082

Caprolactam

105-60-2

2.3

9.6

Captafol

2425-06-1

0.065

0.29

Captan

133-06-2

4.3

19

Carbon Disulfide

75-15-0

730

3,100

24,000

100,000

1,800

7,700

Carbon Tetrachloride

56-23-5

0.47

2.0

16

68

0.66

2.9

Carbonyl Sulfide

463-58-1

100

440

3,500

15,000

4.2

18

Ceric oxide

1306-38-3

0.94

3.9

Chlordane

12789-03-6

0.028

0.12

0.94

4.1

NVT

NVT

Chlordecone (Kepone)

143-50-0

0.00061

0.0027

Chlorine

7782-50-5

0.15

0.64

5.2

22

12

52

Chlorine Dioxide

10049-04-4

0.21

0.88

7.0

29

Chloro-1,1-difluoroethane, 1-

75-68-3

52,000

220,000

1,700,000

7,300,000

400,000

NVT

Chloro-1,3-butadiene, 2-

126-99-8

0.0094

0.041

0.31

1.4

0.0068

0.03

Chloro-2-methylaniline, 4-

95-69-2

0.036

0.16

Chloroacetophenone, 2-

532-27-4

0.031

0.13

Chlorobenzene

108-90-7

52

220

1,700

7,300

730

3,100

Chlorobenzilate

510-15-6

0.091

0.4

Chlorobenzotrifluoride, 4-

98-56-6

310

1,300

10,000

44,000

220

930

Chlorodifluoromethane

75-45-6

52,000

220,000

1,700,000

7,300,000

40,000

170,000

Chloroform

67-66-3

0.12

0.53

4.1

18

1.3

5.5

Chloromethane

74-87-3

94

390

3,100

13,000

340

1,400

Chloromethyl Methyl Ether

107-30-2

0.0041

0.018

0.14

0.59

0.33

1.4

Chloronitrobenzene, o-

88-73-3

0.01

0.044

Chloronitrobenzene, p-

100-00-5

2.1

8.8

Chloropicrin

76-06-2

0.42

1.8

14

58

5.0

21

Chlorothalonil

1897-45-6

3.2

14

32

Chlorozotocin

54749-90-5

0.000041

0.00018

Chromium(VI)

18540-29-9

0.000012

0.00015

Cobalt

7440-48-4

0.00031

0.0014

Coke Oven Emissions

8007-45-2

0.0016

0.02

Cresol, m-

108-39-4

630

2,600

Cresol, o-

95-48-7

630

2,600

Cresol, p-

106-44-5

630

2,600

Cresols

1319-77-3

630

2,600

Cumene

98-82-8

420

1,800

14,000

58,000

1,900

7,800

Cupferron

135-20-6

0.045

0.19

Cyanides$(/td$)

~Cyanide (CN-)

57-12-5

0.83

3.5

28

120

0.84

3.5

~Hydrogen Cyanide

74-90-8

0.83

3.5

28

120

230

960

Cyclohexane

110-82-7

6,300

26,000

210,000

880,000

1,600

6,800

Cyclohexanone

108-94-1

730

3,100

24,000

100,000

4,300,000

18,000,000

Cyclohexene

110-83-8

1,000

4,400

35,000

150,000

900

3,800

DDD

72-54-8

0.041

0.18

DDE, p,p'-

72-55-9

0.029

0.13

0.96

4.2

NVT

NVT

DDT

50-29-3

0.029

0.13

Daminozide

1596-84-5

0.55

2.4

Dibromo-3-chloropropane, 1,2-

96-12-8

0.00017

0.002

0.0056

0.068

0.058

0.70

Dibromoethane, 1,2-

106-93-4

0.0047

0.02

0.16

0.68

0.32

1.4

Dibromomethane (Methylene Bromide)

74-95-3

4.2

18

140

580

210

870

Dichloro-2-butene, 1,4-

764-41-0

0.00067

0.0029

0.022

0.097

0.0019

0.0084

Dichloro-2-butene, cis-1,4-

1476-11-5

0.00067

0.0029

0.022

0.097

0.047

0.20

Dichloro-2-butene, trans-1,4-

110-57-6

0.00067

0.0029

0.022

0.097

0.047

0.20

Dichlorobenzene, 1,2-

95-50-1

210

880

7,000

29,000

5,300

22,000

Dichlorobenzene, 1,4-

106-46-7

0.26

1.1

8.5

37

5.0

22

Dichlorobenzidine, 3,3'-

91-94-1

0.0083

0.036

Dichlorodifluoromethane

75-71-8

100

440

3,500

15,000

12

51

Dichloroethane, 1,1-

75-34-3

1.8

7.7

58

260

12

51

Dichloroethane, 1,2-

107-06-2

0.11

0.47

3.6

16

3.7

16

Dichloroethylene, 1,1-

75-35-4

210

880

7,000

29,000

280

1,200

Dichloropropane, 1,2-

78-87-5

0.28

1.2

9.4

41

4.0

18

Dichloropropene, 1,3-

542-75-6

0.7

3.1

100

36

Dichlorvos

62-73-7

0.034

0.15

Dicyclopentadiene

77-73-6

0.31

1.3

10

44

0.14

0.60

Dieldrin

60-57-1

0.00061

0.0027

Diesel Engine Exhaust

NA

0.0094

0.041

Diethanolamine

111-42-2

0.21

0.88

Diethylene Glycol Monobutyl Ether

112-34-5

0.10

0.44

Diethylene Glycol Monoethyl Ether

111-90-0

0.31

1.3

Diethylstilbestrol

56-53-1

0.000028

0.00012

Difluoroethane, 1,1-

75-37-6

42,000

180,000

1,400,000

5,800,000

65,000

270,000

Dihydrosafrole

94-58-6

0.22

0.94

7.2

31

430

1,900

Diisopropyl Ether

108-20-3

730

3,100

24,000

100,000

7,000

29,000

Dimethylamino azobenzene $(p-$)

60-11-7

0.0022

0.0094

Dimethylformamide

68-12-2

31

130

1,000

4,400

23,000,000

97,000,000

Dimethylhydrazine, 1,1-

57-14-7

0.0021

0.0088

0.07000

0.29

6.5

27

Dimethylhydrazine, 1,2-

540-73-8

0.000018

0.000077

0.00058

0.0026

6.200

27

Dimethylvinylchloride

513-37-1

0.22

0.94

7.2

31

0.048

0.21

Dinitrotoluene, 2,4-

121-14-2

0.032

0.14

Dioxane, 1,4-

123-91-1

0.56

2.5

19

82

5,100

22,000

Dioxins$(/td$)

~Hexachlorodibenzo-p-dioxin, Mixture

NA

0.0000022

0.0000094

~TCDD, 2,3,7,8-

1746-01-6

0.000000074

0.00000032

0.0000025

0.000011

0.000036

0.00016

Diphenylhydrazine, 1,2-

122-66-7

0.013

0.056

Direct Black 38

1937-37-7

0.00002

0.000088

Direct Blue 6

2602-46-2

0.00002

0.000088

Direct Brown 95

16071-86-6

0.00002

0.000088

Epichlorohydrin

106-89-8

1.0

4.4

35

150

840

3,500

Epoxybutane, 1,2-

106-88-7

21

88

700

2,900

4,500

19,000

Ethoxyethanol Acetate, 2-

111-15-9

63

260

2,100

8,800

990,000

4,200,000

Ethoxyethanol, 2-

110-80-5

210

880

7,000

29,000

21,000,000

90,000,000

Ethyl Acetate

141-78-6

73

310

2,400

10,000

22,000

93,000

Ethyl Acrylate

140-88-5

8.3

35

280

10,000

1,100

93,000

Ethyl Chloride (Chloroethane)

75-00-3

10,000

44,000

350,000

1,500,000

32,000

140,000

Ethyl Methacrylate

97-63-2

310

1,300

10,000

44,000

29,000

120,000

Ethylbenzene

100-41-4

1.1

4.9

37

160

6.3

28

Ethylene Glycol

107-21-1

420

1,800

Ethylene Glycol Monobutyl Ether

111-76-2

1,700

7,000

Ethylene Oxide

75-21-8

0.032

0.14

1.1

4.6

7.5

33

Ethylene Thiourea

96-45-7

0.22

0.94

Ethyleneimine

151-56-4

0.00015

0.00065

0.0049

0.022

0.30

1.3

Fluoride

16984-48-8

14

57

Fluorine (Soluble Fluoride)

7782-41-4

14

57

Formaldehyde

50-00-0

0.22

0.94

7.2

31

22,000

93,000

Formic Acid

64-18-6

0.31

1.3

10

44

63,000

260,000

Furfural

98-01-1

52

220

1,700

7,300

640,000

2,700,000

Furium

531-82-8

0.0065

0.029

Furmecyclox

60568-05-0

0.33

1.4

Glutaraldehyde

111-30-8

0.083

0.35

Glycidyl

765-34-4

1.0

4.4

35

150

50,000

210,000

Heptachlor

76-44-8

0.0022

0.0094

0.072

0.31

0.48

2.1

Heptachlor Epoxide

1024-57-3

0.0011

0.0047

0.036

0.16

4.3

19

Hexachloroberizene

118-74-1

0.0061

0.027

0.20

0.89

0.22

0.94

Hexachlorobutadiene

87-68-3

0.13

0.56

4.3

19

0.64

2.8

Hexachlorocyclohexane, Alpha-

319-84-6

0.0016

0.0068

Hexachlorocyclohexane, Beta-

319-85-7

0.0053

0.023

Hexachlorocyclohexane, Gamma- (Lindane)

58-89-9

0.0091

0.04

Hexachlorocyclohexane, Technical

608-73-1

0.0055

0.024

Hexachlorocyclopentadiene

77-47-4

0.21

0.88

7.0

29

4.6

19

Hexachloroethane

67-72-1

0.26

1.1

8.5

37

3.7

16

Hexamethylene Diisocyanate, 1,6-

822-06-0

0.01

0.044

0.35

1.5

5.3

22

Hexane, N-

110-54-3

730

3,100

24,000

100,000

16

65

Hexanone, 2-

591-78-6

31

130

1,000

4,400

15,000

63,000

Hydrazine

302-01-2

0.00057

0.0025

0.019

0.083

46

200

Hydrazine Sulfate

10034-93-2

0.00057

0.0025

Hydrogen Chloride

7647-01-0

21

88

700

2,900

0.00000029

0.0000012

Hydrogen Fluoride

7664-39-3

15

61

490

2,000

3,800

16,000

Hydrogen Sulfide

7783-06-4

2.1

8.8

70

290

7.4

31

Isophorone

78-59-1

2,100

8,800

Isopropanol

67-63-0

210

880

7,000

29,000

1,300,000

5,500,000

JP-7

NA

310

1,300

Lead Compounds$(/td$)

~Lead Chromate

7758-97-6

0.0000068

0.000082

~Lead Phosphate

7446-27-7

0.23

1

~Lead acetate

301-04-2

0.23

1

~Lead and Compounds

7439-92-1

0.15

~Lead subacetate

1335-32-6

0.23

1

Maleic Anhydride

108-31-6

0.73

3.1

Mercury Compounds$(/td$)

~Mercuric Chloride (and other Mercury salts)

7487-94-7

0.31

1.3

~Mercury (elemental)

7439-97-6

0.31

1.3

10

44

2.1

8.6

Methacrylonitrile

126-98-7

31

130

1,000

4,400

5,100

22,000

Methanol

67-56-1

21,000

88,000

700,000

2,900,000

200,000,000

840,000,000

Methoxy-5-nitroaniline, 2-

99-59-2

0.2

0.88

Methoxyethanol Acetate, 2-

110-49-6

1

4.4

35

150

170,000

720,000

Methoxyethanol, 2-

109-86-4

21

88

700

880

2,900,000

Methyl Acrylate

96-33-3

21

88

700

2,900

4,300

18,000

Methyl Ethyl Ketone (2-Butanone)

78-93-3

5,200

22,000

170,000

730,000

3,700,000

15,000,000

Methyl Hydrazine

60-34-4

0.0028

0.012

0.094

0.41

40

180

Methyl Isobutyl Ketone (4-methyl-2-pentanone)

108-10-1

3,100

13,000

100,000

440,000

980,000

4,100,000

Methyl Isocyanate

624-83-9

1

4.4

35

150

28

120

Methyl Methacrylate

80-62-6

730

3,100

24,000

10,000

100,000

430,000

Methyl Styrene (Mixed Isomers)

25013-15-4

42

180

1,400

5,800

920

3,900

Methyl methanesulfonate

66-27-3

0.1

0.44

Methyl tert-Butyl Ether (MTBE)

1634-04-4

11

47

360

1,600

690

3,000

Methyl-N-nitro-N-nitrosoguanidine, N-

70-25-7

0.0012

0.0051

Methylaniline Hydrochloride, 2-

636-21-5

0.076

0.33

Methylcholanthrene, 3-

56-49-5

0.00016

0.0019

Methylene Chloride

75-09-2

100

1,200

3,400

41,000

1,100

14,000

Methylene-bis(2-chloroaniline), 4,4'-

101-14-4

0.0024

0.029

Methylene-bis(N,N-dimethyl) Aniline, 4,4'-

101-61-1

0.22

0.94

Methylenebisbenzenamine, 4,4'-

101-77-9

0.0061

0.027

Methylenediphenyl Diisocyanate

101-68-8

0.63

2.6

Mirex

2385-85-5

0.00055

0.0024

0.018

0.080

0.017

0.073

Naphtha, High Flash Aromatic (HFAN)

64742-95-6

100

440

Nickel Carbonyl

13463-39-3

0.011

0.047

0.36

1.6

0.00081

0.0035

Nitroaniline, 2-

88-74-4

0.052

0.22

Nitroaniline, 4-

100-01-6

6.3

26

Nitrobenzene

98-95-3

0.07

0.31

2.3

10

160

680

Nitrofurazone

59-87-0

0.0076

0.033

Nitromethane

75-52-5

0.32

1.4

11

46

500

2,200

Nitropropane, 2-

79-46-9

0.001

0.0045

0.035

0.15

0.38

1.7

Nitroso-N-ethylurea, N-

759-73-9

0.00013

0.0016

Nitroso-N-methylurea, N-

684-93-5

0.00003

0.00036

Nitroso-di-N-butylamine, N-

924-16-3

0.0018

0.0077

0.058

3.3

Nitroso-di-N-propylamine, N-

621-64-7

0.0014

0.0061

Nitrosodiethanolamine, N-

1116-54-7

0.0035

0.015

Nitrosodiethylamine, N-

55-18-5

0.000024

0.00029

Nitrosodimethylamine, N-

62-75-9

0.000072

0.00088

0.0024

0.97

Nitrosodiphenylamine, N-

86-30-6

1.1

4.7

Nitrosomethylethylamine, N-

10595-95-6

0.00045

0.0019

0.015

7.6

Nitrosomorpholine $(N-$)

59-89-2

0.0015

0.0065

Nitrosopiperidine $(N-$)

100-75-4

0.001

0.0045

Nitrosopyrrolidine, N-

930-55-2

0.0046

0.02

Nonane, n-

111-84-2

21

88

700

2,900

0.34

1.4

Pentane, n-

109-66-0

1,000

4,400

35,000

150,000

30

130

Phenacetin

62-44-2

4.5

19

Phosgene

75-44-5

0.31

1.3

10

44

0.70

2.9

Phosphine

7803-51-2

0.31

1.3

10

44

0.31

1.3

Phosphoric Acid

7664-38-2

10

44

Phthalic Anhydride

85-44-9

21

88

Polybrominated Biphenyls

59536-65-1

0.00033

0.0014

Polychlorinated Biphenyls (PCBs)$(/td$)

~Aroclor 1016

12674-11-2

0.14

0.61

4.7

20

17

75

~Aroclor 1221

11104-28-2

0.0049

0.022

0.16

0.72

0.53

2.3

~Aroclor 1232

11141-16-5

0.0049

0.022

0.16

0.72

0.16

0.72

~Aroclor 1242

53469-21-9

0.0049

0.022

0.16

0.72

0.35

1.5

~Aroclor 1248

12672-29-6

0.0049

0.022

0.16

0.72

0.27

1.2

~Aroclor 1254

11097-69-1

0.0049

0.022

0.16

0.72

0.43

1.9

~Aroclor 1260

11096-82-5

0.0049

0.022

0.16

0.72

0.36

1.6

~Heptachlorobiphenyl, 2,3,3',4,4',5,5'- (PCB 189)

39635-31-9

0.0025

0.011

0.085

0.37

NVT

NVT

~Hexachlorobiphenyl, 2,3',4,4',5,5'- (PCB 167)

52663-72-6

0.0025

0.011

0.085

0.37

0.91

NVT

~Hexachlorobiphenyl, 2,3,3',4,4',5'- (PCB 157)

69782-90-7

0.0025

0.011

0.085

0.37

0.39

NVT

~Hexachlorobiphenyl, 2,3,3',4,4',5- (PCB 156)

38380-08-4

0.0025

0.011

0.085

0.37

0.44

1.9

~Hexachlorobiphenyl, 3,3',4,4',5,5'- (PCB 169)

32774-16-6

0.0000025

0.000011

0.085

0.00037

0.00091

0.0040

~Pentachlorobiphenyl, 2',3,4,4',5- (PCB 123)

65510-44-3

0.0025

0.011

0.085

0.37

0.33

1.4

~Pentachlorobiphenyl, 2,3',4,4',5- (PCB 118)

31508-00-6

0.0025

0.011

0.085

0.37

0.22

0.95

~Pentachlorobiphenyl, 2,3,3',4,4'- (PCB 105)

32598-14-4

0.0025

0.011

0.085

0.37

0.22

0.96

~Pentachlorobiphenyl, 2,3,4,4',5- (PCB 114)

74472-37-0

0.0025

0.011

0.085

0.37

0.68

3.0

~Pentachlorobiphenyl, 3,3',4,4',5- (PCB 126)

57465-28-8

0.00000074

0.0000032

0.000025

0.00011

0.00010

0.00042

~Polychlorinated Biphenyls (high risk)

1336-36-3

0.0049

0.021

~Polychlorinated Biphenyls (low risk)

1336-36-3

0.028

0.12

~Polychlorinated Biphenyls (lowest risk)

1336-36-3

0.14

0.61

~Tetrachlorobiphenyl, 3,3',4,4'- (PCB 77)

32598-13-3

0.00074

0.0032

~Tetrachlorobiphenyl, 3,4,4',5- (PCB 81)

70362-50-4

0.00025

0.0011

0.0085

0.037

0.028

0.12

Polymeric Methylene Diphenyl Diisocyanate (PMDI)

9016-87-9

0.63

2.6

Polynuclear Aromatic Hydrocarbons (PAHs)$(/td$)

~Benz$(a$)anthracene

56-55-3

0.0092

0.11

0.31

NVT

NVT

NVT

~Dimethylbenz(a)anthracene, 7,12-

57-97-6

0.000014

0.00017

~Naphthalene*

91-20-3

0.03

0.24

1.0

8.0

3.5

28

Propionaldehyde

123-38-6

8.3

35

280

1,200

4,300

18,000

Propyl benzene

103-65-1

1,000

4,400

35,000

150,000

4,700

20,000

Propylene

115-07-1

3,100

13,000

100,000

440,000

480

2,000

Propylene Glycol Dinitrate

6423-43-4

0.28

1.2

Propylene Glycol Monomethyl Ether

107-98-2

2,100

8,800

70,000

290,000

95,000,000

400,000,000

Propylene Oxide

75-56-9

0.76

3.3

25

110

400

1,700

Safrole

94-59-7

0.016

0.19

Selenium Sulfide

7446-34-6

21

88

Silica (crystalline, respirable)

7631-86-9

3.1

13

Sodium Dichromate

10588-01-9

0.0000068

0.000082

Sodium Fluoride

7681-49-4

14

57

Strontium Chromate

7789-06-2

0.0000068

0.000082

Styrene

100-42-5

1000

4400

35,000

150,000

17,000

72,000

Sulfolane

126-33-0

2.1

8.8

Sulfur Trioxide

7446-11-9

1

4.4

35

150

Sulfuric Acid

7664-93-9

1

4.4

Sulfurous acid, 2-chloroethyl 2-$(4-(1,1- dimethylethyl)phenoxy$)-1-methylethyl ester

140-57-8

0.4

1.7

Tetrachloroethane, 1,1,1,2-

630-20-6

0.38

1.7

13

55

7.2

32

Tetrachloroethane, 1,1,2,2-

79-34-5

0.048

0.21

1.6

7.0

6.0

26

Tetrachloroethylene*

127-18-4

0.63

5.11

21

170

1.5

12

Tetrafluoroethane, 1,1,1,2-

811-97-2

83,000

350,000

2,800,000

12,000,000

61,000

260,000

Titanium Tetrachloride

7550-45-0

0.1

0.44

3.5

15

Tetrahydrofuran

109-99-9

2,100

8,800

70,000

290,000

1,100,000

4,800,000

Toluene

108-88-3

5,200

22,000

170,000

730,000

33,000

14,000

Toluene-2,4-diisocyante

584-84-9

0.0083

0.035

0.28

1.2

18

77

Toluene-2,6-diisocyante

91-08-7

0.0083

0.035

0.28

1.2

18

77

Toluidine, o- (Methylaniline, 2-)

95-53-4

0.055

0.24

Toxaphene

8001-35-2

0.0088

0.038

Trichloro-1,2,2-trifluoroethane, 1,1,2-

76-13-1

31000

130000

1,000,000

4,400,000

2,200

9,200

Trichlorobenzene, 1,2,4-

120-82-1

2.1

8.8

70

290

78

330

Trichloroethane, 1,1,1-

71-55-6

5,200

22,000

170,000

730,000

12,000

49,000

Trichloroethane, 1,1,2-

79-00-5

0.18

0.77

5.8

26

9.1

40

Trichloroethylene*

79-01-6

0.2

0.70

6.7

23

0.82

2.9

Trichlorophenol, 2,4,6-

88-06-2

0.91

4

Trichloropropane, 1,2,3-

96-18-4

0.31

1.3

10

44

43

180

Trichloropropene, 1,2,3-

96-19-5

0.31

1.3

10

44

0.43

1.8

Triethylamine

121-44-8

7.3

31

240

1,000

2,100

8,700

Trifluoroethane, 1,1,1-

420-46-2

21,000

88,000

700,000

2,900,000

660

2,800

Trimethylbenzene, 1,2,3-

526-73-8

5.2

22

170

730

69

290

Trimethylbenzene, 1,2,4-

95-63-6

7.3

31

240

1,000

57

240

Tris(2,3-dibromopropyl)phosphate

126-72-7

0.0043

0.019

0.14

0.62

4.8

21

Urethane

51-79-6

0.0035

0.042

Vanadium Pentoxide

1314-62-1

0.00034

0.0015

Vinyl Acetate

108-05-4

210

880

7,000

29,000

17,000

70,000

Vinyl Bromide

593-60-2

0.088

0.38

2.9

13

0.24

1.0

Vinyl Chloride*

75-01-4

0.11

1.86

3.7

62

1.3

2.2

Xylenes

1330-20-7

100

440

3,500

15,000

700

2,900

Notes:

1. The USEPA values listed are reflective of the Regional Screening Levels (RSLs) Summary Table May 2016.
2. The Vermont Air Screening Levels were developed by the Vermont Department of Health (VDH). The VDH risk based worker indoor air concentrations were generated by combining current toxicity values (e.g. inhalation reference concentrations and inhalation unit risks) with a hypothetical worker exposure scenario using standard point estimate risk assessment procedures to derive an estimate of the concentration of each individual chemical in air that corresponds to a fixed level of risk i.e., a Hazard Quotient of 0.1 for noncarcinogenic (systemic) effects or an incremental lifetime carcinogenic risk of one in one million. Considering current local work practices, a hypothetical Worker was assumed to be on-site 10 hours each work day, 250 days per years for 30 years. A 70 year lifetime was assumed.
3. The VI Screening Values for soil gas and groundwater were calculated from USEPA RSL indoor air values using the USEPA Vapor Intrusion Screening Level Calculator. The shallow soil gas concentration is the target indoor air concentration divided by the generic attenuation factor for soil gas. Target groundwater concentrations were calculated based on an ambient groundwater temperature of 150 C.
4. For the five analytes denoted with an asterix (*), the vapor intrusion screening values for sub-slab soil gas and groundwater were calculated based on their respective VDH residential or worker target air screening levels.

Key:

Blank cell - no screening level (EPA RSLs not shown when VDH values are present)

NTV - not sufficiently volatile and/or toxic to pose inhalation risk in selected exposure scenario for the indicated medium

NA = not applicable

A3 SEDIMENT VALUES

Click here to view image

Notes: TEC = Threshold Effect Concentration, PEC = Probable Effects Concentration, DW = dry weight

1. Consensus-Based Sediment Quality Guidelines (SQGs) from: MacDonald D.D., Ingersoll C.G. and Berger T.A. 2000. Development and Evaluation of Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems. Archives of Environmental Contamination and Toxicology 39(1). 20-31.
2. SQGs for metals are based on bulk (unsorted) sediment concentrations. Concentrations of metals in sediments can be normalized on percent fines for the purpose of inter-site comparisons but not for comparisons to these SQGs.
3. The SQGs for organics are derived from samples normalized to 1 percent total organic carbon (TOC) in the sediment. The SQGs presented here are based on an assumed TOC of 1 percent. If site specific data show organic carbon content to be significantly different from 1 percent, concentrations should be normalized to 1 percent TOC (divide the site concentration by the percent TOC) prior to comparison with the SQGs in this table. If non site-specific TOC data are available, assume 1 percent TOC.
4. Included on USEPA's list of important persistent, bioaccumulative, toxic compounds (PBTs).

Appendix B Establishment of Background Concentrations

(a) Purpose. A PRP may conduct a site-specific background study when there is reason to believe that the contamination present is naturally occurring. An approved site-specific background concentration will take the place of an adopted environmental media standard.
(b) Sampling plan. A sampling and monitoring plan shall be prepared by an environmental professional that will produce data representative of the site at and around the area of interest. The plan shall identify, at a minimum, the following:
(1) the number of monitoring points that will be sampled to establish a statistically defensible data set that will substantiate the validity of the background concentrations;
(2) the location and depth of monitoring points, which shall be selected so as to be geologically and geochemically similar to the area of interest and to be unaffected by current and historic activities at the site, including by being hydrogeologically up-gradient of such activities if possible;
(3) the number and frequency of the samples to be taken from the monitoring points and any existing sources of data for the media for which a background standard is proposed, including water for potable water supplies, public water sources, or non-potable wells or springs;
(4) the sampling methodology;
(5) the contaminants of concern to be analyzed in the samples that are collected;
(6) the analytical methods to be used in conducting the sample analysis;
(7) identification of whether samples obtained prior to the approval of the monitoring plan will be used as data points and, if so, the sampling date, location, method of analysis for each of the samples to be used; and
(8) a quality assurance/quality control plan for sample collection, testing, and analysis.
(c) Review of sampling plan. The information required by subsection (b) of this section may be included in a site investigation work plan submitted under Subchapter 3. The Secretary may request additional information from an applicant when the Secretary determines that the sampling and monitoring plan may not provide data representative of the background conditions at and around the area of interest.
(d) Report on background investigation. Following the Secretary's approval of the sampling and monitoring plan and the completion of sampling, the person seeking to establish a site-specific background standard shall report on the following as a part of their site investigation report required by § 35-305:
(1) All sampling results and data collected pursuant to the approved monitoring and sampling plan.
(2) An analysis of all data collected pursuant to the approved monitoring and sampling plan.
(3) Any discrepancies between the approved sampling and monitoring plan and the sampling completed for the area of interest.
(4) A proposed background concentration of all substances for which the person seeks to establish background standard and a justification for each concentration. The justification may include statistical analysis.
(5) Additional information the Secretary determines is necessary to approve or deny the proposed background groundwater concentrations.
(e) Site-specific standard. Following submission of the proposed background concentrations to the Secretary, the Secretary shall approve or deny the request.

Appendix C Site Management Waivers

(a) Purpose. A technical impracticality (TI) waiver is a mechanism to manage risks to human health and the environment in situations where there is no readily available technology to complete remediation and achieve compliance with the applicable environmental media standards within a reasonable timeframe. A TI waiver does not waive the requirements to delineate the nature and extent of the release of pollutants, to remediate continuing sources of pollution, or to address potential risks to receptors.
(b) Applicability. A TI waiver may be considered as a part of § 35-503. TI waivers may be considered for any of the following:
(1) The Secretary determines that there are non-aqueous phase liquids that cannot be contained or removed;
(2) The Secretary determines that there is only one response action for the activity and it cannot obtain other necessary permits;
(3) The Secretary determines that remediation has taken place to reduce in concentration hazardous materials in environmental media and the plume has been controlled to the extent practical based on an evaluation of reliable and innovative technologies; or
(4) The Secretary determines that achieving compliance with the applicable criteria is technically impracticable as determined using Directive No. 9234.2-25 issued September 1993 by the U.S. Environmental Protection Agency's Office of Solid Waste and Emergency Response.
(c) Prohibition. A TI waiver is prohibited in the following circumstances:
(1) situations where the Secretary determines that active remediation is necessary to control the migration of a plume or materially reduce the concentration of a hazardous material; or
(2) after approval of a TI waiver there would continue to be unmanaged exposure to human health receptors.
(d) Technical impracticality waiver documentation. For any PRP proposing a TI waiver, the site investigation report prepared under § 35-305 shall, in addition to all other requirements, contain the following materials:
(1) A proposal for the environmental standard or standards that the PRP is seeking a TI waiver for;
(2) A proposed TI zone for purposes of implementing the waiver that documents the following:
(A) The plume is not increasing in size or concentration in a manner which would alter the risk assumptions associated with the TI waiver request or the extent of the TI Zone;
(B) The plume is not increasing at compliance points at the TI Zone boundary.
(3) Documentation that all necessary permits have been applied for, made best efforts to obtain, and were denied;
(4) Documentation that the site has been adequately characterized including the nature and three-dimensional extent of the contamination;
(5) Any potential changes in contaminant concentrations will not pose a risk to human health or the environment;
(6) Documentation that potential exposure pathways threatening human health and the environment from contaminated environmental media have been identified and appropriately managed;
(7) Documentation that all data gaps have been identified and evaluated for significance (a significant data gap would be one that limits the ability to formulate a single scientifically defensible interpretation of environmental conditions or potential risks, or that may affect the choice of remedial approach);
(8) An evaluation showing the remedial restoration times using active remedial treatments. All assumptions and the degree of uncertainty associated with any model shall be thoroughly discussed;
(9) An evaluation showing natural attenuation, based on monitoring subsequent to source remediation, has shown that contaminated environmental media will not achieve remedial criteria within a reasonable timeframe. All assumptions and the degree of uncertainty associated with any model shall be thoroughly discussed;
(10) An estimate the cost of remedial alternatives. Cost estimates shall include the present worth of construction, operation, and maintenance costs; and
(11) An evaluation of implementing remediation alternatives for plume containment or for reduction of the concentration of hazardous materials in the plume.

Note: When conducting a TI waiver analysis as a part of an evaluation of cleanup options, the Agency recommends review of the following guidance documents in preparing a request for a TI waiver:

Technical Impracticability: Guidance for Evaluating Technical Impracticability of Ground-Water Restoration, September 1993. USEPA OSWER Directive 9234.2-25

Technical Impracticability Guidance for Groundwater, December 2013. New Jersey Department of Environmental Protection.

Draft Guidance for Applying Technical Impracticability of Groundwater, February 2014. Connecticut Department of Energy and Environmental Protection.

SUBCHAPTER 9 INSTITUTIONAL CONTROLS
901 Institutional Control Plan
(a) Purpose. The purpose of an institutional control plan is to identify a series of land use restrictions to ensure the protection of human health and the environment.
(b) Acceptable Alternate Institutional Controls. In addition to the institutional controls identified in § 35-902 and § 35-903, the following institutional controls may be acceptable when included as a part of an institutional control plan approved by the Secretary:
(1) Zoning Ordinances. Zoning ordinances that place restrictions on uses of an area where the property is located may be considered as a part of an institutional control plan, e.g. zoning an area for non-residential use only or limiting subsurface excavation. Institutional control plans shall address how reporting on zoning ordinances will take place to ensure that future modifications to ordinances or bylaws do not allow land use to adversely affect human health or the environment.
(2) Water Ordinances. Water ordinances that require all property owners to be connected to a public community water supply when service is available may be an acceptable institutional control for groundwater use restrictions. Institutional control plans shall address how reporting on water ordinances will take place to ensure that future modifications to ordinances or bylaws to ensure compliance with land use restrictions.
(3) Groundwater reclassification. Groundwater reclassifications may be an acceptable institutional control for groundwater use restrictions.
(4) Judicially approved controls. Judicial controls may be an acceptable institutional control. The institutional control plan shall identify how the judicially approved controls will allow the control to survive changes to property ownership or other transfers of the property.
(5) Approval of institutional control plan. The PRP shall submit an institutional control plan to the Secretary for approval. The plan shall include the following:
(A) The PRP has identified all residual contamination that remains on the property;
(B) The PRP has identified appropriate restrictions to ensure that exposure pathways are not created by uses or activities that take place on the property;
(C) The PRP has identified a control or controls that adequately address the land use restrictions identified in subsection (c)(2) of this section; and
(D) The PRP has identified a means to ensure that the controls continue to be effective until the contamination no longer poses an unacceptable impact to human health or the environment.
902 Notice to the Land Records
(a) Purpose. The purpose of a notice to the land records is to inform present and future property owners of the presence of residual contamination at the property, and applicable land use restrictions.
(b) Applicability. A Notice to the Land Records is an acceptable institutional control when corrective actions have addressed exposure pathways to sensitive receptors, but residual contamination above applicable environmental media standards may be present on site.
(c) Required Elements. All notices to the land record shall contain:
(1) A brief description of the release of hazardous materials;
(2) A brief description of any corrective action that took place on the site;
(3) What residual hazardous materials remain on the site above applicable media standards and the location of those hazardous materials;
(4) A description of the necessary land use restriction(s) to ensure that no further exposure to hazardous materials can occur; and.
(5) The following language shall be included: "If a person fails to follow the land use restrictions contained within this notice the person may be liable for further site investigation, remediation, and penalties pursuant to the Vermont Waste Management Act, 10 V.S.A. chapter 159."
(d) Filing. A PRP shall file a notice to the land records within one week of approval by the Secretary. The PRP shall provide a copy to the Secretary, including the recorder stamp, date of recording, book, and page number, of the recorded notice to the land record within 10 days of its recording.
903 Environmental Easement
(a) Purpose. The purpose of an environmental easement is to place legally enforceable land use restrictions on a property to prevent exposure to any hazardous material left on the property and to ensure the protectiveness of any corrective action at the property.
(b) Applicability. The Secretary may require the use of an environmental easement in the following situations:
(1) When long term maintenance or monitoring of the corrective action, engineered remedy or land use restrictions are required to prevent contamination from posing a risk to human health or the environment;
(2) When land use restrictions will include restrictions for residential property use;
(3) When active remedial infrastructure must remain in place in order to prevent a risk to human health or the environment;
(4) When a Technical Impracticality (TI) Waiver has been granted by the Secretary in accordance with Appendix C; or
(5) When groundwater contamination remains or is projected to remain at the site above the Vermont Groundwater Enforcement Standards at a compliance point in accordance with the timeline established in the Vermont Groundwater Protection Rule and Strategy.
(c) Required Elements. The following shall be included in an environmental easement:
(1) A legal description of the site property;
(2) A description of the release, corrective action, and statement of the need for an environmental easement an environmental easement on the property;
(3) A grant of access to the Agency of Natural Resources to the property for any reason related to the purpose of the easement, including monitoring of the site, monitoring of the land use restriction, planning future corrective action;
(4) Restrictions on future uses of the property or portions of the property to prevent receptors from being exposed to any residual contamination that remains on the property and to ensure the effectiveness of any corrective action;
(5) A process for enforcing the terms of the easement; and
(6) A map including the most recent parcel boundary survey that depicts the area of the parcel to which the restrictions apply.
(d) Approval. The Secretary shall review and approve the environmental easement upon demonstration that easement complies with the requirements of § 35-903(c).
(e) Filing. A PRP shall file an approved environmental easement and all exhibits within one week of its approval by the Secretary and shall provide a copy to the Secretary, including the recorder stamp, book, and page number, of the recorded environmental easement on within one week of its recording.
904 Land Use Restrictions Within a Certificate of Completion
(a) Purpose. The Secretary may establish land use restrictions within a certificate of completion upon closure of a site enrolled in BRELLA pursuant 10 V.S.A. Chapter 159. The purpose of these restrictions is to ensure the ongoing effectiveness of response actions taken at the site.
(b) Applicability. The Secretary may restrict future uses of a property as a part of a certificate of completion in any of the following situations:
(1) When long term maintenance or monitoring of the corrective action or land use restrictions are required to ensure a risk to human health or the environment will not occur;
(2) When land use restrictions will include constraints regarding residential property use;
(3) When active remedial infrastructure must remain in place in order to prevent contamination from posing a risk to human health or the environment;
(4) When a Technical Impracticality (TI) Waiver has been granted by the Secretary in accordance with Appendix C; or
(5) When groundwater contamination remains or is projected to remain at the site above the Vermont Groundwater Enforcement Standards at a compliance point in accordance with the timeline established in the Vermont Groundwater Protection Rule and Strategy.
(c) Required Elements. A certificate shall include the following items:
(1) A legal description of the site property;
(2) A description of the release, corrective action, and statement of the need for land use restrictions on the property;
(3) Restrictions on future uses of the property or portions of the property to prevent receptors from being exposed to any residual contamination that remains on the property and to ensure the effectiveness of any corrective action; and
(4) A map including the most recent parcel boundary survey that depicts the area of the parcel to which the restrictions apply.
(d) Recording. The PRP shall record a certificate of completion and all supporting documentation and exhibits with the land records of the municipality or municipalities in which the site is located. Such recording shall be made within one week of the date of issuance of the certificate of completion. Within one week of the date of recording, the PRP shall provide a copy of the recorded and stamped certificate of completion and all recorded documents to the Secretary, which includes the book and page number of where those documents were recorded.
SUBCHAPTER 10 SITE CLOSURE
1001 Site Management Activities Complete
(a) Purpose. A Site Management Activities Complete (SMAC) designation may be issued to signify that, based on current information, no additional work related to a release is required.
(b) Eligibility. A PRP shall submit a request for a SMAC designation that summarizes the site investigation and corrective action undertaken at the site and that demonstrates all the following:
(1) Each source area that was removed, remediated, or adequately controlled.
(2) Hazardous material data trends collected from site specific environmental media demonstrate that contaminant concentrations are stable, falling, or are not detectable.
(3) Groundwater enforcement standards as adopted in the Groundwater Protection Rule and Strategy have been met at compliance points established for the site.
(4) No hazardous materials associated with the site are present in drinking water supplies at concentrations in excess of Vermont's groundwater quality standards (Vermont Groundwater Enforcement Standards or Vermont Action Levels, when one is available).
(5) Active remediation at the site has been completed.
(6) Soil standards have been met at compliance points or, if soil standards have not been met, then a corrective action plan has been implemented as well as approved institutional controls and land use restrictions, as necessary.
(7) Vermont Water Quality Standards have been achieved at all surface water compliance points established for the site.
(8) Sediment remediation has been completed or was not required.
(9) Migration of hazardous materials from soil to groundwater is not occurring at a concentration which will result in an exceedance of the Vermont Groundwater Enforcement Standards.
(10) No completed vapor intrusion pathway exists.
(11) The site has been properly closed following the corrective action, including:
(A) All groundwater monitoring wells have been properly closed in accordance with the Vermont Water Supply Rule or an alternate plan has been approved by the Secretary for maintaining the monitoring wells. The Secretary shall be notified of the closure of the monitoring wells.
(B) Abandoned water supply wells have been properly closed in accordance with the Vermont Water Supply Rule.
(C) All site remedial infrastructure or monitoring points have been closed in a manner to prevent impacts to the environment or human health.
(D) Excavated contaminated soils have been properly treated or disposed of in accordance with § 35-803, § 35-611, or § 35-804.
(12) Any outstanding or overdue balances owed to the State (e.g. Petroleum Cleanup fund "PCF" deferred deductible, PCF cost recovery, Environmental Contingency Fund (ECF) cost recovery, UST loan, settlement agreements, penalties, fines, natural resources damage assessments, taxes, unpaid child support, etc.) have been paid to the satisfaction of the State.
(13) Injection wells and floor drains have been closed in accordance with the Underground Injection Control Rule, as appropriate.
(14) All required institutional controls, engineered controls, and inspection plans are in place and copies have been provided to the Secretary.
(15) All documentation required by this rule has been submitted to and approved by the Secretary.
(c) Issuance of SMAC designation. The Secretary shall issue a SMAC designation for the site upon compliance with the requirements of subsection (b) of this section. The Secretary may issue a SMAC designation upon his or her own discretion upon a demonstration that the requirements of subsection (b) are met.
(d) SMAC as notice to the land records. A copy of the SMAC designation shall be recorded in municipal land records in the municipality where the site is located.
(1) The PRP shall within 10 days of recording provide to the Secretary a copy of the recorded SMAC letter with the recorder's stamp, recording date, Book and Page number(s).
(2) SMAC letters shall include a copy of the site map showing properly decommissioned monitoring points original source area(s), remediated area(s) and the approximate extents of residual contamination.
(e) Effect on liability. ASMAC designation shall not release the PRP(s) from any past or future liability associated with an identified release or a release discovered after such designation. A SMAC designation does not prevent the Secretary from requiring further assessment of the site pursuant to subsection (f) of this section.
(f) Reopening of SMAC designation. The Secretary may require additional investigation or remediation of a designated site upon finding any of the following:
(1) Previous remediation activities were inadequate;
(2) New information is discovered regarding the time, extent, amount, type, or nature of materials released;
(3) New information is discovered regarding the migration of the hazardous materials, health effects of the hazardous materials, or site conditions;
(4) The Secretary identifies errors or omissions in any of the investigation, or corrective action plan, or their associated implementation;
(5) A new hazardous material is listed or identified that requires a response by the PRP;
(6) Additional release(s) occur;
(7) A condition of the SMAC designation was not completed;
(8) A requirement of the institutional control plan or necessary reporting was not followed; or
(9) Any other condition that presents a threat of unreasonable exposure to humans or the environment from a hazardous material that was released from the site.
1002 Certificate of Completion
(a) Eligibility for Certificate of Completion. A PRP may receive a certificate of completion pursuant to this section if the following have been established:
(1) The PRP meets the eligibility requirements identified in 10 V.S.A. 6645, and has been accepted into the BRELLA program;
(2) The Secretary determines that all work required pursuant to 10 V.S.A. Chapter 159, Subchapter 3 has been completed; and
(3) The Secretary determines that the requirements of this section have been met.
(b) Request; review. A PRP may request the Secretary issue a certificate of completion by filing an application in the same manner as required by § 35-1001(b). The Secretary shall review a request for a certificate of completion in the same manner as § 35-1001(b).
(c) Substantial completion. A PRP may request that the Secretary issue a certificate of completion based upon substantial completion of the corrective action. A certificate of completion shall only be issued to persons who entered the BRELLA program as a prospective purchaser, and only upon determination by the Secretary that one of the following bases exists at the time the application:
(1) that long term monitoring is a component of the corrective action, but the long-term monitoring has not been completed; or
(2) institutional controls are required but have not yet been recorded at the time of the request.
(d) Failure to comply with conditions for a certificate of completion. Any protections provided by a certificate of completion shall be contingent upon the PRP's compliance with conditions identified by the Secretary. Failure to comply with such conditions shall nullify any such protections or other terms of a certificate.
SUBCHAPTER 11 REQUESTS FOR REIMBURSEMENT FOR MUNICIPAL WATER LINE EXTENSIONS FROM THE PETROLEUM CLEANUP OR ENVIRONMENTAL CONTINGENCY FUNDS
1101 Reimbursement of Municipalities to Provide Alternate Water Supplies
(a) Applicability. This section shall apply when:
(1) There has been a release of a hazardous material;
(2) The construction or expansion of or connection to a municipal water line eliminates a sensitive receptor's exposure to a hazardous material; and
(3) The work is performed by a municipality and meets the requirements of this section.
(b) Source of funds. When the release is predominately gasoline, fuel oil, or the release of another petroleum product that would potentially be eligible for reimbursement from the fund established under 10 V.S.A. § 1941 then the reimbursement shall be made from the Petroleum Cleanup Fund; all other reimbursements shall be made from the Contingency Fund established pursuant to 10 V.S.A. § 1283.
(c) Prohibition on Reimbursement.
(1) Reimbursements from the Petroleum Cleanup Fund shall be limited to the reimbursement caps established in 10 V.S.A. § 1941(a)(1) and shall only be for uninsured costs.
(2) Reimbursements from the Contingency Fund shall be limited to the caps established in 10 V.S.A. § 1283(b) or an amount established by the Secretary taking into consideration the current fund balance and known and estimated future obligations on the fund, whichever is lesser.
(3) Where there is a potentially responsible party who has refused to reimburse a municipality for the extension of a municipal water line, the Secretary may condition reimbursement on the successful recovery of funds from that responsible party.
(d) Requirements for reimbursement.
(1) The municipality has applied for all necessary permits required for the project, including public drinking water supply permits;
(2) Municipality must submit cost estimate for review and approval by the Secretary for all work proposed for reimbursement. If an evaluation of corrective action alternatives, including cost effectiveness compared to water treatment or well replacement, has not been completed prior to the final design of a municipal water line extension, the Secretary may require such an analysis prior to approval of the preliminary approval or prior to the construction of the water line extension.
(3) Prior to bidding on a construction project that may encounter contaminated media an environmental professional shall, at a minimum, provide the Secretary with the following:
(A) Identify any land uses that may have resulted in the release of hazardous materials on the route of the municipal water line extension. Identification shall be confined to a review of records at the Agency and municipal records.
(B) If sampling is necessary, submit a plan to conduct limited sampling to estimate the costs associated with management of contaminated soil and groundwater when installing the municipal water line.
(C) Soil management plan. This plan shall include work procedures, treatment, and disposal locations for contaminated soil encountered during the construction process. Contaminated soils shall be backfilled during construction unless it is clearly documented that the soils are geotechnically unsuitable or cannot be replaced within the excavation. Contaminated soils to be backfilled, shall be placed at the bottom of the trench with at least 18" of uncontaminated soil used for closing the trench.
(D) Groundwater management plan. If contaminated groundwater is expected to be encountered, the municipality shall have an environmental professional develop a plan for the treatment of contaminated groundwater. Treatment methods may include re-injection through an infiltration basin, filtration through activated carbon, air stripping, pumping to fractionation tanks, or disposal to a wastewater treatment plant (with appropriate permission from the plant owner and Wastewater Management Division).
(e) Approval of pre-bid preliminary investigation. Prior to implementing any work proposed for reimbursement, the Secretary shall approve the pre-bid preliminary investigation. The Secretary may require additional investigation and work as a part of the approval. The Secretary may disprove any cost associated with a request provided there is a reasonable basis for the disapproval. If an evaluation of corrective action alternatives has not been completed prior to the construction of a municipal water line extension, the Secretary may require such an analysis prior to approval of the pre-bid preliminary investigation.
(f) Final reimbursement request. As a part of any request for reimbursement, a municipality shall provide the Secretary, at a minimum, the following information:
(1) The results of any investigation, sampling, and field work that took place as a part of the investigation.
(2) Receipts for any waste discovered and disposed during the municipal water line extension.
(3) Documentation, such as as-builts and certificate of completions, that the constructed municipal water line extension was constructed per the applicable permit requirements.
(4) The amount requested for reimbursement, including detailed supporting information such as contracts to perform work, detailed invoices from contractors, and other similar information.
(5) The Secretary may require additional documentation to support the request for reimbursement.
(g) Approval of final reimbursement request. Prior to reimbursing a municipality for the extension of a municipal water line the Secretary shall approve the final reimbursement request. The Secretary may require additional documentation to support the request for reimbursement. The Secretary may disprove any cost associated with a request provided there is a reasonable basis for the disapproval.

Appendix A Environmental Media Standards

(see notes at end of table)

Vermont Soil Standards (TR=1 E-06, HQ=1.0)

Analyte

CAS Number

Resident Soil (mg/kg)

Non-Resident Soil (mg/kg)

Urban Background (mg/kg)

Acetochlor

34256-82-1

1,216

14,362

Acetone

67-64-1

40,609

100,028

Alachlor

15972-60-8

61

718

Aldrin

309-00-2

0.02

0.10

Aluminum

7429-90-5

72,507

941,748

Antimony

7440-36-0

26

319

Arsenic, Inorganic

7440-38-2

16

16

Barium

7440-39-3

11,247

127,382

Benomyl

17804-35-2

116

701

Benzene

71-43-2

0.70

4.2

Benzo$(a$)pyrene (a)

50-32-8

0.07

1.54

0.580

Beryllium

7440-41-7

35

289

Bis(2-chloro-1-methylethyl) ether

108-60-1

2,804

36,274

Boron

7440-42-8

14,658

196,100

Bromate

15541-45-4

0.54

3.3

Bromochloromethane

74-97-5

193

597

Bromoxynil

1689-84-5

2.7

16

Butylbenzene, n-

104-51-8

3,504

51,100

Butytbenzene, sec-

135-98-8

7,009

102,200

Butylbenzene, tert-

98-06-6

7,009

102,200

Cadmium (food)

7440-43-9

6.9

87

Carbaryl

63-25-2

317

1,915

Carbon Disulfide

75-15-0

608

662

Carbon Tetrachloride

56-23-5

0.37

2.2

Chlorobenzene

108-90-7

414

726

Chromium(IU), Insoluble Salts

16065-83-1

40,223

360,223

Chromium(VI)

18540-29-9

0.09

1.7

Cobalt

7440-48-4

22

291

Copper

7440-50-8

10,407

139,231

Bis(2-ethylhexyl)phthalate

117-81-7

20

120

Dibromochloropropane

96-12-8

0.01

0.06

Dibromoethane, 1,2-

106-93-4

0.02

0.14

Dichloroethane, 1,1-

75-34-3

2.1

13

Dichloroethane, 1,2-

107-06-2

0.29

1.7

Dichloroethylene, 1,2-cis-

156-59-2

140

1,814

Dichtoroethylene, 1,2-trans-

156-60-5

1,402

18,137

Dichloropropane, 1,2-

78-87-5

1.5

9.1

Dioxane, 1,4-

123-91-1

2.8

17

Ethylbenzene

100-41-4

3.7

22

Fluoranthene

206-44-0

2,301

26,371

Fluorene

86-73-7

2,301

26,371

Hexachlorobenzene

118-74-1

0.13

0.69

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)

121-82-4

4.6

28

Iron

7439-89-6

51,302

686,351

lsopropylbenzene (cumene)

98-82-8.

256

264

Lead and Compounds

7439-92-1

400

800

Manganese (Non-diet)

7439-96-5

1,118

11,350

Mercury (elemental)

7439-97-6

3.1

3.1

Methyl Ethyl Ketone (2-Butanone)

78-93-3

16,952

26,991

Methyl tert-Butyl Ether (MTBE)

1634-04-4

649

4,464

Molybdenum

7439-98-7

366

4,903

Naphthalene

91-20-3

2.7

16

Nickel

7440-02-0

940

9,707

Octahydro-1,3,5, 7-tetranitro-1,3,5,7-tetrazocine (HMX)

2691-41-0

3,698

49,834

Pentachlorophenol

87-86-5

0.48

2.9

Pentaerythritol tetranitrate (PETN)

78-11-5

122

1,436

Perchlorate

14797-73-0

51

686

Perfluoroheptanoic acid (PFHpA)

375-85-9

1.22(b)

14.36(b)

Perfluorohexane sulfonic acid (PFHxS)

355-46-4

Perfluorononanoic acid (PFNA)

375-95-1

Perfluorooctane sulfonic acid (PFOS)

1763-23-1

Perfluorooctanic Acid (PFOA)

335-67-1

Polychlorinated Biphenyls (high risk)

1336-36-3

0.114 (c)

0.68 (c)

Propoxur (Baygon)

114-26-1

79

476

Propyl benzene, n-

103-65-1

253

261

Selenium

7782-49-2

366

4,900

Silver

7440-22-4

237

2,483

Tetrachlorodibenzo-ixlioxin, 2,3,7,8- (TCDD)

1746-01-6

2.25E-06

1.37E-05

Tetrachloroethane, 1,1,1,2-

630-20-6

1.3

8.0

Tetrachloroethylene

127-18-4

2.4

14

Thallium (soluble Thallium)

7440-28-0 *

0.73

196,100

Toluene

108-88-3

706

798

Trichloroethylene

79-01-6

0.68

6.5

Trichloropropane, 1,2,3-

96-18-4

3.11E-03

0.07

Trimethylbenzene, 1,2,3-

526-73-8

144 (d)

177 (d)

Trimethylbenzene, 1,2,4-

95-63-6

Trimethylbenzene, 1,3,5-

108-67-8

Trinitrotoluene, 2,4,6- (TNT)

118-96-7

12

70

Uranium (Soluble Salts)

NA

44

588

Vanadium

7440-62-2

2.8

27

Vinyl Chloride

75-01-4

0.10

0.59

Xylenes

1330-20-7

252

257

Zinc

7440-66-6

21,986

294,150

Notes:

1. Groundwater temperature of 150C used in derivation of volatiziation factors with May 2018 Regional Screening Level Calculator.
2. Csat substitution used if soil inhalation screening value greater than Csat. Csats derived using May 2018 Regional Screening Level Calculator.
2a. All cancer-based soil inhalation screening values were less than respective Csat thus no substitutions.
2b. Residential noncancer-based soil inhalation screening value above respective Csat thus Csat substitiouion employed for the following: Acetone, Carbon Disulfide, Ethylbenzene, lsopropylbenzene (cumene), Mercury (elemental), Methyl ethyl ketone, Methyl tert-butyl ether, n-Propyl benzene, Tetrachloroethylene, Toluene, Trimethyl benzenes, Xylenes.
2c. Non-residential noncancer-based soil inhalation screening value above respective Csat thus Csat substitution employed for the following: Acetone, Carbon Disulfide, Carbon tetrachloride, Chlorobezene, Ethylbenzene, lsopropylbenzene (cumene) Mercury (elemental), Methyl ethyl ketone, Methyl tert-butyl ether, n-Propyl benzene, Tetrachloroethylene, Toluene, Trimethyl benzenes, Xylenes.
3. Lead soil standards are based on the U.S. EPA Regional Screening Levels, effective November 2018.

* GAS Number is for Metallic Thallium

(a) Benzo(a)pyrene cancer-based resident value applicable to benzo(a)pyrene itself and to total benzo(a)pyrene toxic equivalents [B(a)P-TE]. Benzo(a)pyrene noncancer-based value applicable only to benzo(a)pyrene itself.
(b) PFAS - Sum of PFHpA, PFHxS, PFNA, PFOS and PFOA not to exceed applicable resident or non-resident values.
(c) PCBs- sum of all PCBs not to exceed 1.14E-01 mg/kg for the resident scenario and not to exceed 6.8E-01 for the non-resident scenario (IRIS high risk and persistence cancer toxicity values used in cancer assessment; oral reference dose for Aroclor 1254 used in noncancer assessment).
(d) Trimethyl benzenes -Sum of the three isomers not to exceed applicable resident or non-resident values, based on the most conservative value derived for an individual isomer.

VERMONT DEPARTMENT OF HEALTH

EXPOSURE ASSUMPTIONS, PARAMETER VALUES AND FACTORS

2019 RESIDENTIAL SOIL VALUES

SYMBOL

DEFINITION (units)

VALUE

RSV

Residential Soil Value (mg/kg)

Chemical-Specific

RSVnc-ing

Resident, Soil, Noncancer, Ingestion (mg/kg)

Chemical-Specific

RSVnc-der

Resident, Soil, Noncancer, Dermal (mg/kg)

Chemical-Specific

RSVnc-inh

Resident, Soil, Noncancer, Inhalation (mg/kg)

Chemical-Specific

RSVnc-comb

Resident, Soil, Noncancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RSVca-ing

Resident, Soil, Cancer, Ingestion (mg/kg)

Chemical-Specific

RSVca-der

Resident, Soil, Cancer, Dermal (mg/kg)

Chemical-Specific

RSVca-inh

Resident, Soil, Cancer, Inhalation (mg/kg)

Chemical-Specific

RSVca-comb

Resident, Soil, Cancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RSVm-ing

Resident, Soil, Mutagenic, Ingestion (mg/kg)

Chemical-Specific

RSVm-der

Resident, Soil, Mutagenic, Dermal (mg/kg)

Chemical-Specific

RSVm-inh

Resident, Soil, Mutagenic, Inhalation (mg/kg)

Chemical-Specific

RSVm-comb

Resident, Soil, Mutagenic, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RfDO

Chronic Oral Reference Dose (mg/kg-d)

Chemical-Specific

RfC

Chronic Inhalation Reference Concentration (mg/m 3)

Chemical-Specific

CSFO

Oral Cancer Slope Factor (mg/kg-d) -1

Chemical-Specific

IUR

Inhalation Unit Risk (µg/m 3) -1

Chemical-Specific

THQ

Target Hazard Quotient (unitless)

1.0

TR

Target Incremental Lifetime Cancer Risk (unitless)

1x10-6

LT

Lifetime (years)

70

ATR-nc

Averaging Time, Resident, Noncancer (days)

365 x EDYC = 2190

ATR-ca

Averaging Time, Resident, Cancer (days)

365 x EDLT = 25550

IRYC

Soil Ingestion Rate, Young Child Birth-<6years (mg/day)

200

IROC

Soil Ingestion Rate, Older Child6-<18years (mg/day)

100

IRBirth-<2 yr

Soil Ingestion Rate, Fine Age Range ChildBirth-<2years (mg/day)

200

IR2-<6yr

Soil Ingestion Rate, Fine Age Range Child2-<6years (mg/day)

200

IR6-<16yr

Soil Ingestion Rate, Fine Age Range Child 6-<16years (mg/day)

100

IR16-<18yr

Soil Ingestion Rate, Fine Age Range Child16-<18years (mg/day)

100

IRA

Soil Ingestion Rate, Adult (mg/day)

100

IFSR-adj

Resident Soil Ingestion Rate Factor, Age-adjusted (mg/kg)

65,439

IFSMR-adj

Resident Mutagenic Soil Ingestion Rate Factor, Age-adjusted (mg/kg)

250,620

SAYC

Skin Surface Area, Young ChildBirth-<6years (cm2)

2336

SAOC

Skin Surface Area, Older Child6-<18years (cm 2)

4591

SABirth-<2 yr

Skin Surface Area, Fine Age Range ChildBirth-<2years (cm2)

2028

SA2-<6yr

Skin Surface Area, Fine Age Range Child2-<6years (cm2)

2490

SA6-<16yr

Skin Surface Area, Fine Age Range Child6-<16years (cm2)

4407

SA16-<18yr

Skin Surface Area, Fine Age Range Child16<18years (cm2)

5512

SAA

Skin Surface Area, Adult (cm2)

6034

DFSR-adj

Soil Dermal Contact Factor, Age-adjusted (mg/kg)

266,522

DFSMR-adj

Mutagenic Soil Dermal Contact Factor, Age-adjusted (mg/kg)

770,281

ADc

Soil on Skin Adherence Factor, Child (mg/cm2)

0.2

ADA

Soil on Skin Adherence Factor, Adult (mg/cm2)

0.07

BWYC

Body Weight, Young ChildBirth-<6years (kg)

15

BWOC

Body Weight, Older Child6-<18years (kg)

48

BWBirth-<2yr

Body Weight, Fine Age Range, ChildBirth-<2years (kg)

10

BW2-<6yr

Body Weight, Fine Age Range, Child2-<6years (kg)

17

BW6-<16yr

Body Weight, Fine Age Range, Child 6-<16years (kg)

44

BW16-<18yr

Body Weight, Fine Age Range, Child16<18years (kg)

67

BWA

Body Weight, Adult (kg)

70

ABSd

Fraction of chemical absorbed from soil due to dermal contact (unitless)

Chemical-specific

ABSGI

Fraction of chemical absorbed in gastrointestinal tract (unitless). If ABSGI>50%, a value of 1 (100%) used.

Chemical-specific

EFYC

Exposure Frequency, Young ChildBirth-<6years (days/year)

365

EFOC

Exposure Frequency, Older Child6-<18years (days/year)

365

EFBirth-<2yr

Exposure Frequency, Fine Age Range ChildBirth-<2years (days/year)

365

EF2-<6yr

Exposure Frequency, Fine Age Range Child2-<6years (days/year)

365

EF6-<16yr

Exposure Frequency, Fine Age Range Child 6-<16years (days/year)

365

EF16-<18yr

Exposure Frequency, Fine Age Range Child16-<18years (days/year)

365

EFA

Exposure Frequency, Adult (days/year)

365

EDYC

Exposure Duration, Young ChildBirth-<6years (years)

6

EDOC

Exposure Duration, Older Child6-<18years (years)

12

EDBirth-<2yr

Exposure Duration, Fine Age Range ChildBirth-<2years (years)

2

ED2-<6yr

Exposure Duration, Fine Age Range Child2-<6years (years)

4

ED6-<16yr

Exposure Duration, Fine Age Range Child 6-<16years (years)

10

ED16-<18yr

Exposure Duration, Fine Age Range, Child16-<18years (years)

2

EDA

Exposure Duration, Adult (years)

52

ETYC

Exposure Time, Young ChildBirth-<6years (hours/day)

24

ETOC

Exposure Time, Older Child6-<18years (hours/day)

24

ETBirth-<2yr

Exposure Time, Fine Age Range ChildBirth-<2years (hours/day)

24

ET2-<6yr

Exposure Time, Fine Age Range Child2-<6years (hours/day)

24

ET6-<16yr

Exposure Time, Fine Age Range Child6-<16years (hours/day)

24

ET16-<18yr

Exposure Time, Fine Age Range Child16-<18years (hours/day)

24

ETA

Exposure Time, Adult (hours/day)

24

InFSMR-adj

Mutagenic Soil Inhalation Factor, Age-adjusted (days)

42,340

PEF

Particulate Emission Factor (wind-driven) (m3/kg)

1.36 x 109

VF

Volatilization Factor (m3/kg)

Chemical-Specific

RBA

Relative Bioavailability (unitless)

1

SCMF

Snow Cover Modification Factor (unitless)

(e)

Notes:

(a) Surface areas derived using information presented in EPA, 2011 and Boniol et al., 2007 for sexes combined. Mean of 50 [th ]percentile (consistent with EPA, 1989 p. 3-39) Total Body Surface Area for each age range of interest developed. Head, hands, forearms, lower legs and feet considered in contact/exposed for all Child age ranges. Consistent with EPA, 2004 (p. 3-10), head, hands, forearms and lower legs considered for Adult. Percent of Total Surface Area represented by body parts considered in contact/exposed was calculated (mean across age range of interest).
(b) Average mean annual Body Weight for age range of interest (based on both sexes) derived using information presented in Portier, et al., 2007.
(c) Default value employed in U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites. (accessed January 2019).
(d) Chemical-specific Volatilization Factors from U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites. (accessed September 10, 2018 through February 4, 2019).
(e) Snow Cover Modification Factor (SCMF) of 0.7342 applied only to soil inhalation route and only for chemicals that meet "v" criteria (effectively yields exposure frequency of 268 days per year for this route of exposure for this receptor). SCMF of 1 employed for all other routes and for chemicals that do not meet "v" criteria.

References:

Boniol, et al, 2007. Proportion of skin surface area of children and young adults from 2 to 18 years old. J Investig Dermatol 128(2):461-464.

EPA, 1989. Risk Assessment Guidance for Superfund. Volume I: Human Health Evaluation Manual (Part A). Interim Final. United States Environmental Protection Agency. Office of Emergency and Remedial Response. Washington, D.C. EPA/540/1-89/002. December 1989.

EPA, 1991. Human Health Evaluation Manual, Supplemental Guidance: "Standard Default Exposure Factors". United States Environmental Protection Agency.. Office of Solid Waste and Emergency Response. OSWER Publication 9285.6-03. March 1991.

EPA, 2002. Supplemental Guidance for Developing Soil Screening Levels for Superfund Sites. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9355.4-24-02. December 2002.

EPA, 2004. Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9285.7-02EP. July 2004.

EPA, 2011. Exposure Factors Handbook 2011 Edition (Final). U.S. Environmental Protection Agency. Office of Research and Development. Washington, D.C. EPA/600/R-090/052F. September 2011.

EPA, 2018. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. May and November 2018 editions. (accessed various times September 10, 2018 -- February 4, 2019).

Portier et al., 2007. Body weight distributions for risk assessment. Risk Anal 27(1):11-26.

VERMONT DEPARTMENT OF HEALTH

ENDPOINT AND PATHWAY SPECIFIC EQUATIONS 2019 RESIDENTIAL SOIL VALVES

-- Noncarcinogenic (threshold type, systemic effects)

Residential Soil Values

Click here to view image

-- Carcinogenic

Residential Soil Values

Click here to view image

Click here to view image

-- Carcinogenic via Mutagenic Mode of Action and Default ADAFs used

Residential Soil Values

o Ingestion

Click here to view image

Click here to view image

Click here to view image

VERMONT DEPARTMENT OF HEALTH

EXPOSURE ASSUMPTIONS, PARAMETER VALVES AND FACTORS

2019 COMMERCIAL WORKER SOIL VALVES

SYMBOL

DEFINITION (units)

VALUE

CSV

Commercial Worker Soil Value (mg/kg)

Chemical-Specific

CSVnc-ing

Commercial Worker, Soil, Noncancer, Ingestion (mg/kg)

Chemical-Specific

CSVnc-der

Commercial Worker, Soil, Noncancer, Dermal (mg/kg)

Chemical-Specific

CSVnc-inh

Commercial Worker, Soil, Noncancer, Inhalation (mg/kg)

Chemical-Specific

CSVnc-comb

Commercial Worker, Soil, Noncancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

CSVca-ing

Commercial Worker, Soil, Cancer, Ingestion (mg/kg)

Chemical-Specific

CSVca-der

Commercial Worker, Soil, Cancer, Dermal (mg/kg)

Chemical-Specific

CSVca-inh

Commercial Worker, Soil, Cancer, Inhalation (mg/kg)

Chemical-Specific

CSVca-comb

Commercial Worker, Soil, Cancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RfDO

Chronic Oral Reference Dose (mg/kg-d)

Chemical-Specific

RfC

Chronic Inhalation Reference Concentration (mg/m3)

Chemical-Specific

CSFO

Oral Cancer Slope Factor (mg/kg-d)-1

Chemical-Specific

IUR

Inhalation Unit Risk (µg/m 3) -1

Chemical-Specific

THQ

Target Hazard Quotient (unitless)

1.0

TR

Target Incremental Lifetime Cancer Risk (unitless)

1x10-6

LT

Lifetime (years)

70

ATR-nc

Averaging Time, Commercial Worker, Noncancer (days)

365 x EDW = 9125

ATR-ca

Averaging Time, Commercial Worker, Cancer (days)

365 x EDLT = 25550

IRW

Soil Ingestion Rate, Commercial Worker (mg/day)

100

SAW

Skin Surface Area, Adult (cm2)

3527

ADW

Soil on Skin Adherence Factor, Adult (mg/cm2)

0.12

BWW

Body Weight, Adult (kg)

70

ABSd

Fraction of chemical absorbed from soil due to dermal contact (unitless)

Chemical-specific

ABSGI

Fraction of chemical absorbed in gastrointestinal tract (unitless). If ABSGI>50%, a value of 1 (100%) used.

Chemical-specific

EFW

Exposure Frequency, Ingestion & Dermal Commercial Worker (days/year)

250

ETW

Exposure Time, Adult (hours/day)

10

PEF

Particulate Emission Factor (wind-driven) (m3/kg)

1.36 x 109

VF

Volatilization Factor (m3/kg)

Chemical-Specific

RBA

Relative Bioavailability (unitless)

1

Notes:

(a) Surface areas derived using information presented in EPA, 2011, Table 7-2; weighted average of mean values for head, hands, and forearms (male and female, 21+years)
(b) Average mean annual Body Weight for age range of interest (based on both sexes) derived using information presented in Portier, et al., 2007.
(c) Default value employed in U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites (accessed January 2019).
(d) Chemical-specific Volatilization Factors from U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites (accessed September 10, 2018 through February 2019).

References:

BLS, 2016. United States Bureau of Labor Statistics. Division of Labor Force Statistics. Labor Force Statistics from Current Population Survey. Household Data. Annual Average. Last modified February 8, 2017 (accessed 3/28/2017) https://www.bls.gov/cps/cpsaat19.htm.

EPA, 1989. Risk Assessment Guidance for Superfund. Volume I: Human Health Evaluation Manual (Part A). Interim Final. United States Environmental Protection Agency. Office of Emergency and Remedial Response. Washington, D.C. EPA/540/1-89/002. December 1989.

EPA, 1991. Human Health Evaluation Manual, Supplemental Guidance: "Standard Default Exposure Factors". United States Environmental Protection Agency.. Office of Solid Waste and Emergency Response. OSWER Publication 9285.6-03. March 1991.

EPA, 2002. Supplemental Guidance for Developing Soil Screening Levels for Superfund Sites. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9355.4-24-02. December 2002.

EPA, 2004. Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9285.7-02EP. July 2004.

EPA, 2011. Exposure Factors Handbook 2011 Edition (Final). U.S. Environmental Protection Agency. Office of Research and Development. Washington, D.C. EPA/600/R-090/052F. September 2011.

EPA, 2015. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. November 2015 edition. (accessed December 11, 2015).

EPA, 2018. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. May and November 2018 editions. (accessed September 10, 2018 through February 2019).

Portier et al., 2007. Body weight distributions for risk assessment. Risk Anal 27(1):11-26.

VERMONT DEPARTMENT OF HEALTH

ENDPOINT AND PATHWAY SPECIFIC EQUATIONS

2019 COMMERCIAL WORKER SOIL VALVES

-- Noncarcinogenic (threshold type, systemic effects)

Commercial Soil Values

Click here to view image

-- Carcinogenic

-- Commercial Soil Values

Click here to view image

A1 SOIL STANDARDS

(see notes at end of table)

Vermont Soil Standards (TR=1 E-06, HQ=1.0)

Analyte

CAS Number

Resident Soil (mg/kg)

Non-Resident Soil (mg/kg)

Urban Background (mg/kg)

Acetochlor

34256-82-1

1,216

14,362

Acetone

67-64-1

40,609

100,028

Alachlor

15972-60-8

61

718

Aldrin

309-00-2

0.02

0.10

Aluminum

7429-90-5

72,507

941,748

Antimony

7440-36-0

26

319

Arsenic, Inorganic

7440-38-2

16

16

Barium

7440-39-3

11,247

127,382

Benomyl

17804-35-2

116

701

Benzene

71-43-2

0.70

4.2

Benzo$(a$)pyrene (a)

50-32-8

0.07

1.54

0.580

Beryllium

7440-41-7

35

289

Bis(2-chloro-1-methylethyl) ether

108-60-1

2,804

36,274

Boron

7440-42-8

14,658

196,100

Bromate

15541-45-4

0.54

3.3

Bromochloromethane

74-97-5

193

597

Bromoxynil

1689-84-5

2.7

16

Butylbenzene, n-

104-51-8

3,504

51,100

Butytbenzene, sec-

135-98-8

7,009

102,200

Butylbenzene, tert-

98-06-6

7,009

102,200

Cadmium (food)

7440-43-9

6.9

87

Carbaryl

63-25-2

317

1,915

Carbon Disulfide

75-15-0

608

662

Carbon Tetrachloride

56-23-5

0.37

2.2

Chlorobenzene

108-90-7

414

726

Chromium(IU), Insoluble Salts

16065-83-1

40,223

360,223

Chromium(VI)

18540-29-9

0.09

1.7

Cobalt

7440-48-4

22

291

Copper

7440-50-8

10,407

139,231

Bis(2-ethylhexyl)phthalate

117-81-7

20

120

Dibromochloropropane

96-12-8

0.01

0.06

Dibromoethane, 1,2-

106-93-4

0.02

0.14

Dichloroethane, 1,1-

75-34-3

2.1

13

Dichloroethane, 1,2-

107-06-2

0.29

1.7

Dichloroethylene, 1,2-cis-

156-59-2

140

1,814

Dichtoroethylene, 1,2-trans-

156-60-5

1,402

18,137

Dichloropropane, 1,2-

78-87-5

1.5

9.1

Dioxane, 1,4-

123-91-1

2.8

17

Ethylbenzene

100-41-4

3.7

22

Fluoranthene

206-44-0

2,301

26,371

Fluorene

86-73-7

2,301

26,371

Hexachlorobenzene

118-74-1

0.13

0.69

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)

121-82-4

4.6

28

Iron

7439-89-6

51,302

686,351

lsopropylbenzene (cumene)

98-82-8.

256

264

Lead and Compounds

7439-92-1

400

800

Manganese (Non-diet)

7439-96-5

1,118

11,350

Mercury (elemental)

7439-97-6

3.1

3.1

Methyl Ethyl Ketone (2-Butanone)

78-93-3

16,952

26,991

Methyl tert-Butyl Ether (MTBE)

1634-04-4

649

4,464

Molybdenum

7439-98-7

366

4,903

Naphthalene

91-20-3

2.7

16

Nickel

7440-02-0

940

9,707

Octahydro-1,3,5, 7-tetranitro-1,3,5,7-tetrazocine (HMX)

2691-41-0

3,698

49,834

Pentachlorophenol

87-86-5

0.48

2.9

Pentaerythritol tetranitrate (PETN)

78-11-5

122

1,436

Perchlorate

14797-73-0

51

686

Perfluoroheptanoic acid (PFHpA)

375-85-9

1.22(b)

14.36(b)

Perfluorohexane sulfonic acid (PFHxS)

355-46-4

Perfluorononanoic acid (PFNA)

375-95-1

Perfluorooctane sulfonic acid (PFOS)

1763-23-1

Perfluorooctanic Acid (PFOA)

335-67-1

Polychlorinated Biphenyls (high risk)

1336-36-3

0.114 (c)

0.68 (c)

Propoxur (Baygon)

114-26-1

79

476

Propyl benzene, n-

103-65-1

253

261

Selenium

7782-49-2

366

4,900

Silver

7440-22-4

237

2,483

Tetrachlorodibenzo-ixlioxin, 2,3,7,8- (TCDD)

1746-01-6

2.25E-06

1.37E-05

Tetrachloroethane, 1,1,1,2-

630-20-6

1.3

8.0

Tetrachloroethylene

127-18-4

2.4

14

Thallium (soluble Thallium)

7440-28-0 *

0.73

196,100

Toluene

108-88-3

706

798

Trichloroethylene

79-01-6

0.68

6.5

Trichloropropane, 1,2,3-

96-18-4

3.11E-03

0.07

Trimethylbenzene, 1,2,3-

526-73-8

144 (d)

177 (d)

Trimethylbenzene, 1,2,4-

95-63-6

Trimethylbenzene, 1,3,5-

108-67-8

Trinitrotoluene, 2,4,6- (TNT)

118-96-7

12

70

Uranium (Soluble Salts)

NA

44

588

Vanadium

7440-62-2

2.8

27

Vinyl Chloride

75-01-4

0.10

0.59

Xylenes

1330-20-7

252

257

Zinc

7440-66-6

21,986

294,150

Notes:

1. Groundwater temperature of 150C used in derivation of volatiziation factors with May 2018 Regional Screening Level Calculator.
2. Csat substitution used if soil inhalation screening value greater than Csat. Csats derived using May 2018 Regional Screening Level Calculator.
2a. All cancer-based soil inhalation screening values were less than respective Csat thus no substitutions.
2b. Residential noncancer-based soil inhalation screening value above respective Csat thus Csat substitiouion employed for the following: Acetone, Carbon Disulfide, Ethylbenzene, lsopropylbenzene (cumene), Mercury (elemental), Methyl ethyl ketone, Methyl tert-butyl ether, n-Propyl benzene, Tetrachloroethylene, Toluene, Trimethyl benzenes, Xylenes.
2c. Non-residential noncancer-based soil inhalation screening value above respective Csat thus Csat substitution employed for the following: Acetone, Carbon Disulfide, Carbon tetrachloride, Chlorobezene, Ethylbenzene, lsopropylbenzene (cumene) Mercury (elemental), Methyl ethyl ketone, Methyl tert-butyl ether, n-Propyl benzene, Tetrachloroethylene, Toluene, Trimethyl benzenes, Xylenes.
3. Lead soil standards are based on the U.S. EPA Regional Screening Levels, effective November 2018.

* GAS Number is for Metallic Thallium

(a) Benzo(a)pyrene cancer-based resident value applicable to benzo(a)pyrene itself and to total benzo(a)pyrene toxic equivalents [B(a)P-TE]. Benzo(a)pyrene noncancer-based value applicable only to benzo(a)pyrene itself.
(b) PFAS - Sum of PFHpA, PFHxS, PFNA, PFOS and PFOA not to exceed applicable resident or non-resident values.
(c) PCBs- sum of all PCBs not to exceed 1.14E-01 mg/kg for the resident scenario and not to exceed 6.8E-01 for the non-resident scenario (IRIS high risk and persistence cancer toxicity values used in cancer assessment; oral reference dose for Aroclor 1254 used in noncancer assessment).
(d) Trimethyl benzenes -Sum of the three isomers not to exceed applicable resident or non-resident values, based on the most conservative value derived for an individual isomer.

VERMONT DEPARTMENT OF HEALTH

EXPOSURE ASSUMPTIONS, PARAMETER VALUES AND FACTORS

2019 RESIDENTIAL SOIL VALUES

SYMBOL

DEFINITION (units)

VALUE

RSV

Residential Soil Value (mg/kg)

Chemical-Specific

RSVnc-ing

Resident, Soil, Noncancer, Ingestion (mg/kg)

Chemical-Specific

RSVnc-der

Resident, Soil, Noncancer, Dermal (mg/kg)

Chemical-Specific

RSVnc-inh

Resident, Soil, Noncancer, Inhalation (mg/kg)

Chemical-Specific

RSVnc-comb

Resident, Soil, Noncancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RSVca-ing

Resident, Soil, Cancer, Ingestion (mg/kg)

Chemical-Specific

RSVca-der

Resident, Soil, Cancer, Dermal (mg/kg)

Chemical-Specific

RSVca-inh

Resident, Soil, Cancer, Inhalation (mg/kg)

Chemical-Specific

RSVca-comb

Resident, Soil, Cancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RSVm-ing

Resident, Soil, Mutagenic, Ingestion (mg/kg)

Chemical-Specific

RSVm-der

Resident, Soil, Mutagenic, Dermal (mg/kg)

Chemical-Specific

RSVm-inh

Resident, Soil, Mutagenic, Inhalation (mg/kg)

Chemical-Specific

RSVm-comb

Resident, Soil, Mutagenic, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RfDO

Chronic Oral Reference Dose (mg/kg-d)

Chemical-Specific

RfC

Chronic Inhalation Reference Concentration (mg/m 3)

Chemical-Specific

CSFO

Oral Cancer Slope Factor (mg/kg-d) -1

Chemical-Specific

IUR

Inhalation Unit Risk (µg/m 3) -1

Chemical-Specific

THQ

Target Hazard Quotient (unitless)

1.0

TR

Target Incremental Lifetime Cancer Risk (unitless)

1x10-6

LT

Lifetime (years)

70

ATR-nc

Averaging Time, Resident, Noncancer (days)

365 x EDYC = 2190

ATR-ca

Averaging Time, Resident, Cancer (days)

365 x EDLT = 25550

IRYC

Soil Ingestion Rate, Young Child Birth-<6years (mg/day)

200

IROC

Soil Ingestion Rate, Older Child6-<18years (mg/day)

100

IRBirth-<2 yr

Soil Ingestion Rate, Fine Age Range ChildBirth-<2years (mg/day)

200

IR2-<6yr

Soil Ingestion Rate, Fine Age Range Child2-<6years (mg/day)

200

IR6-<16yr

Soil Ingestion Rate, Fine Age Range Child 6-<16years (mg/day)

100

IR16-<18yr

Soil Ingestion Rate, Fine Age Range Child16-<18years (mg/day)

100

IRA

Soil Ingestion Rate, Adult (mg/day)

100

IFSR-adj

Resident Soil Ingestion Rate Factor, Age-adjusted (mg/kg)

65,439

IFSMR-adj

Resident Mutagenic Soil Ingestion Rate Factor, Age-adjusted (mg/kg)

250,620

SAYC

Skin Surface Area, Young ChildBirth-<6years (cm2)

2336

SAOC

Skin Surface Area, Older Child6-<18years (cm 2)

4591

SABirth-<2 yr

Skin Surface Area, Fine Age Range ChildBirth-<2years (cm2)

2028

SA2-<6yr

Skin Surface Area, Fine Age Range Child2-<6years (cm2)

2490

SA6-<16yr

Skin Surface Area, Fine Age Range Child6-<16years (cm2)

4407

SA16-<18yr

Skin Surface Area, Fine Age Range Child16<18years (cm2)

5512

SAA

Skin Surface Area, Adult (cm2)

6034

DFSR-adj

Soil Dermal Contact Factor, Age-adjusted (mg/kg)

266,522

DFSMR-adj

Mutagenic Soil Dermal Contact Factor, Age-adjusted (mg/kg)

770,281

ADc

Soil on Skin Adherence Factor, Child (mg/cm2)

0.2

ADA

Soil on Skin Adherence Factor, Adult (mg/cm2)

0.07

BWYC

Body Weight, Young ChildBirth-<6years (kg)

15

BWOC

Body Weight, Older Child6-<18years (kg)

48

BWBirth-<2yr

Body Weight, Fine Age Range, ChildBirth-<2years (kg)

10

BW2-<6yr

Body Weight, Fine Age Range, Child2-<6years (kg)

17

BW6-<16yr

Body Weight, Fine Age Range, Child 6-<16years (kg)

44

BW16-<18yr

Body Weight, Fine Age Range, Child16<18years (kg)

67

BWA

Body Weight, Adult (kg)

70

ABSd

Fraction of chemical absorbed from soil due to dermal contact (unitless)

Chemical-specific

ABSGI

Fraction of chemical absorbed in gastrointestinal tract (unitless). If ABSGI>50%, a value of 1 (100%) used.

Chemical-specific

EFYC

Exposure Frequency, Young ChildBirth-<6years (days/year)

365

EFOC

Exposure Frequency, Older Child6-<18years (days/year)

365

EFBirth-<2yr

Exposure Frequency, Fine Age Range ChildBirth-<2years (days/year)

365

EF2-<6yr

Exposure Frequency, Fine Age Range Child2-<6years (days/year)

365

EF6-<16yr

Exposure Frequency, Fine Age Range Child 6-<16years (days/year)

365

EF16-<18yr

Exposure Frequency, Fine Age Range Child16-<18years (days/year)

365

EFA

Exposure Frequency, Adult (days/year)

365

EDYC

Exposure Duration, Young ChildBirth-<6years (years)

6

EDOC

Exposure Duration, Older Child6-<18years (years)

12

EDBirth-<2yr

Exposure Duration, Fine Age Range ChildBirth-<2years (years)

2

ED2-<6yr

Exposure Duration, Fine Age Range Child2-<6years (years)

4

ED6-<16yr

Exposure Duration, Fine Age Range Child 6-<16years (years)

10

ED16-<18yr

Exposure Duration, Fine Age Range, Child16-<18years (years)

2

EDA

Exposure Duration, Adult (years)

52

ETYC

Exposure Time, Young ChildBirth-<6years (hours/day)

24

ETOC

Exposure Time, Older Child6-<18years (hours/day)

24

ETBirth-<2yr

Exposure Time, Fine Age Range ChildBirth-<2years (hours/day)

24

ET2-<6yr

Exposure Time, Fine Age Range Child2-<6years (hours/day)

24

ET6-<16yr

Exposure Time, Fine Age Range Child6-<16years (hours/day)

24

ET16-<18yr

Exposure Time, Fine Age Range Child16-<18years (hours/day)

24

ETA

Exposure Time, Adult (hours/day)

24

InFSMR-adj

Mutagenic Soil Inhalation Factor, Age-adjusted (days)

42,340

PEF

Particulate Emission Factor (wind-driven) (m3/kg)

1.36 x 109

VF

Volatilization Factor (m3/kg)

Chemical-Specific

RBA

Relative Bioavailability (unitless)

1

SCMF

Snow Cover Modification Factor (unitless)

(e)

Notes:

(a) Surface areas derived using information presented in EPA, 2011 and Boniol et al., 2007 for sexes combined. Mean of 50 [th ]percentile (consistent with EPA, 1989 p. 3-39) Total Body Surface Area for each age range of interest developed. Head, hands, forearms, lower legs and feet considered in contact/exposed for all Child age ranges. Consistent with EPA, 2004 (p. 3-10), head, hands, forearms and lower legs considered for Adult. Percent of Total Surface Area represented by body parts considered in contact/exposed was calculated (mean across age range of interest).
(b) Average mean annual Body Weight for age range of interest (based on both sexes) derived using information presented in Portier, et al., 2007.
(c) Default value employed in U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites. (accessed January 2019).
(d) Chemical-specific Volatilization Factors from U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites. (accessed September 10, 2018 through February 4, 2019).
(e) Snow Cover Modification Factor (SCMF) of 0.7342 applied only to soil inhalation route and only for chemicals that meet "v" criteria (effectively yields exposure frequency of 268 days per year for this route of exposure for this receptor). SCMF of 1 employed for all other routes and for chemicals that do not meet "v" criteria.

References:

Boniol, et al, 2007. Proportion of skin surface area of children and young adults from 2 to 18 years old. J Investig Dermatol 128(2):461-464.

EPA, 1989. Risk Assessment Guidance for Superfund. Volume I: Human Health Evaluation Manual (Part A). Interim Final. United States Environmental Protection Agency. Office of Emergency and Remedial Response. Washington, D.C. EPA/540/1-89/002. December 1989.

EPA, 1991. Human Health Evaluation Manual, Supplemental Guidance: "Standard Default Exposure Factors". United States Environmental Protection Agency.. Office of Solid Waste and Emergency Response. OSWER Publication 9285.6-03. March 1991.

EPA, 2002. Supplemental Guidance for Developing Soil Screening Levels for Superfund Sites. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9355.4-24-02. December 2002.

EPA, 2004. Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9285.7-02EP. July 2004.

EPA, 2011. Exposure Factors Handbook 2011 Edition (Final). U.S. Environmental Protection Agency. Office of Research and Development. Washington, D.C. EPA/600/R-090/052F. September 2011.

EPA, 2018. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. May and November 2018 editions. (accessed various times September 10, 2018 -- February 4, 2019).

Portier et al., 2007. Body weight distributions for risk assessment. Risk Anal 27(1):11-26.

VERMONT DEPARTMENT OF HEALTH

ENDPOINT AND PATHWAY SPECIFIC EQUATIONS 2019 RESIDENTIAL SOIL VALVES

-- Noncarcinogenic (threshold type, systemic effects)

Residential Soil Values

Click here to view image

-- Carcinogenic

Residential Soil Values

Click here to view image

Click here to view image

-- Carcinogenic via Mutagenic Mode of Action and Default ADAFs used

Residential Soil Values

o Ingestion

Click here to view image

Click here to view image

Click here to view image

VERMONT DEPARTMENT OF HEALTH

EXPOSURE ASSUMPTIONS, PARAMETER VALVES AND FACTORS

2019 COMMERCIAL WORKER SOIL VALVES

SYMBOL

DEFINITION (units)

VALUE

CSV

Commercial Worker Soil Value (mg/kg)

Chemical-Specific

CSVnc-ing

Commercial Worker, Soil, Noncancer, Ingestion (mg/kg)

Chemical-Specific

CSVnc-der

Commercial Worker, Soil, Noncancer, Dermal (mg/kg)

Chemical-Specific

CSVnc-inh

Commercial Worker, Soil, Noncancer, Inhalation (mg/kg)

Chemical-Specific

CSVnc-comb

Commercial Worker, Soil, Noncancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

CSVca-ing

Commercial Worker, Soil, Cancer, Ingestion (mg/kg)

Chemical-Specific

CSVca-der

Commercial Worker, Soil, Cancer, Dermal (mg/kg)

Chemical-Specific

CSVca-inh

Commercial Worker, Soil, Cancer, Inhalation (mg/kg)

Chemical-Specific

CSVca-comb

Commercial Worker, Soil, Cancer, Combined Routes of Exposure (mg/kg)

Chemical-Specific

RfDO

Chronic Oral Reference Dose (mg/kg-d)

Chemical-Specific

RfC

Chronic Inhalation Reference Concentration (mg/m3)

Chemical-Specific

CSFO

Oral Cancer Slope Factor (mg/kg-d)-1

Chemical-Specific

IUR

Inhalation Unit Risk (µg/m 3) -1

Chemical-Specific

THQ

Target Hazard Quotient (unitless)

1.0

TR

Target Incremental Lifetime Cancer Risk (unitless)

1x10-6

LT

Lifetime (years)

70

ATR-nc

Averaging Time, Commercial Worker, Noncancer (days)

365 x EDW = 9125

ATR-ca

Averaging Time, Commercial Worker, Cancer (days)

365 x EDLT = 25550

IRW

Soil Ingestion Rate, Commercial Worker (mg/day)

100

SAW

Skin Surface Area, Adult (cm2)

3527

ADW

Soil on Skin Adherence Factor, Adult (mg/cm2)

0.12

BWW

Body Weight, Adult (kg)

70

ABSd

Fraction of chemical absorbed from soil due to dermal contact (unitless)

Chemical-specific

ABSGI

Fraction of chemical absorbed in gastrointestinal tract (unitless). If ABSGI>50%, a value of 1 (100%) used.

Chemical-specific

EFW

Exposure Frequency, Ingestion & Dermal Commercial Worker (days/year)

250

ETW

Exposure Time, Adult (hours/day)

10

PEF

Particulate Emission Factor (wind-driven) (m3/kg)

1.36 x 109

VF

Volatilization Factor (m3/kg)

Chemical-Specific

RBA

Relative Bioavailability (unitless)

1

Notes:

(a) Surface areas derived using information presented in EPA, 2011, Table 7-2; weighted average of mean values for head, hands, and forearms (male and female, 21+years)
(b) Average mean annual Body Weight for age range of interest (based on both sexes) derived using information presented in Portier, et al., 2007.
(c) Default value employed in U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites (accessed January 2019).
(d) Chemical-specific Volatilization Factors from U.S. EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites (accessed September 10, 2018 through February 2019).

References:

BLS, 2016. United States Bureau of Labor Statistics. Division of Labor Force Statistics. Labor Force Statistics from Current Population Survey. Household Data. Annual Average. Last modified February 8, 2017 (accessed 3/28/2017) https://www.bls.gov/cps/cpsaat19.htm.

EPA, 1989. Risk Assessment Guidance for Superfund. Volume I: Human Health Evaluation Manual (Part A). Interim Final. United States Environmental Protection Agency. Office of Emergency and Remedial Response. Washington, D.C. EPA/540/1-89/002. December 1989.

EPA, 1991. Human Health Evaluation Manual, Supplemental Guidance: "Standard Default Exposure Factors". United States Environmental Protection Agency.. Office of Solid Waste and Emergency Response. OSWER Publication 9285.6-03. March 1991.

EPA, 2002. Supplemental Guidance for Developing Soil Screening Levels for Superfund Sites. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9355.4-24-02. December 2002.

EPA, 2004. Risk Assessment Guidance for Superfund Volume I: Human Health Evaluation Manual (Part E, Supplemental Guidance for Dermal Risk Assessment) Final. U.S. Environmental Protection Agency. Washington, D.C. OSWER 9285.7-02EP. July 2004.

EPA, 2011. Exposure Factors Handbook 2011 Edition (Final). U.S. Environmental Protection Agency. Office of Research and Development. Washington, D.C. EPA/600/R-090/052F. September 2011.

EPA, 2015. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. November 2015 edition. (accessed December 11, 2015).

EPA, 2018. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. May and November 2018 editions. (accessed September 10, 2018 through February 2019).

Portier et al., 2007. Body weight distributions for risk assessment. Risk Anal 27(1):11-26.

VERMONT DEPARTMENT OF HEALTH

ENDPOINT AND PATHWAY SPECIFIC EQUATIONS

2019 COMMERCIAL WORKER SOIL VALVES

-- Noncarcinogenic (threshold type, systemic effects)

Commercial Soil Values

Click here to view image

-- Carcinogenic

-- Commercial Soil Values

Click here to view image

A2 Vapor Intrusion Standards

Indoor Air Standards TR=1 E-06, HQ=1.0)

Vapor Intrusion Standards - Sub-slab Soil Gas

Vapor Intrusion Standards - Groundwater

Analyte

CAS Number

Resident (µg/m3)

Non-resident (µg/m3)

Resident (µg/m3)

Non-resident (µg/L)

Resident (µg/m3)

Non-resident (µg/L)

Benzene

71-43-2

0.13

1.05

4.3

35

0.92

7.4

Carbon Tetrachloride

56-23-5

0.17

1.36

5.7

45

0.24

1.9

Chloroethane

75-00-3

10,000.00

35,040.00

330,000

1,200,000

31,000

110,000

Chloroform

67-66-3

0.04

0.36

1.3

12

0.41

. 3.7

Dichloroethane, 1,1-

75-34-3

0.63

5.11

21

170

4.2

34

Dichloroethylene, 1,1-

75-35-4

200.00

700.8

6,700

23,000

270

950

Ethylbenzene

100-41-4

0.40

3.27

13

110

2.2

18

Mercury (elemental)

7439-97-6

0.30

0.3 (b)

10

10

2.0

2.0

Methylene Chloride

75-09-2

60.34

817.60

2,000

27,000

680

9,300

Naphthalene

91-20-3

0.262 (c)

0.262 (c)

1.0

8.0

4

28

Tetrachloroethylene

127-18-4

0.63

5.11

21

170

1.5

12

Trichloroethytene

79-01-6

0.20

0.7 (a)

6.7

23

0.82

2.9

Trirnethylbenzene, 1,2,3-

526-73-8

60 (d)

210.24 (d)

2000 (d)

7000 (d)

790

2,800

Trirnethylbenzene, 1,2,4-

95-63-6

470

1,700

Trirnethylbenzene, 1,3,5-

108-67-8

330

1,200

Vinyl Chloride

75-01-4

0.11

1.86

3.7

62

0.13

2.2

Notes:

1. The VI Screening Values for soil gas and groundwater were calculated from the indoor air standards using the USEPA Vapor Intrusion Screening Level Calculator. The sub-slab soil gas concentration is the target indoor air concentration divided by the generic attenuation factor for soil gas (0.03). Target groundwater concentrations were calculated based on an ambient groundwater temperature of 150 C and a generic attenuation factor for groundwater (0.001).
(a) Due to the nature and severity of a particular non-cancer endpoint (fetal cardiac malformations) that may be associated with a brief window of susceptability, there is significant uncertainty regarding the exposure period of concern. Thus, a target hazard quotient of 0.1 was used in the calculation of the non-cancer values.
(b) Due to the developmental toxicity associated with mercury exposure the reference concentration is used as the nonresidental air value without adjusting for the exposure period.
(c) The indoor air values for naphthalene have been adjusted upwards from the risk-based values (0.03/0.24) to reflect the laboratory method detection limit value.
(d) Trimethylbenzenes - Sum of the three isomers not to exceed applicable resident or non-resident values, based on the most conservative value derived for an individual isomer.

VERMONT DEPARTMENT OF HEALTH

EXPOSURE ASSUMPTIONS, PARAMETER VALUES AND FACTORS

2019 RESIDENTIAL AIR VALUES (RAVs)

2019 NONRESIDENTIAL AIR VALUES (NAVs)

SYMBOL

DEFINITION (units)

VALUE

RAV

Residential Air Value (µg/m3)

Chemical-Specific

RAVnc-inh

Resident, Air, Noncancer, Inhalation (µg/m3)

Chemical-Specific

RAVca-inh

Resident, Air, Cancer, Inhalation (µg/m3)

Chemical-Specific

RAVm-inh

Resident, Air, Mutagenic, Inhalation (µg/m3)

Chemical-Specific

NAV

Nonresidential Air Value (µg/m3)

Chemical-Specific

NAVnc-inh

Nonresidential, Air, Noncancer, Inhalation (µg/m3)

Chemical-Specific

NAVca-inh

Nonresidential, Air, Cancer, Inhalation (µg/m3)

Chemical-Specific

RfC

Chronic Inhalation Reference Concentration (mg/m3)

Chemical-Specific

IUR

Inhalation Unit Risk (µg/m3) -1

Chemical-Specific

THQ

Target Hazard Quotient (unitless)

1.0

TR

Target Incremental Lifetime Cancer Risk (unitless)

1x10-6

LT

Lifetime (years)

70

ATR-ca

Averaging Time, Resident, Cancer (days)

365 x EDR =25550

ATN-nc

Averaging Time, Nonresidential, Noncancer (days)

365 x EDN =10950

ATN-ca

Averaging Time, Nonresidential, Cancer (days)

365 x EDN =25550

EFR

Resident Exposure Frequency (days/year)

365

EFBirth-<2yr

Resident Exposure Frequency, Fine Age Range ChildBirth-<2years (days/year)

365

EF2-<6yr

Resident Exposure Frequency, Fine Age Range Child2-<6years (days/year)

365

EF6-<16yr

Resident Exposure Frequency, Fine Age Range Child6-<16years (days/year)

365

EF16-<18yr

Resident, Exposure Frequency, Fine Age Range Child16-<18years (days/years)

365

EFA

Resident Exposure Frequency, Adult (days/year)

365

EFN

Nonresidential Exposure Frequency (days/year)

250

EDR

Resident Exposure Duration (years)

70

EDBirth-<2yr

Resident Exposure Duration, Fine Age Range ChildBirth-<2years (years)

2

ED2-<6yr

Resident Exposure Duration, Fine Age Range Child2-<6years (years)

4

ED6-<16yr

Resident Exposure Duration, Fine Age Range Child6-<16years (years)

10

ED16-<18yr

Resident Exposure Duration, Fine Age Range Child16-<18years (years)

2

EDA

Resident Exposure Duration, Adult (years)

52

EDN

Nonresidential Exposure Duration (years)

30

ETR

Resident Exposure Time (hours/day)

24

ETBirth-<2yr

Resident Exposure Time, Fine Age Range ChildBirth-<2years (hours/day)

24

ET2-<6yr

Resident Exposure Time, Fine Age Range Child2-<6years (hours/day)

24

ET6-<16yr

Resident Exposure Time, Fine Age Range Child6-<16years (hours/day)

24

ET16-<18yr

Resident Exposure Time, Fine Age Range Child16-<18years (hours/day)

24

ETA

Resident Exposure Time, Adult (hours/day)

24

ETN

Nonresidential Exposure Time (hours/day)

10

IFAMR-adj

Resident Mutagenic Air Inhalation Factor, age-adjusted (hours)

1,016,160

Notes:

(a) General estimate of years of service for full benefits

References:

BLS, 2016. United States Bureau of Labor Statistics. Division of Labor Force Statistics. Labor Force Statistics from Current Population Survey. Household Data. Annual Average. Last modified February 8, 2017 (accessed 3/28/2017) https://www.bls.gov/cps/cpsaat19.htm.

EPA, 1989. Risk Assessment Guidance for Superfund. Volume I: Human Health Evaluation Manual (Part A). Interim Final. United States Environmental Protection Agency. Office of Emergency and Remedial Response. Washington, D.C. EPA/540/1-89/002. December 1989.

EPA, 1991. Human Health Evaluation Manual, Supplemental Guidance: "Standard Default Exposure Factors". United States Environmental Protection Agency. Office of Solid Waste and Emergency Response. OSWER Publication 9285.6-03. March 1991.

EPA, 2016. United States Environmental Protection Agency. Regional Screening Levels for Chemical Contaminants at Superfund Sites. User's Guide. May 2016 edition. (accessed June 6, 2016). https://www.epa.gov/risk/regional-screening-levels-rsls.

VERMONT DEPARTMENT OF HEALTH

SCENARIO, ENDPOINT AND PATHWAY SPECIFIC EQUATIONS

2019 RESIDENTIAL AIR VALVES (RAVs)

019 NONRESIDENTIAL AIR VALVES (NAVs)

2
I. RESIDENTIAL AIR VALVES

-- Noncarcinogenic (threshold type, systemic effects)

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-- Carcinogenic

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-- Carcinogenic via Mutagenic Mode of Action and Default ADAFs used

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II. NONRESIDENTIAL AIR VALUES

-- Noncarcinogenic (threshold type, systemic effects)

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-- Carcinogenic

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Table 3-Recommended Sediment Quality Guidelines for the Protection of Aquatic Biota in Freshwater Ecosystems

Analyte

TEC

PEC

Notes

Metals (in mg/kg - ppm DW)

Arsenic

9.79

33

1,2

Cadmium

0.99

4.98

1,2

Chromium

43.4

111

1,2

Copper

31.6

149

1,2

Lead

35.8

128

1,2

Mercury

0.18

1.06

1,2,4

Nickel

22.7

48.6

1,2

Zinc

121

459

1,2

Polycyclic Aromatic Hydrocarbons (in µg/kg - ppb DW)

Anthracene

57.2

845

1,3

Fluorene

77.4

536

1,3

Naphthalene

176

561

1,3

Phenanthrene

204

1,170

1,3

Benz(a)anthracene

108

1,050

1,3

Benzo(a)pyrene

150

1,450

1,3,4

Chrysene

166

1,290

1,3

Dibenz(a,h)anthracene

33

1,3

Fluoranthene

423

2,230

1,3

Pyrene

195

1,520

1,3

Total PAHs

1,610

22,800

1,3

Polychlorinated Biphenyls (in µg/kg -- ppb DW)

Total PCBs

59.8

676

1,3,4

Organochlorine Pesticides (in µg/kg -- ppb DW)

Chlordane

3.24

17.6

1,3,4

Dieldrin

1.9

61.8

1,3,4

Sum DDD

4.88

28

1,3,4

Sum DDE

3.16

31.3

1,3,4

Sum DDT

4.16

62.9

1,3,4

Total DDTs

5.28

572

1,3,4

Endrin

2.22

207

1,3

Heptachlor Epoxide

2.47

16

1,3

Lindane (gamma-BHC)

2.37

4.99

1,3

Notes: TEC = Threshold Effect Concentration, PEC = Probable Effects Concentration, DW = dry weight

1. Consensus-Based Sediment Quality Guidelines (SQGs) from: MacDonald D.D., Ingersoll C.G. and Berger T.A. 2000. Development and Evaluation of Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems. Archives of Environmental Contamination and Toxicology 39(1). 20-31.
2. SQGs for metals are based on bulk (unsorted) sediment concentrations. Concentrations of metals in sediments can be normalized on percent fines for the purpose of inter-site comparisons but not for comparisons to these SQGs.
3. The SQGs for organics are derived from samples normalized to 1 percent total organic carbon (TOC) in the sediment. The SQGs presented here are based on an assumed TOC of 1 percent. If site specific data show organic carbon content to be significantly different from 1 percent, concentrations should be normalized to 1 percent TOC (divide the site concentration by the percent TOC) prior to comparison with the SQGs in this table. If non site-specific TOC data are available, assume 1 percent TOC.
4. Included on USEPA's list of important persistent, bioaccumulative, toxic compounds (PBTs). Appendix B. Establishment of Background Concentrations.

Appendix B Establishment of Background Concentrations

(a) Purpose. A PRP may conduct a site-specific background study when there is reason to believe that the contamination present is naturally occurring. An approved site specific background concentration will take the place of an adopted environmental media standard.
(b) Sampling plan. A sampling and monitoring plan must be prepared by an environmental professional that will produce data representative of the site at and around the area of interest. The plan shall identify, at a minimum, the following:
(1) The number of monitoring points that will be sampled to establish a statistically defensible data set that will substantiate the validity of the background concentrations;
(2) The location and depth of monitoring points, which shall be selected so as to be geologically and geochemically similar to the area of interest and to be unaffected by current and historic activities at the site, including by being hydrogeologically upgradient of such activities if possible;
(3) The number and frequency of the samples to be taken from the monitoring points and any existing sources of data for the media for which a background standard is proposed, including water for potable water supplies, public water sources, or nonpotable wells or springs;
(4) The sampling methodology; (5) The contaminants of concern to be analyzed in the samples that are collected;
(6) The analytical methods to be used in conducting the sample analysis;
(7) Identification of whether samples obtained prior to the approval of the monitoring plan will be used as data points and, if so, the sampling date, location, method of analysis for each of the samples to be used; and
(8) A quality assurance/ quality control plan for sample collection, testing, and analysis.
(c) Review of sampling plan. The information required by subsection (b) of this section may be included in a site investigation work plan submitted under Subchapter 3. The Secretary may request additional information from an applicant when the Secretary determines that the sampling and monitoring plan may not provide data representative of the background conditions at and around the area of interest.
(d) Report on background investigation. Following the Secretary's approval of the sampling and monitoring plan and the completion of sampling, the person seeking to establish a site specific background standard shall report on the following as a part of their site investigation report required by § 35-306:
(1) All sampling results and data collected pursuant to the approved monitoring and sampling plan.
(2) An analysis of all data collected pursuant to the approved monitoring and sampling plan.
(3) Any discrepancies between the approved sampling and monitoring plan and the sampling completed for the area of interest.
(4) A proposed background concentration of all substances for which the person seeks to establish background standard and a justification for each concentration. The justification may include statistical analysis.
(5) Additional information the Secretary determines is necessary to approve or deny the proposed background groundwater concentrations.
(e) Site specific standard. Following submission of the background groundwater quality report to the Secretary, the Secretary shall approve or deny the proposed background groundwater concentrations or may establish alternative background groundwater concentrations based on the background groundwater quality report.

Appendix C Site Management Waivers

(a) Purpose. A technical impracticality (TI) waiver is a mechanism to manage risks to human health and the environment in situations where there is no readily available technology to complete remediation and achieve compliance with the applicable environmental media standards within a reasonable timeframe. A TI waiver does not waive the requirements to delineate the nature and extent of the release of pollutants, to remediate continuing sources of pollution, or to address potential risks to receptors.
(b) Applicability. A TI waiver may be considered as a part of § 35-903. TI waivers may be considered for any of the following:
(1) The Secretary determines that there are non-aqueous phase liquids that cannot be contained or removed.
(2) The Secretary determines that there is only one response action for the activity and it cannot obtain other necessary permits.
(3) The Secretary determines that remediation has taken place to reduce in concentration hazardous materials in groundwater and the plume has been controlled to the extent practical based on an evaluation of reliable and innovative technologies.
(4) The Secretary determines that achieving compliance with the applicable criteria is technically impracticable as determined using Directive No. 9234.2-25 issued September 1993 by the U.S. Environmental Protection Agency's Office of Solid Waste and Emergency Response.
(c) Prohibition. A TI waiver is prohibited in the following circumstances:
(1) Situations where the Secretary determines that active remediation is necessary to control the migration of a plume or materially reduce the concentration of a hazardous material; or
(2) After approval of a TI waiver there would continue to be unmanaged exposure to human health receptors.
(d) Technical impracticality waiver documentation. For any PRP proposing a TI waiver, the site investigation report prepared under § 35-306 shall, in addition to all other requirements, contain the following materials:
(1) A proposal for the environmental standard or standards for which the PRP is seeking a TI waiver.
(2) A proposed TI zone for purposes of implementing the waiver that documents the following:
(A) The plume is not increasing in size or concentration in a manner which would alter the risk assumptions associated with the TI waiver request or the extent of the TI Zone.
(B) The plume is not increasing at compliance points at the TI Zone boundary.
(3) Documentation that all necessary permits have been applied for, made best efforts to obtain, and were denied.
(4) Documentation that the site has been adequately characterized including the nature and three-dimensional extent of the contamination.
(5) Any potential changes in contaminant concentrations will not pose a risk to human health or the environment.
(6) Documentation that potential exposure pathways threatening human health and the environment from polluted groundwater have been identified and appropriately managed.
(7) Documentation that all data gaps have been identified and evaluated for significance (a significant data gap would be one that limits the ability to formulate a single scientifically defensible interpretation of environmental conditions or potential risks, or that may affect the choice of remedial approach).
(8) An evaluation showing the remedial restoration times using active remedial treatments. All assumptions and the degree of uncertainty associated with any model shall be thoroughly discussed.
(9) An evaluation showing natural attenuation, based on monitoring subsequent to source remediation, has shown that groundwater will not achieve remedial criteria within a reasonable timeframe. All assumptions and the degree of uncertainty associated with any model shall be thoroughly discussed.
(10) An estimate the cost of remedial alternatives. Cost estimates shall include the present worth of construction, operation, and maintenance costs.
(11) An evaluation of implementing remediation alternatives for plume containment or for reduction of the concentration of hazardous materials in the plume.

Note: When conducting a TI waiver analysis as a part of an evaluation of cleanup options, the Agency recommends review of the following guidance documents in preparing a request for a TI waiver:

Technical Impracticability: Guidance for Evaluating Technical Impracticability of GroundWater Restoration, September 1993. U.S. E.P.A. OSWER Directive 9234.2-25

Technical Impracticability Guidance for Groundwater, December 2013. New Jersey Department of Environmental Protection.

Draft Guidance for Applying Technical Impracticability of Groundwater, February 2014. Connecticut Department of Energy and Environmental Protection.

Notes

12-008 Code Vt. R. 12-032-008-X
EFFECTIVE DATE:
July 27, 2017 Secretary of State Rule Log #17044
AMENDED:
July 6, 2019 Secretary of State Rule Log #19028

STATUTORY AUTHORITY: 10 V.S.A. §§ 6603, 6604c; C.47, 59, 159

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